cMOF Evidence Base

Synthesis evidence

MOF-74(M) Films Obtained through Vapor-Assisted Conversion - Impact on Crystal Orientation and Optical Properties

Scheurle P.I., Mahringer A., Biewald A. et al. · Chemistry of Materials · 2021 · 5896-5904

22 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Complete recipeSource: SI

Route 1: Solvothermal

10 · MOF-74 bulk material synthesis

Metal precursorsCo(NO3)2.6H2O, 2.377 g, 8.67 mmol
Linker precursors2,5-dihydroxy-1,4-benzenedicarboxylic acid, 0.482 g, 2.43 mmol
SolventsDMF/ethanol/water, 1:1:1 (666 uL : 666 uL : 666 uL), total 200 mL
Atmospherenot specified; handled in air unless otherwise noted
Temperature100
Time24
Work-upprecipitate washed with DMF (2 x 10 mL) and methanol (1 x 10 mL), dried under reduced pressure
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Linker2,5-dihydroxy-1,4-benzenedicarboxylic acid0.482 g; 2.43 mmol10 · MOF-74 bulk material synthesis
Metal SourceCo(NO3)2.6H2O2.377 g; 8.67 mmol10 · MOF-74 bulk material synthesis
SolventDMF/ethanol/water1:1:1 mixture; total 200 mL10 · MOF-74 bulk material synthesis
Complete recipeSource: SI

Route 2: Solvothermal

10 · MOF-74 bulk material synthesis

Metal precursorsMg(NO3)2.6H2O, 0.475 mg, 1.85 mmol as extracted
Linker precursors2,5-dihydroxy-1,4-benzenedicarboxylic acid, 0.111 g, 0.559 mmol
SolventsDMF/ethanol/water, 15:1:1 (44.1 mL : 295 uL : 295 uL), total 50 mL
Atmospherenot specified; handled in air unless otherwise noted
Temperature125
Time24
Work-upprecipitate washed with DMF (2 x 10 mL) and methanol (1 x 10 mL), dried under reduced pressure
Activationfor krypton sorption: degassed/activated under high vacuum at 120 deg C for at least 12 h
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Linker2,5-dihydroxy-1,4-benzenedicarboxylic acid0.111 g; 0.559 mmol10 · MOF-74 bulk material synthesis
Metal SourceMg(NO3)2.6H2O0.475 mg; 1.85 mmol10 · MOF-74 bulk material synthesis
SolventDMF/ethanol/water44.1 mL / 295 uL / 295 uL10 · MOF-74 bulk material synthesis
Complete recipeSource: SI

Route 3: Solvothermal

10 · MOF-74 bulk material synthesis

Metal precursorsNi(NO3)2.6H2O, 2.378 mg, 8.178 mmol as extracted
Linker precursors2,5-dihydroxy-1,4-benzenedicarboxylic acid, 0.478 g, 2.41 mmol
SolventsDMF/ethanol/water, 1:1:1 (666 uL : 666 uL : 666 uL), total 200 mL
Atmospherenot specified; handled in air unless otherwise noted
Temperature100
Time24
Work-upprecipitate washed with DMF (2 x 10 mL) and methanol (1 x 10 mL), dried under reduced pressure
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Linker2,5-dihydroxy-1,4-benzenedicarboxylic acid0.478 g; 2.41 mmol10 · MOF-74 bulk material synthesis
Metal SourceNi(NO3)2.6H2O2.378 mg; 8.178 mmol10 · MOF-74 bulk material synthesis
SolventDMF/ethanol/water1:1:1 mixture; total 200 mL10 · MOF-74 bulk material synthesis
Complete recipeSource: SI

Route 4: Solvothermal

10 · MOF-74 bulk material synthesis

Metal precursorszinc nitrate tetrahydrate, Zn(NO3)2.4H2O, 0.053 mg, 0.203 mmol as extracted
Linker precursors2,5-dihydroxy-1,4-benzenedicarboxylic acid, 0.019 g, 0.096 mmol
SolventsDMF 2 mL, 2-propanol 0.1 mL, water 0.1 mL
Atmospherenot specified; handled in air unless otherwise noted
Temperature105
Time24
Work-upprecipitate washed with DMF (2 x 10 mL) and ethanol (1 x 10 mL), dried under reduced pressure
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Linker2,5-dihydroxy-1,4-benzenedicarboxylic acid0.019 g; 0.096 mmol10 · MOF-74 bulk material synthesis
Metal SourceZn(NO3)2.4H2O0.053 mg; 0.203 mmol10 · MOF-74 bulk material synthesis
SolventDMF / 2-propanol / water2 mL / 0.1 mL / 0.1 mL10 · MOF-74 bulk material synthesis
Complete recipeSource: Both

