Spectroscopy — Heterometallic Actinide-Containing Photoresponsive Metal-Organic Frameworks: Dynamic and Static Tuning of Electronic Properties

6 measurement groups · 8 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Th-34% · Powder

Diffuse reflectance spectra; direct allowed transition assumption; dark and after 1 min UV irradiation at 365 nm.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Optical attenuation rate for Th-34% merocyanine-to-spiropyran conversion	3.9 x 10^-1 s^-1	—	—	Text Rounded Reported	8077 · Results and Discussion · Figures 3b and S31

Th5U-50% · Powder

Diffuse reflectance spectra; direct allowed transition assumption; dark and after 1 min UV irradiation at 365 nm.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Th5U-50% optical band gap under UV	2.04 eV	—	—	SI Table Exact Reported	S31 · Table S2 · Table S2

Th-65% · Powder

Diffuse reflectance spectra; direct allowed transition assumption; dark and after 1 min UV irradiation at 365 nm.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Th-65% optical band gap, dark	2.08 eV	—	—	SI Table Exact Reported	S31 · Table S2 · Table S2
Th-65% optical band gap under UV	2.04 eV	—	—	SI Table Exact Reported	S31 · Table S2 · Table S2

Zr-33% · Powder

Diffuse reflectance spectra; direct allowed transition assumption; dark and after 1 min UV irradiation at 365 nm.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Optical attenuation rate for Zr-33% spiropyran moiety	1.53 x 10^-1 s^-1	—	—	Text Rounded Reported	8077 · Results and Discussion · Figures 3b and S31
Zr-33% optical band gap under UV	2.11 eV	—	—	SI Table Exact Reported	S31 · Table S2 · Table S2

Zr-65% · Powder

Diffuse reflectance spectra; direct allowed transition assumption; dark and after 1 min UV irradiation at 365 nm.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Zr-65% optical band gap under UV	2.11 eV	—	—	SI Table Exact Reported	S31 · Table S2 · Table S2

Zr-MOF powder · Powder

Diffuse reflectance spectra; direct allowed transition assumption; dark and after 1 min UV irradiation at 365 nm.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Zr-MOF optical band gap, dark	3.35 eV	—	—	SI Table Exact Reported	S31 · Table S2 · Table S2