cMOF Evidence Base
Other — Synthesis and changes of conductivities and thermal stabilities of 4,4′-oxybis [N-(3,4-dihydroxybenzilidene) aniline] chelate polymers

Measurement evidence

Other

Synthesis and changes of conductivities and thermal stabilities of 4,4′-oxybis [N-(3,4-dihydroxybenzilidene) aniline] chelate polymers · Kaya I., Yildirim M. · Journal of Inorganic and Organometallic Polymers and Materials · 2008 · 325-333

20 measurement groups · 74 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Atomic absorption spectroscopy (Shimadzu 6200) after HNO3 decomposition/dilution

Bulk elemental and compositional analysis

P-3,4-HBA-Cd pristine coordination-polymer solid/pellet · Pellet

Metal analyses of chelated polymers decomposed with HNO3, diluted with deionised water.

Context
pristine polymer composition analysis
Measurement source
3-4 · Section 2.4; Table 1 · Table 1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
P-3,4-HBA-Cd metal content18.68%——Table
Exact Reported		4 · Table 1 · Table 1

Atomic absorption spectroscopy (Shimadzu 6200) after HNO3 decomposition/dilution

Bulk elemental and compositional analysis

P-3,4-HBA-Co pristine coordination-polymer solid/pellet · Pellet

Metal analyses of chelated polymers decomposed with HNO3, diluted with deionised water.

Context
pristine polymer composition analysis
Measurement source
3-4 · Section 2.4; Table 1 · Table 1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
P-3,4-HBA-Co metal content11.05%——Table
Exact Reported		4 · Table 1 · Table 1

Atomic absorption spectroscopy (Shimadzu 6200) after HNO3 decomposition/dilution

Bulk elemental and compositional analysis

P-3,4-HBA-Cr pristine coordination-polymer solid/pellet · Pellet

Metal analyses of chelated polymers decomposed with HNO3, diluted with deionised water.

Context
pristine polymer composition analysis
Measurement source
3-4 · Section 2.4; Table 1 · Table 1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
P-3,4-HBA-Cr metal content10.0%——Table
Exact Reported		4 · Table 1 · Table 1

Atomic absorption spectroscopy (Shimadzu 6200) after HNO3 decomposition/dilution

Bulk elemental and compositional analysis

P-3,4-HBA-Cu pristine coordination-polymer solid/pellet · Pellet

Metal analyses of chelated polymers decomposed with HNO3, diluted with deionised water.

Context
pristine polymer composition analysis
Measurement source
3-4 · Section 2.4; Table 1 · Table 1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
P-3,4-HBA-Cu metal content11.95%——Table
Exact Reported		4 · Table 1 · Table 1

Atomic absorption spectroscopy (Shimadzu 6200) after HNO3 decomposition/dilution

Bulk elemental and compositional analysis

P-3,4-HBA-Mn pristine coordination-polymer solid/pellet · Pellet

Metal analyses of chelated polymers decomposed with HNO3, diluted with deionised water.

Context
pristine polymer composition analysis
Measurement source
3-4 · Section 2.4; Table 1 · Table 1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
P-3,4-HBA-Mn metal content10.87%——Table
Exact Reported		4 · Table 1 · Table 1

Atomic absorption spectroscopy (Shimadzu 6200) after HNO3 decomposition/dilution

Bulk elemental and compositional analysis

P-3,4-HBA-Ni pristine coordination-polymer solid/pellet · Pellet

Metal analyses of chelated polymers decomposed with HNO3, diluted with deionised water.

Context
pristine polymer composition analysis
Measurement source
3-4 · Section 2.4; Table 1 · Table 1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
P-3,4-HBA-Ni metal content10.95%——Table
Exact Reported		4 · Table 1 · Table 1

Atomic absorption spectroscopy (Shimadzu 6200) after HNO3 decomposition/dilution

Bulk elemental and compositional analysis

P-3,4-HBA-Pb pristine coordination-polymer solid/pellet · Pellet

Metal analyses of chelated polymers decomposed with HNO3, diluted with deionised water.