Route 5: Other

9 · Experimental; Table S7 · Table S7

Metal precursorsCo(OAc)2, 2.39 mg, 9.6 mmol as extracted
Linker precursors2,5-dihydroxyterephthalic acid, 0.95 mg, 4.8 mmol as extracted
SolventsDMF precursor, 2.2 mL; DMF vapour source, 5 mL
Atmospherehandled in air unless otherwise noted; closed glass bottle during VAC
Temperature100
Time18
Substrate orientationglass substrate
Work-upcool to room temperature; substrate removed and dried under reduced pressure
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Linker2,5-dihydroxyterephthalic acid0.95 mg; 4.8 mmol9 · Experimental; Table S7 · Table S7
Metal SourceCo(OAc)22.39 mg; 9.6 mmol9 · Experimental; Table S7 · Table S7
SolventDMF2.2 mL precursor; 5 mL vapour source9 · Experimental; Table S7 · Table S7
Complete recipeSource: Both

Route 6: Other

9 · Experimental; Table S7 · Table S7

Metal precursorsCoCl2.6H2O, 2.28 mg, 9.6 mmol as extracted
Linker precursors2,5-dihydroxyterephthalic acid, 0.95 mg, 4.8 mmol as extracted
SolventsDMF 2.1 mL and H2O 0.1 mL precursor; DMF/H2O vapour source 5 mL (1:0.044)
Atmospherehandled in air unless otherwise noted; closed glass bottle during VAC
Temperature100
Time18
Substrate orientationgold substrate
Work-upcool to room temperature; substrate removed and dried under reduced pressure
Activationfor sorption: high vacuum at 120 deg C for at least 12 h
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Linker2,5-dihydroxyterephthalic acid0.95 mg; 4.8 mmol9 · Experimental; Table S7 · Table S7
Metal SourceCoCl2.6H2O2.28 mg; 9.6 mmol9 · Experimental; Table S7 · Table S7
SolventDMF/H2O2.1 mL / 0.1 mL precursor; 5 mL vapour source9 · Experimental; Table S7 · Table S7
Complete recipeSource: SI

Route 7: Other

9 · Experimental; Table S7 · Table S7

Metal precursorsCo(OAc)2, 2.39 mg, 9.6 mmol as extracted
Linker precursors2,5-dihydroxyterephthalic acid, 0.95 mg, 4.8 mmol as extracted
SolventsDMF precursor, 2.2 mL; DMF vapour source, 5 mL
Atmospherehandled in air unless otherwise noted; closed glass bottle during VAC
Temperature100
Time18
Substrate orientationquartz substrate
Work-upcool to room temperature; substrate removed and dried under reduced pressure
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Linker2,5-dihydroxyterephthalic acid0.95 mg; 4.8 mmol9 · Experimental; Table S7 · Table S7
Metal SourceCo(OAc)22.39 mg; 9.6 mmol9 · Experimental; Table S7 · Table S7
SolventDMF2.2 mL precursor; 5 mL vapour source9 · Experimental; Table S7 · Table S7
Complete recipeSource: Both

Route 8: Other

9 · Experimental; Table S7 · Table S7

Metal precursorsCo(OAc)2, 2.39 mg, 9.6 mmol as extracted
Linker precursors2,5-dihydroxyterephthalic acid, 0.95 mg, 4.8 mmol as extracted
SolventsDMF 0.73 mL, EtOH 0.73 mL, H2O 0.73 mL precursor; DMF/EtOH/H2O vapour source 5 mL (1:1:1)
Atmospherehandled in air unless otherwise noted; closed glass bottle during VAC
Temperature110
Time18
Substrate orientationsilicon substrate
Work-upcool to room temperature; substrate removed and dried under reduced pressure
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Linker2,5-dihydroxyterephthalic acid0.95 mg; 4.8 mmol9 · Experimental; Table S7 · Table S7
Metal SourceCo(OAc)22.39 mg; 9.6 mmol9 · Experimental; Table S7 · Table S7
SolventDMF/EtOH/H2O0.73 mL / 0.73 mL / 0.73 mL9 · Experimental; Table S7 · Table S7
Complete recipeSource: Both

