Spectroscopy — Efficient and tunable one-dimensional charge transport in layered lanthanide metal–organic frameworks

4 measurement groups · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

HoHHTP powder · Powder

Diffuse reflectance spectra from 350-3000 nm stitched with DRIFTS; Tauc plots for direct allowed transitions.

Temperature: ambient
Atmosphere: ambient
Geometry: KBr-diluted powder diffuse reflectance
Context: pristine LnHHTP powder
Measurement source: SI p.5 · Optical spectroscopy · Supplementary Figs. 24-29

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
direct-allowed Tauc optical bandgap	0.76 eV (visual estimate from Fig. 3b inset)	—	—	Figure Axis Approximate	main p.133 · Optical spectroscopy · Fig. 3b
sub-edge defect absorption feature for Ho/Yb	~0.7 eV for Ho and Yb	—	—	Text Approximate	main p.133 · Optical spectroscopy · Fig. 3a

LaHHTP powder · Powder

Diffuse reflectance spectra from 350-3000 nm stitched with DRIFTS; Tauc plots for direct allowed transitions.

Temperature: ambient
Atmosphere: ambient
Geometry: KBr-diluted powder diffuse reflectance
Context: pristine LnHHTP powder
Measurement source: SI p.5 · Optical spectroscopy · Supplementary Figs. 24-29

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
sub-edge defect absorption feature for La/Nd	~0.3 eV for La and Nd	—	—	Text Approximate	main p.133 · Optical spectroscopy · Fig. 3a
direct-allowed Tauc optical bandgap	0.85 eV	—	—	Text Exact Reported	main p.133 · Optical spectroscopy · Fig. 3b

NdHHTP powder · Powder

Diffuse reflectance spectra from 350-3000 nm stitched with DRIFTS; Tauc plots for direct allowed transitions.

Temperature: ambient
Atmosphere: ambient
Geometry: KBr-diluted powder diffuse reflectance
Context: pristine LnHHTP powder
Measurement source: SI p.5 · Optical spectroscopy · Supplementary Figs. 24-29

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
direct-allowed Tauc optical bandgap	0.81 eV (visual estimate from Fig. 3b inset)	—	—	Figure Axis Approximate	main p.133 · Optical spectroscopy · Fig. 3b

YbHHTP powder · Powder

Diffuse reflectance spectra from 350-3000 nm stitched with DRIFTS; Tauc plots for direct allowed transitions.

Temperature: ambient
Atmosphere: ambient
Geometry: KBr-diluted powder diffuse reflectance
Context: pristine LnHHTP powder
Measurement source: SI p.5 · Optical spectroscopy · Supplementary Figs. 24-29

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
direct-allowed Tauc optical bandgapMarked as a best value within this paper	0.73 eV	—	—	Text Exact Reported	main p.133 · Optical spectroscopy · Fig. 3b