Microscopy Morphology — MOF-74(M) Films Obtained through Vapor-Assisted Conversion - Impact on Crystal Orientation and Optical Properties

4 measurement groups · 22 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

MOF-74(Co) thin film on gold · Thin Film

MOF-74(Co) film on gold grown from CoCl2.6H2O/DMF-H2O route.

Geometry: thin film on gold substrate
Context: pristine MOF-74(Co) film
Measurement source: 5900 · Highly Crystalline MOF-74(Co) and MOF-74(Ni) Films · Figure 4C

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
MOF-74(Co) on gold crystallite length	average 380 nm length	—	—	Text Rounded Reported	5900 · Highly Crystalline MOF-74(Co) and MOF-74(Ni) Films · Figure 4C
MOF-74(Co) on gold crystallite width	average 130 nm width	—	—	Text Rounded Reported	5900 · Highly Crystalline MOF-74(Co) and MOF-74(Ni) Films · Figure 4C

MOF-74(Mg) thin film on gold, oriented · Thin Film

Oriented MOF-74(Mg) film on gold.

Geometry: thin film on gold substrate
Context: pristine MOF-74(Mg) film
Measurement source: 5900 · Highly Crystalline and Oriented MOF-74(Mg) Films · Figures 3C, S17-S19

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
MOF-74(Mg) oriented gold AFM RMS Sq, 1 um x 1 um	35 nm	—	—	Caption Exact Reported	18 · Additional characterization of MOF-74(Mg) films · Figure S19
MOF-74(Mg) oriented gold AFM RMS Sq, 5 um x 5 um	54 nm	—	—	Caption Exact Reported	18 · Additional characterization of MOF-74(Mg) films · Figure S19
MOF-74(Mg) on glass rod length	800 nm	—	—	Text Rounded Reported	5899 · Highly Crystalline and Oriented MOF-74(Mg) Films · Figures 3D and S14
MOF-74(Mg) on glass rod width	about 170 nm	—	—	Text Approximate	5899 · Highly Crystalline and Oriented MOF-74(Mg) Films · Figures 3D and S14
MOF-74(Mg) oriented gold bundle length	3 um	3000 nm	—	Text Rounded Reported	5900 · Highly Crystalline and Oriented MOF-74(Mg) Films · Figures 3C and S18
MOF-74(Mg) oriented gold bundle width	about 400 nm	—	—	Text Approximate	5900 · Highly Crystalline and Oriented MOF-74(Mg) Films · Figures 3C and S18
MOF-74(Mg) oriented gold film thicknessMarked as a best value within this paper	about 3 um	3000 nm	—	Text Approximate	5900 · Highly Crystalline and Oriented MOF-74(Mg) Films · Figure S18
MOF-74(Mg) TEM lattice fringe spacing	1.3 nm	—	—	Text Rounded Reported	5900 · Highly Crystalline and Oriented MOF-74(Mg) Films · Figure S17

MOF-74(Ni) thin film on glass · Thin Film

MOF-74(Ni) film on glass.

Geometry: thin film on glass substrate
Context: pristine MOF-74(Ni) film
Measurement source: 5900 · Highly Crystalline MOF-74(Co) and MOF-74(Ni) Films · Figure 4D and Figure S32

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
MOF-74(Ni) on glass AFM RMS Sq	18.5 nm	—	—	Caption Exact Reported	23 · Additional characterization of MOF-74(Ni) films · Figure S32
MOF-74(Ni) crystallite diameter	around 50 nm	—	—	Text Approximate	5900 · Highly Crystalline MOF-74(Co) and MOF-74(Ni) Films · Figures 4D, S30, S31
MOF-74(Ni) glass film thickness	about 250 nm	—	—	Text Approximate	5900 · Highly Crystalline MOF-74(Co) and MOF-74(Ni) Films · Figure 4D

MOF-74(Zn) thin film on gold · Thin Film

MOF-74(Zn) films on gold, glass and silicon; AFM 5 um x 5 um and 1 um x 1 um scans in SI.

Geometry: thin film on substrate
Context: pristine MOF-74(Zn) films
Measurement source: 5898 · Highly Crystalline and Oriented MOF-74(Zn) Films · Figures 2, S6-S8

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
MOF-74(Zn) on glass AFM RMS Sq	33.6 nm	—	—	Caption Exact Reported	13 · Additional characterization of MOF-74(Zn) films · Figure S6
MOF-74(Zn) on gold AFM RMS Sq, 1 um x 1 umMarked as a best value within this paper	5.3 nm	—	—	Caption Exact Reported	13 · Additional characterization of MOF-74(Zn) films · Figure S7
MOF-74(Zn) on gold AFM RMS Sq, 5 um x 5 um	11.5 nm	—	—	Caption Exact Reported	13 · Additional characterization of MOF-74(Zn) films · Figure S6
MOF-74(Zn) on silicon AFM RMS Sq	33.1 nm	—	—	Caption Exact Reported	14 · Additional characterization of MOF-74(Zn) films · Figure S8
MOF-74(Zn) rod crystallite average length	length of 700 nm	—	—	Text Rounded Reported	5898 · Highly Crystalline and Oriented MOF-74(Zn) Films · Figure 2D-F
MOF-74(Zn) rod crystallite average width	average width of 150 nm	—	—	Text Rounded Reported	5898 · Highly Crystalline and Oriented MOF-74(Zn) Films · Figure 2D-F
MOF-74(Zn) film thickness range	350-650 nm	—	—	Text Range	5898 · Highly Crystalline and Oriented MOF-74(Zn) Films · Figure 2
MOF-74(Zn) on glass crystallite length range	650-700 nm	—	—	Text Range	5898 · Highly Crystalline and Oriented MOF-74(Zn) Films · Figure 2E
MOF-74(Zn) on glass crystallite width	defined width of 200 nm	—	—	Text Rounded Reported	5898 · Highly Crystalline and Oriented MOF-74(Zn) Films · Figure 2E