Scheurle P.I., Mahringer A., Biewald A. et al. · Chemistry of Materials · 2021 · 5896-5904
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
Oriented MOF-74(Mg) films on gold are highly porous and are attractive candidates for on-chip host-guest experiments.
Caveat: BET value is normalised to geometric surface area and is partly attributed to the roughly 3 um film thickness.
5902 · Conclusions · Linked to 3 structured results
MOF-74(Zn) and MOF-74(Mg) films show blue emission with similar PL lifetimes and homogeneous confocal PL maps.
Caveat: Detailed lifetime analysis focused on Zn and Mg because Ni and Co emission intensities were low.
5902 · Conclusions · Figure 6 · Linked to 6 structured results
This paper does not provide first-hand electrical-transport, thermoelectric or electrochemical performance measurements for the MOF-74 films.
Caveat: The paper discusses potential optical or electrical properties and cites earlier conductive MOF-74 work, but no transport data are measured here.
5902 · Conclusions · Linked to 1 structured result
MOF-74 films based on different metal ions grow with substantially different modes and orientations on the same surfaces.
Caveat: Mechanistic interpretation is based on observed morphologies and time-dependent growth experiments, not direct in situ spectroscopy.
5902 · Conclusions · Linked to 3 structured results
Vapor-assisted conversion enables on-surface growth of crystalline MOF-74(M = Zn, Mg, Ni, Co) thin films on multiple substrates with tunable crystallite orientation.
Caveat: Orientation control was strongest for Zn and Mg; Ni and Co remained nonoriented after screening.
5902 · Conclusions · Linked to 5 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| MOF-74(Co)Browse family: Co₂(DOBDC) / Co–MOF-74 / CPO-27-Co | Co-MOF-74; framework built from divalent Co ions and 2,5-dihydroxyterephthalateCo2+ metal-oxo columns · 2,5-dihydroxyterephthalic acid / 2,5-dihydroxyterephthalate (DOT) | 3D · PristineMOF-74 structure; XRD patterns agree with MOF-74(Co) bulk material | 5900 · Results and Discussion · Figure 4 and Figures S24-S25 |
| MOF-74(Mg)Browse family: Mg₂(DOBDC) / Mg–MOF-74 / CPO-27-Mg | Mg-MOF-74; framework built from divalent Mg ions and 2,5-dihydroxyterephthalateMg2+ metal-oxo columns · 2,5-dihydroxyterephthalic acid / 2,5-dihydroxyterephthalate (DOT) | 3D · PristineMOF-74 structure; crystalline films matched MOF-74(Mg) bulk XRD/GIWAXS patterns | 5899 · Results and Discussion · Figure 3 |
| MOF-74(Ni)Browse family: Ni₂(DOBDC) / Ni–MOF-74 / CPO-27-Ni | Ni-MOF-74; framework built from divalent Ni ions and 2,5-dihydroxyterephthalateNi2+ metal-oxo columns · 2,5-dihydroxyterephthalic acid / 2,5-dihydroxyterephthalate (DOT) | 3D · PristineMOF-74 structure; XRD patterns agree with MOF-74(Ni) bulk material | 5900 · Results and Discussion · Figure 4 and Figures S28-S29 |
| MOF-74(Zn)Browse family: Zn₂(DOBDC) / Zn–MOF-74 / CPO-27-Zn | Zn-MOF-74; framework built from divalent Zn ions and 2,5-dihydroxyterephthalateZn2+ metal-oxo columns · 2,5-dihydroxyterephthalic acid / 2,5-dihydroxyterephthalate (DOT) | 3D · PristineMOF-74 structure; R-3 space group identified from GIWAXS indexing | 5896 · Abstract and Introduction |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| MOF-74(Co) bulk materialresearch_0715__mat__mof74_co | Powder · Pristine Control · Pristine Framework | bulk powder reference; washed and dried under reduced pressure | 10 · MOF-74 bulk material synthesis · Figures S46-S47 |
