Measurement evidence
MOF-74(M) Films Obtained through Vapor-Assisted Conversion - Impact on Crystal Orientation and Optical Properties · Scheurle P.I., Mahringer A., Biewald A. et al. · Chemistry of Materials · 2021 · 5896-5904
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
MOF-74(Mg) thin film on gold, oriented · Thin Film
MOF-74(Mg) film recorded at emission maximum 487 nm with 378 nm excitation.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| MOF-74(Mg) short PL lifetime tau1 | 20 ps | — | — | Text Exact Reported | 5902 · Optical Properties of the MOF-74(M) Films · Figure 6F |
| MOF-74(Mg) long PL lifetime tau2 | 168 ps | — | — | Text Exact Reported | 5902 · Optical Properties of the MOF-74(M) Films · Figure 6F |
MOF-74(Zn) thin film on gold · Thin Film
MOF-74(Zn) film recorded at emission maximum 476 nm with 378 nm excitation.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Short lifetime channel fractional contribution | 89% | 0.89 fraction | — | Text Exact Reported | 5902 · Optical Properties of the MOF-74(M) Films · Figure 6E-F |
| MOF-74(Zn) short PL lifetime tau1 | 19 ps | — | — | Text Exact Reported | 5902 · Optical Properties of the MOF-74(M) Films · Figure 6E |
| MOF-74(Zn) long PL lifetime tau2 | 161 ps | — | — | Text Exact Reported | 5902 · Optical Properties of the MOF-74(M) Films · Figure 6E |
MOF-74(Co) thin film on quartz · Thin Film
MOF-74(Co) film on quartz; UV-vis and PL with 378 nm excitation.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| MOF-74(Co) absorption maximum | 398 nm | — | — | Text Exact Reported | 5901-5902 · Optical Properties of the MOF-74(M) Films · Figure S35 |
MOF-74(Mg) thin film on quartz · Thin Film
MOF-74(Mg) film on quartz; UV-vis in transmission; PL with 378 nm excitation.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| MOF-74(Mg) absorption maximum | 393 nm | — | — | Text Exact Reported | 5901-5902 · Optical Properties of the MOF-74(M) Films · Figure 6D |
| MOF-74(Mg) PL emission maximum | 487 nm | — | — | Text Exact Reported | 5902 · Optical Properties of the MOF-74(M) Films · Figure 6D |
MOF-74(Ni) thin film on quartz · Thin Film
MOF-74(Ni) film on quartz; UV-vis and PL with 378 nm excitation.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| MOF-74(Ni) absorption maximum | 396 nm | — | — | Text Exact Reported | 5901-5902 · Optical Properties of the MOF-74(M) Films · Figure S35 |
| MOF-74(Ni/Co) weaker second emission band | 690 nm | — | — | Text Rounded Reported | 5902 · Optical Properties of the MOF-74(M) Films · Figure S38 |
MOF-74(Zn) thin film on quartz · Thin Film
MOF-74(Zn) film on quartz; UV-vis in transmission; PL with 378 nm excitation.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Optical band gaps for examined MOF-74(M) films | about 2.8 eV for all examined MOFs | — | — | Text Approximate | 5901 · Optical Properties of the MOF-74(M) Films · Figure S36 |
| MOF-74(Zn) absorption maximum | 406 nm | — | — | Text Exact Reported | 5901-5902 · Optical Properties of the MOF-74(M) Films · Figure 6C |
| MOF-74(Zn) absorption onset | between 458 and 453 nm | — | — | Text Range | 5901 · Optical Properties of the MOF-74(M) Films · Figure 6C-D |
| MOF-74(Zn) PL emission maximum | 476 nm | — | — | Text Exact Reported | 5902 · Optical Properties of the MOF-74(M) Films · Figure 6C |