Context
pristine polymer composition analysis
Measurement source
3-4 · Section 2.4; Table 1 · Table 1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
P-3,4-HBA-Pb metal content31.8%——Table
Exact Reported		4 · Table 1 · Table 1

Atomic absorption spectroscopy (Shimadzu 6200) after HNO3 decomposition/dilution

Bulk elemental and compositional analysis

P-3,4-HBA-Zn pristine coordination-polymer solid/pellet · Pellet

Metal analyses of chelated polymers decomposed with HNO3, diluted with deionised water.

Context
pristine polymer composition analysis
Measurement source
3-4 · Section 2.4; Table 1 · Table 1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
P-3,4-HBA-Zn metal content12.8%——Table
Exact Reported		4 · Table 1 · Table 1

Size exclusion chromatography (Shimadzu 10AVp HPLC-SEC) with RI and UV-vis detectors

UV-visible and optical absorption spectroscopy

P-3,4-HBA-Cr pristine coordination-polymer solid/pellet · Pellet

25 °C; DMF/methanol (4/1 v/v) eluent at 0.4 mL/min; calibrated with polystyrene standards.

Temperature
298.15
Geometry
Macherey-Nagel column, 3.3 mm i.d. x 300 mm
Context
pristine soluble Cr coordination polymer
Measurement source
3-4 · Sections 2.4 and 3.2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
P-3,4-HBA-Cr SEC Mn by RI detector10770 g mol^-1——Text
Exact Reported		4 · Section 3.2
P-3,4-HBA-Cr SEC Mn by UV detector10400 g mol^-1——Text
Exact Reported		4 · Section 3.2
P-3,4-HBA-Cr SEC Mw by RI detector10950 g mol^-1——Text
Exact Reported		4 · Section 3.2
P-3,4-HBA-Cr SEC Mw by UV detector10430 g mol^-1——Text
Exact Reported		4 · Section 3.2
P-3,4-HBA-Cr SEC PDI by RI detector1.017——Text
Exact Reported		4 · Section 3.2
P-3,4-HBA-Cr SEC PDI by UV detector1.003——Text
Exact Reported		4 · Section 3.2
P-3,4-HBA-Cr approximate repeat units21-22 repeat units——Text
Range		4 · Section 3.2

Solubility test

P-3,4-HBA-Cr pristine coordination-polymer solid/pellet · Pellet

1 mg polymer in 1 mL solvent; tested at 25 °C and 60 °C.

Temperature
298.15; 333.15
Geometry
vial solubility test
Context
pristine polymer solubility
Measurement source
3 · Section 2.4 Solubility and Characterization
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
P-3,4-HBA-Cr solubility behaviourpartially soluble in water, THF, methanol and DMF at 25 °C; completely soluble in DMF and methanol at 60 °C——Text
Qualitative		3 · Section 2.4

TGA-DTA/DTG using Perkin Elmer Diamond Thermal Analyzer

Calorimetry and thermal analysisThermogravimetric analysis

3,4-HBA monomer, pristine pressed pellet/solid · Pellet

20-1000 °C under N2 at 10 °C/min heating rate.

Temperature
293.15-1273.15
Atmosphere
N2
Geometry
thermal analysis pan/sample
Context
pristine monomer/polymer thermal stability
Measurement source
3,8 · Section 2.4; Section 3.5 · Table 3; Figs. 7-8
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
3,4-HBA DTA endothermic peak218——Table
Exact Reported		8 · Table 3 · Table 3
3,4-HBA DTA exothermic peak228——Table
Exact Reported		8 · Table 3 · Table 3
3,4-HBA temperature at 20% weight loss382——Table
Exact Reported		8 · Table 3 · Table 3
3,4-HBA carbon residue at 1000 °C53.7%——Table
Exact Reported		8 · Table 3 · Table 3
3,4-HBA TGA onset temperature218——Table
Exact Reported		8 · Table 3 · Table 3
3,4-HBA DTG maximum weight-loss temperature 1232——Table
Exact Reported		8 · Table 3 · Table 3
3,4-HBA DTG maximum weight-loss temperature 2302——Table
Exact Reported		8 · Table 3 · Table 3
3,4-HBA DTG maximum weight-loss temperature 3447——Table
Exact Reported		8 · Table 3 · Table 3

TGA-DTA/DTG using Perkin Elmer Diamond Thermal Analyzer

Calorimetry and thermal analysisThermogravimetric analysis

P-3,4-HBA-Cd pristine coordination-polymer solid/pellet · Pellet

20-1000 °C under N2 at 10 °C/min heating rate.