Route 9: Other

8 · Experimental; Table S4 · Table S4

Metal precursorsMg(NO3)2.6H2O, 2.45 mg, 9.6 mmol as extracted
Linker precursors2,5-dihydroxyterephthalic acid, 0.95 mg, 4.8 mmol as extracted
SolventsDMF precursor solution, 2.2 mL; DMF vapour source, 5 mL
Additivesbenzoic acid solution, 50 uL
Atmospherehandled in air unless otherwise noted; closed glass bottle during VAC
Temperature100
Time18
Substrate orientationglass substrate
Work-upcool to room temperature; substrate removed and dried under reduced pressure
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Linker2,5-dihydroxyterephthalic acid0.95 mg; 4.8 mmol8 · Experimental; Table S4 · Table S4
Metal SourceMg(NO3)2.6H2O2.45 mg; 9.6 mmol8 · Experimental; Table S4 · Table S4
Acidbenzoic acid50 uL8 · Experimental; Table S4 · Table S4
SolventDMF2.2 mL precursor; 5 mL vapour source8 · Experimental; Table S4 · Table S4
Complete recipeSource: Both

Route 10: Other

8 · Experimental; Table S4 · Table S4

Metal precursorsMg(NO3)2.6H2O, 2.45 mg, 9.6 mmol as extracted
Linker precursors2,5-dihydroxyterephthalic acid, 0.95 mg, 4.8 mmol as extracted
SolventsDMF 1.6 mL and EtOH 0.6 mL precursor; DMF/EtOH vapour source 5 mL (1:0.28)
Atmospherehandled in air unless otherwise noted; closed glass bottle during VAC
Temperature100
Time18
Substrate orientationgold substrate
Work-upcool to room temperature; substrate removed and dried under reduced pressure
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Linker2,5-dihydroxyterephthalic acid0.95 mg; 4.8 mmol8 · Experimental; Table S4 · Table S4
Metal SourceMg(NO3)2.6H2O2.45 mg; 9.6 mmol8 · Experimental; Table S4 · Table S4
SolventDMF1.6 mL precursor8 · Experimental; Table S4 · Table S4
SolventEtOH0.6 mL precursor8 · Experimental; Table S4 · Table S4
Complete recipeSource: Both

Route 11: Other

8 · Experimental; Table S5 · Table S5

Metal precursorsMg(NO3)2.6H2O, 4.9 mg, 19.2 mmol as extracted
Linker precursors2,5-dihydroxyterephthalic acid, 1.9 mg, 9.6 mmol as extracted
SolventsDMF 1.94 mL, EtOH 0.13 mL, H2O 0.13 mL precursor; 5 mL DMF/EtOH/H2O vapour source (1:0.06:0.06)
Additivesbenzoic acid solution, 75 uL
Atmospherehandled in air unless otherwise noted; closed glass bottle during VAC
Temperature100
Time28
Substrate orientationgold substrate
Work-upcool to room temperature; substrate removed and dried under reduced pressure
Activationfor sorption: high vacuum at 120 deg C for at least 12 h
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Linker2,5-dihydroxyterephthalic acid1.9 mg; 9.6 mmol8 · Experimental; Table S5 · Table S5
Metal SourceMg(NO3)2.6H2O4.9 mg; 19.2 mmol8 · Experimental; Table S5 · Table S5
Acidbenzoic acid75 uL8 · Experimental; Table S5 · Table S5
SolventDMF/EtOH/H2O1.94 mL / 0.13 mL / 0.13 mL precursor; 5 mL vapour source8 · Experimental; Table S5 · Table S5
Complete recipeSource: Both

