Diffraction Structure — MOF-74(M) Films Obtained through Vapor-Assisted Conversion - Impact on Crystal Orientation and Optical Properties

5 measurement groups · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

MOF-74(Co) thin film on gold · Thin Film

MOF-74(Co) film on gold.

Geometry: thin film on gold substrate
Context: pristine MOF-74(Co) film
Measurement source: 5900 · Highly Crystalline MOF-74(Co) and MOF-74(Ni) Films · Figure S25

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source

MOF-74(Mg) thin film on gold, oriented · Thin Film

Oriented MOF-74(Mg) film grown on gold after adding water and benzoic acid.

Geometry: thin film on gold substrate
Context: pristine MOF-74(Mg) film
Measurement source: 5900 · Highly Crystalline and Oriented MOF-74(Mg) Films · Figure 3A

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
MOF-74(Mg) oriented gold c-axis orientation	c-axis aligned nearly orthogonally to substrate	—	—	Text Qualitative	5900 · Highly Crystalline and Oriented MOF-74(Mg) Films · Figure 3A

MOF-74(Mg) thin film on gold, nonoriented · Thin Film

MOF-74(Mg) film grown on gold with DMF/EtOH route.

Geometry: thin film on gold substrate
Context: pristine MOF-74(Mg) film
Measurement source: 5899-5900 · Highly Crystalline and Oriented MOF-74(Mg) Films · Figure S16

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
MOF-74(Mg) nonoriented gold orientation	random crystallite orientation	—	—	Text Qualitative	5899-5900 · Highly Crystalline and Oriented MOF-74(Mg) Films · Figure S16
MOF-74(Mg) nonoriented gold film thickness	about 350 nm	—	—	Text Approximate	5899-5900 · Highly Crystalline and Oriented MOF-74(Mg) Films · Figure S15

MOF-74(Ni) thin film on glass · Thin Film

MOF-74(Ni) films on gold, glass and silicon; glass GIWAXS shown in Figure S29.

Geometry: thin film on glass substrate
Context: pristine MOF-74(Ni) film
Measurement source: 5900 · Highly Crystalline MOF-74(Co) and MOF-74(Ni) Films · Figures 4B, S28, S29

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source

MOF-74(Zn) thin film on gold · Thin Film

GIWAXS patterns of MOF-74(Zn) thin films on gold, glass and silicon; gold sample cited as highest degree of order.

Geometry: thin film on substrate
Context: pristine MOF-74(Zn) film
Measurement source: 5898 · Highly Crystalline and Oriented MOF-74(Zn) Films · Figure 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
First-hand electrical transport measurements	not reported	—	—	Qualitative Qualitative	5896 and 5902 · Abstract, Introduction, Conclusions
MOF-74(Zn) GIWAXS (110) qz	qy = 0 nm-1, qz = 4.8 nm-1	—	—	Text Rounded Reported	5898 · Highly Crystalline and Oriented MOF-74(Zn) Films · Figure 2
MOF-74(Zn) c-axis orientation	c-axis aligned horizontally to the substrate	—	—	Text Qualitative	5898 · Highly Crystalline and Oriented MOF-74(Zn) Films · Figure 2