Temperature
293.15-1273.15
Atmosphere
N2
Geometry
thermal analysis pan/sample
Context
pristine monomer/polymer thermal stability
Measurement source
3,8 · Section 2.4; Section 3.5 · Table 3; Figs. 7-8
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
P-3,4-HBA-Cd temperature at 20% weight loss452——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Cd temperature at 50% weight loss633——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Cd carbon residue at 1000 °C30.54%——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Cd TGA onset temperature380——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Cd DTG maximum weight-loss temperature 1474——Table
Exact Reported		8 · Table 3 · Table 3

TGA-DTA/DTG using Perkin Elmer Diamond Thermal Analyzer

Calorimetry and thermal analysisThermogravimetric analysis

P-3,4-HBA-Co pristine coordination-polymer solid/pellet · Pellet

20-1000 °C under N2 at 10 °C/min heating rate.

Temperature
293.15-1273.15
Atmosphere
N2
Geometry
thermal analysis pan/sample
Context
pristine monomer/polymer thermal stability
Measurement source
3,8 · Section 2.4; Section 3.5 · Table 3; Figs. 7-8
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
P-3,4-HBA-Co temperature at 20% weight loss514——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Co temperature at 50% weight loss940——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Co carbon residue at 1000 °C48.81%——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Co TGA onset temperature437——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Co DTG maximum weight-loss temperature 1519——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Co DTG maximum weight-loss temperature 2734——Table
Exact Reported		8 · Table 3 · Table 3

TGA-DTA/DTG using Perkin Elmer Diamond Thermal Analyzer

Calorimetry and thermal analysisThermogravimetric analysis

P-3,4-HBA-Cr pristine coordination-polymer solid/pellet · Pellet

20-1000 °C under N2 at 10 °C/min heating rate.

Temperature
293.15-1273.15
Atmosphere
N2
Geometry
thermal analysis pan/sample
Context
pristine monomer/polymer thermal stability
Measurement source
3,8 · Section 2.4; Section 3.5 · Table 3; Figs. 7-8
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
P-3,4-HBA-Cr temperature at 20% weight loss400——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Cr carbon residue at 1000 °C52.01%——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Cr TGA onset temperature210——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Cr DTG maximum weight-loss temperature 1247——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Cr DTG maximum weight-loss temperature 2452——Table
Exact Reported		8 · Table 3 · Table 3

TGA-DTA/DTG using Perkin Elmer Diamond Thermal Analyzer

Calorimetry and thermal analysisThermogravimetric analysis

P-3,4-HBA-Cu pristine coordination-polymer solid/pellet · Pellet

20-1000 °C under N2 at 10 °C/min heating rate.

Temperature
293.15-1273.15
Atmosphere
N2
Geometry
thermal analysis pan/sample
Context
pristine monomer/polymer thermal stability
Measurement source
3,8 · Section 2.4; Section 3.5 · Table 3; Figs. 7-8
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
P-3,4-HBA-Cu temperature at 20% weight loss446——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Cu carbon residue at 1000 °C50.83%——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Cu TGA onset temperature153——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Cu DTG maximum weight-loss temperature 1174——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Cu DTG maximum weight-loss temperature 2336——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Cu DTG maximum weight-loss temperature 3439——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Cu DTG maximum weight-loss temperature 4550——Table
Exact Reported		8 · Table 3 · Table 3

TGA-DTA/DTG using Perkin Elmer Diamond Thermal Analyzer

Calorimetry and thermal analysisThermogravimetric analysis

P-3,4-HBA-Mn pristine coordination-polymer solid/pellet · Pellet

20-1000 °C under N2 at 10 °C/min heating rate.