Route 12: Other

8 · Experimental; Table S4 · Table S4

Metal precursorsMg(NO3)2.6H2O, 2.45 mg, 9.6 mmol as extracted
Linker precursors2,5-dihydroxyterephthalic acid, 0.95 mg, 4.8 mmol as extracted
SolventsDMF precursor solution, 2.2 mL; DMF vapour source, 5 mL
Additivesbenzoic acid solution, 50 uL
Atmospherehandled in air unless otherwise noted; closed glass bottle during VAC
Temperature100
Time18
Substrate orientationquartz substrate
Work-upcool to room temperature; substrate removed and dried under reduced pressure
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Linker2,5-dihydroxyterephthalic acid0.95 mg; 4.8 mmol8 · Experimental; Table S4 · Table S4
Metal SourceMg(NO3)2.6H2O2.45 mg; 9.6 mmol8 · Experimental; Table S4 · Table S4
Acidbenzoic acid50 uL8 · Experimental; Table S4 · Table S4
SolventDMF2.2 mL precursor; 5 mL vapour source8 · Experimental; Table S4 · Table S4
Complete recipeSource: SI

Route 13: Other

8 · Experimental; Table S4 · Table S4

Metal precursorsMg(NO3)2.6H2O, 2.45 mg, 9.6 mmol as extracted
Linker precursors2,5-dihydroxyterephthalic acid, 0.95 mg, 4.8 mmol as extracted
SolventsDMF precursor solution, 2.2 mL; DMF vapour source, 5 mL
Additivesbenzoic acid solution, 50 uL
Atmospherehandled in air unless otherwise noted; closed glass bottle during VAC
Temperature100
Time18
Substrate orientationsilicon substrate
Work-upcool to room temperature; substrate removed and dried under reduced pressure
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Linker2,5-dihydroxyterephthalic acid0.95 mg; 4.8 mmol8 · Experimental; Table S4 · Table S4
Metal SourceMg(NO3)2.6H2O2.45 mg; 9.6 mmol8 · Experimental; Table S4 · Table S4
Acidbenzoic acid50 uL8 · Experimental; Table S4 · Table S4
SolventDMF2.2 mL precursor; 5 mL vapour source8 · Experimental; Table S4 · Table S4
Complete recipeSource: Both

Route 14: Other

8 · Experimental; Table S6 · Table S6

Metal precursorsNi(NO3)2.4H2O, 2.79 mg, 9.6 mmol as extracted
Linker precursors2,5-dihydroxyterephthalic acid, 0.95 mg, 4.8 mmol as extracted
SolventsDMF 2.0 mL, EtOH 0.1 mL, H2O 0.1 mL precursor; DMF/EtOH/H2O vapour source 5 mL (1:0.04:0.04)
Atmospherehandled in air unless otherwise noted; closed glass bottle during VAC
Temperature100
Time18
Substrate orientationglass substrate
Work-upcool to room temperature; substrate removed and dried under reduced pressure
Activationfor sorption: high vacuum at 120 deg C for at least 12 h
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Linker2,5-dihydroxyterephthalic acid0.95 mg; 4.8 mmol8 · Experimental; Table S6 · Table S6
Metal SourceNi(NO3)2.4H2O2.79 mg; 9.6 mmol8 · Experimental; Table S6 · Table S6
SolventDMF/EtOH/H2O2.0 mL / 0.1 mL / 0.1 mL precursor; 5 mL vapour source8 · Experimental; Table S6 · Table S6
Complete recipeSource: Both

Route 15: Other

9 · Experimental; Table S6 · Table S6

Metal precursorsNiCl2.6H2O, 2.28 mg, 9.6 mmol as extracted
Linker precursors2,5-dihydroxyterephthalic acid, 0.95 mg, 4.8 mmol as extracted
SolventsDMF precursor, 2.2 mL; DMF vapour source, 5 mL
Atmospherehandled in air unless otherwise noted; closed glass bottle during VAC
Temperature110
Time18
Substrate orientationgold substrate
Work-upcool to room temperature; substrate removed and dried under reduced pressure
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Linker2,5-dihydroxyterephthalic acid0.95 mg; 4.8 mmol9 · Experimental; Table S6 · Table S6
Metal SourceNiCl2.6H2O2.28 mg; 9.6 mmol9 · Experimental; Table S6 · Table S6
SolventDMF2.2 mL precursor; 5 mL vapour source9 · Experimental; Table S6 · Table S6
Complete recipeSource: SI

Route 16: Other

8 · Experimental; Table S6 · Table S6

Metal precursorsNi(NO3)2.4H2O, 2.79 mg, 9.6 mmol as extracted
Linker precursors2,5-dihydroxyterephthalic acid, 0.95 mg, 4.8 mmol as extracted
SolventsDMF 2.0 mL, EtOH 0.1 mL, H2O 0.1 mL precursor; DMF/EtOH/H2O vapour source 5 mL (1:0.04:0.04)
Atmospherehandled in air unless otherwise noted; closed glass bottle during VAC
Temperature100
Time18
Substrate orientationquartz substrate
Work-upcool to room temperature; substrate removed and dried under reduced pressure
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Linker2,5-dihydroxyterephthalic acid0.95 mg; 4.8 mmol8 · Experimental; Table S6 · Table S6
Metal SourceNi(NO3)2.4H2O2.79 mg; 9.6 mmol8 · Experimental; Table S6 · Table S6
SolventDMF/EtOH/H2O2.0 mL / 0.1 mL / 0.1 mL8 · Experimental; Table S6 · Table S6
Complete recipeSource: SI

Route 17: Other

8 · Experimental; Table S6 · Table S6

Metal precursorsNi(NO3)2.4H2O, 2.79 mg, 9.6 mmol as extracted
Linker precursors2,5-dihydroxyterephthalic acid, 0.95 mg, 4.8 mmol as extracted
SolventsDMF 0.73 mL, EtOH 0.73 mL, H2O 0.73 mL precursor; DMF/EtOH/H2O vapour source 5 mL (1:1:1)
Atmospherehandled in air unless otherwise noted; closed glass bottle during VAC
Temperature100
Time18
Substrate orientationsilicon substrate
Work-upcool to room temperature; substrate removed and dried under reduced pressure
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Linker2,5-dihydroxyterephthalic acid0.95 mg; 4.8 mmol8 · Experimental; Table S6 · Table S6
Metal SourceNi(NO3)2.4H2O2.79 mg; 9.6 mmol8 · Experimental; Table S6 · Table S6
SolventDMF/EtOH/H2O0.73 mL / 0.73 mL / 0.73 mL8 · Experimental; Table S6 · Table S6
Complete recipeSource: Both

Route 18: Other

7 · Experimental; Table S2 · Table S2

Metal precursorsZn(OAc)2, 1.76 mg, 9.6 mmol as extracted
Linker precursors2,5-dihydroxyterephthalic acid, 0.95 mg, 4.8 mmol as extracted
SolventsDMF precursor solution, 2.2 mL; DMF vapour source, 5 mL
Additivesbenzoic acid solution, 100 uL; benzoic acid stock: 1.02 mmol, 124 mg in DMF 2 mL
Atmospherehandled in air unless otherwise noted; closed glass bottle during VAC
Temperature100
Time18
Substrate orientationglass substrate, 1.2 cm x 1 cm
Work-upcool to room temperature; substrate removed and dried under reduced pressure
Activationnot part of synthesis; sorption samples activated under high vacuum at 120 deg C for at least 12 h
Scalability contextSubstrate pieces were 1.2 cm x 1 cm; total sorption film area was 30 cm2 for selected films.
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Linker2,5-dihydroxyterephthalic acid0.95 mg; 4.8 mmol7 · Experimental; Table S2 · Table S2
Metal SourceZn(OAc)21.76 mg; 9.6 mmol7 · Experimental; Table S2 · Table S2
Acidbenzoic acid100 uL of stock · 1.02 mmol; 124 mg in DMF (2 mL)7 · Experimental; Table S2 · Table S2
SolventDMF2.2 mL precursor; 5 mL vapour source7 · Experimental; Table S2 · Table S2
Complete recipeSource: Both