Temperature
293.15-1273.15
Atmosphere
N2
Geometry
thermal analysis pan/sample
Context
pristine monomer/polymer thermal stability
Measurement source
3,8 · Section 2.4; Section 3.5 · Table 3; Figs. 7-8
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
P-3,4-HBA-Mn temperature at 20% weight loss531——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Mn temperature at 50% weight loss988——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Mn carbon residue at 1000 °C47.84%——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Mn TGA onset temperature364——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Mn DTG maximum weight-loss temperature 1348——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Mn DTG maximum weight-loss temperature 2480——Table
Exact Reported		8 · Table 3 · Table 3

TGA-DTA/DTG using Perkin Elmer Diamond Thermal Analyzer

Calorimetry and thermal analysisThermogravimetric analysis

P-3,4-HBA-Ni pristine coordination-polymer solid/pellet · Pellet

20-1000 °C under N2 at 10 °C/min heating rate.

Temperature
293.15-1273.15
Atmosphere
N2
Geometry
thermal analysis pan/sample
Context
pristine monomer/polymer thermal stability
Measurement source
3,8 · Section 2.4; Section 3.5 · Table 3; Figs. 7-8
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
P-3,4-HBA-Ni temperature at 20% weight loss446——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Ni temperature at 50% weight loss755——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Ni carbon residue at 1000 °C37.9%——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Ni TGA onset temperature351——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Ni DTG maximum weight-loss temperature 1398——Table
Exact Reported		8 · Table 3 · Table 3

TGA-DTA/DTG using Perkin Elmer Diamond Thermal Analyzer

Calorimetry and thermal analysisThermogravimetric analysis

P-3,4-HBA-Pb pristine coordination-polymer solid/pellet · Pellet

20-1000 °C under N2 at 10 °C/min heating rate.

Temperature
293.15-1273.15
Atmosphere
N2
Geometry
thermal analysis pan/sample
Context
pristine monomer/polymer thermal stability
Measurement source
3,8 · Section 2.4; Section 3.5 · Table 3; Figs. 7-8
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
P-3,4-HBA-Pb temperature at 20% weight loss687——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Pb carbon residue at 1000 °C54.85%——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Pb TGA onset temperature387——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Pb DTG maximum weight-loss temperature 1441——Table
Exact Reported		8 · Table 3 · Table 3

TGA-DTA/DTG using Perkin Elmer Diamond Thermal Analyzer

Calorimetry and thermal analysisThermogravimetric analysis

P-3,4-HBA-Zn pristine coordination-polymer solid/pellet · Pellet

20-1000 °C under N2 at 10 °C/min heating rate.

Temperature
293.15-1273.15
Atmosphere
N2
Geometry
thermal analysis pan/sample
Context
pristine monomer/polymer thermal stability
Measurement source
3,8 · Section 2.4; Section 3.5 · Table 3; Figs. 7-8
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
P-3,4-HBA-Zn temperature at 20% weight loss668——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Zn temperature at 50% weight loss887——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Zn carbon residue at 1000 °C44.1%——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Zn TGA onset temperature477——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Zn DTG maximum weight-loss temperature 1493——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Zn DTG maximum weight-loss temperature 2869——Table
Exact Reported		8 · Table 3 · Table 3

TGA-DTA/DTG using Perkin Elmer Diamond Thermal Analyzer

Calorimetry and thermal analysisThermogravimetric analysis

P-3,4-HBA-Zr pristine coordination-polymer solid/pellet · Pellet

20-1000 °C under N2 at 10 °C/min heating rate.

Temperature
293.15-1273.15
Atmosphere
N2
Geometry
thermal analysis pan/sample
Context
pristine monomer/polymer thermal stability
Measurement source
3,8 · Section 2.4; Section 3.5 · Table 3; Figs. 7-8
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
P-3,4-HBA-Zr temperature at 20% weight loss507——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Zr carbon residue at 1000 °CMarked as a best value within this paper62.76%——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Zr TGA onset temperature367——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Zr DTG maximum weight-loss temperature 1229——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Zr DTG maximum weight-loss temperature 2423——Table
Exact Reported		8 · Table 3 · Table 3
P-3,4-HBA-Zr DTG maximum weight-loss temperature 3850——Table
Exact Reported		8 · Table 3 · Table 3