Route 19: Other

7 · Experimental; Table S2 · Table S2

Metal precursorsZn(OAc)2, 1.76 mg, 9.6 mmol as extracted
Linker precursors2,5-dihydroxyterephthalic acid, 0.95 mg, 4.8 mmol as extracted
SolventsDMF precursor solution, 2.2 mL; DMF vapour source, 5 mL
Additivesbenzoic acid solution, 50 uL
Atmospherehandled in air unless otherwise noted; closed glass bottle during VAC
Temperature100
Time18
Substrate orientationgold substrate (10 nm Ti / 40 nm Au on glass), 1.2 cm x 1 cm
Work-upcool to room temperature; substrate removed and dried under reduced pressure
Activationfor sorption: high vacuum at 120 deg C for at least 12 h
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Linker2,5-dihydroxyterephthalic acid0.95 mg; 4.8 mmol7 · Experimental; Table S2 · Table S2
Metal SourceZn(OAc)21.76 mg; 9.6 mmol7 · Experimental; Table S2 · Table S2
Acidbenzoic acid50 uL7 · Experimental; Table S2 · Table S2
SolventDMF2.2 mL precursor; 5 mL vapour source7 · Experimental; Table S2 · Table S2
Complete recipeSource: Both

Route 20: Other

7 · Experimental; Table S2 · Table S2

Metal precursorsZn(OAc)2, 1.76 mg, 9.6 mmol as extracted
Linker precursors2,5-dihydroxyterephthalic acid, 0.95 mg, 4.8 mmol as extracted
SolventsDMF precursor solution, 2.2 mL; DMF vapour source, 5 mL
Additivesbenzoic acid solution, 100 uL
Atmospherehandled in air unless otherwise noted; closed glass bottle during VAC
Temperature100
Time18
Substrate orientationquartz substrate, 1.2 cm x 1 cm
Work-upcool to room temperature; substrate removed and dried under reduced pressure
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Linker2,5-dihydroxyterephthalic acid0.95 mg; 4.8 mmol7 · Experimental; Table S2 · Table S2
Metal SourceZn(OAc)21.76 mg; 9.6 mmol7 · Experimental; Table S2 · Table S2
Acidbenzoic acid100 uL7 · Experimental; Table S2 · Table S2
SolventDMF2.2 mL precursor; 5 mL vapour source7 · Experimental; Table S2 · Table S2
Complete recipeSource: Both

Route 21: Other

7 · Experimental; Table S2 · Table S2

Metal precursorsZn(OAc)2, 1.76 mg, 9.6 mmol as extracted
Linker precursors2,5-dihydroxyterephthalic acid, 0.95 mg, 4.8 mmol as extracted
SolventsDMF precursor solution, 2.2 mL; DMF vapour source, 5 mL
Additivesbenzoic acid solution, 50 uL
Atmospherehandled in air unless otherwise noted; closed glass bottle during VAC
Temperature100
Time18
Substrate orientationsilicon substrate, 1.2 cm x 1 cm
Work-upcool to room temperature; substrate removed and dried under reduced pressure
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Linker2,5-dihydroxyterephthalic acid0.95 mg; 4.8 mmol7 · Experimental; Table S2 · Table S2
Metal SourceZn(OAc)21.76 mg; 9.6 mmol7 · Experimental; Table S2 · Table S2
Acidbenzoic acid50 uL7 · Experimental; Table S2 · Table S2
SolventDMF2.2 mL precursor; 5 mL vapour source7 · Experimental; Table S2 · Table S2
Complete recipeSource: Both

Route 22: Other

7 · Experimental; Table S3 · Table S3

Metal precursors70 nm ALD ZnO layer on glass as immobilised metal precursor
Linker precursors2,5-dihydroxyterephthalic acid, 0.95 mg, 4.8 mmol as extracted
SolventsTHF 1.1 mL and H2O 1.1 mL precursor solution; THF 2.5 mL and H2O 2.5 mL vapour source
Atmospherehandled in air unless otherwise noted; closed glass bottle during VAC
Temperature110
Time18
Substrate orientation70 nm ALD ZnO on glass
Work-upcool to room temperature; substrate removed and dried under reduced pressure
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Linker2,5-dihydroxyterephthalic acid0.95 mg; 4.8 mmol7 · Experimental; Table S3 · Table S3
Metal Source70 nm ALD ZnO on glasssubstrate-supported layer7 · Experimental; Table S3 · Table S3
SolventTHF1.1 mL precursor; 2.5 mL vapour source7 · Experimental; Table S3 · Table S3
SolventH2O1.1 mL precursor; 2.5 mL vapour source7 · Experimental; Table S3 · Table S3