| MOF-74(Mg) bulk materialresearch_0715__mat__mof74_mg | Powder · Pristine Control · Pristine Framework | bulk powder reference; washed and dried under reduced pressure | 10 · MOF-74 bulk material synthesis · Figures S34, S46-S47 |
| MOF-74(Ni) bulk materialresearch_0715__mat__mof74_ni | Powder · Pristine Control · Pristine Framework | bulk powder reference; washed and dried under reduced pressure | 10 · MOF-74 bulk material synthesis · Figures S46-S47 |
| MOF-74(Zn) bulk materialresearch_0715__mat__mof74_zn | Powder · Pristine Control · Pristine Framework | bulk powder reference; washed and dried under reduced pressure | 10 · MOF-74 bulk material synthesis · Figures S46-S47 |
| MOF-74(Co) thin film on glassresearch_0715__mat__mof74_co | Thin Film · Target Sample · Pristine Framework | VAC-grown, nonorientedglass · not stated | 5900 · Highly Crystalline MOF-74(Co) and MOF-74(Ni) Films · Figure S27 |
| MOF-74(Co) thin film on goldresearch_0715__mat__mof74_co | Thin Film · Target Sample · Pristine Framework | VAC-grown, nonoriented; activated at 120 deg C for 12 h for krypton sorptiongold on glass (10 nm Ti / 40 nm Au) · not stated | 5900 · Highly Crystalline MOF-74(Co) and MOF-74(Ni) Films · Figure 4C |
| MOF-74(Co) thin film on quartzresearch_0715__mat__mof74_co | Thin Film · Target Sample · Pristine Framework | VAC-grown; used for UV-vis and PL spectroscopyquartz · average film thickness 500 nm stated for MOF-74(M) films | 25 · Additional characterization · Figure S39 |
| MOF-74(Co) thin film on siliconresearch_0715__mat__mof74_co | Thin Film · Target Sample · Pristine Framework | VAC-grown, nonorientedsilicon · not stated | 21-22 · Additional characterization of MOF-74(Co) films · Figures S24 and S27 |
| MOF-74(Mg) thin film on glassresearch_0715__mat__mof74_mg | Thin Film · Target Sample · Pristine Framework | VAC-grown, preferentially orthogonally orientedglass · average film thickness 500 nm stated for MOF-74(M) films | 5899 · Highly Crystalline and Oriented MOF-74(Mg) Films · Figure 3 and Figure S14 |
| MOF-74(Mg) thin film on gold, nonorientedresearch_0715__mat__mof74_mg | Thin Film · Target Sample · Pristine Framework | VAC-grown using DMF/EtOH solvent mixturegold on glass (10 nm Ti / 40 nm Au) · about 350 nm | 5899-5900 · Highly Crystalline and Oriented MOF-74(Mg) Films · Figures S15-S16 |
| MOF-74(Mg) thin film on gold, orientedresearch_0715__mat__mof74_mg | Thin Film · Target Sample · Pristine Framework | VAC-grown with water and benzoic acid; activated at 120 deg C for 12 h for krypton sorptiongold on glass (10 nm Ti / 40 nm Au) · about 3 um | 5900 · Highly Crystalline and Oriented MOF-74(Mg) Films · Figure 3 and Figure S18 |
| MOF-74(Mg) thin film on quartzresearch_0715__mat__mof74_mg | Thin Film · Target Sample · Pristine Framework | VAC-grown; used for UV-vis and PL spectroscopyquartz · average film thickness 500 nm stated for MOF-74(M) films | 5901 · Optical Properties of the MOF-74(M) Films · Figure 6 |
| MOF-74(Mg) thin film on siliconresearch_0715__mat__mof74_mg | Thin Film · Target Sample · Pristine Framework | VAC-grownsilicon · not stated | 15 · Additional characterization of MOF-74(Mg) films · Figure S12 |
| MOF-74(Ni) thin film on glassresearch_0715__mat__mof74_ni | Thin Film · Target Sample · Pristine Framework | VAC-grown, nonoriented; activated at 120 deg C for 12 h for krypton sorptionglass · about 250 nm on glass | 5900 · Highly Crystalline MOF-74(Co) and MOF-74(Ni) Films · Figure 4D |
| MOF-74(Ni) thin film on goldresearch_0715__mat__mof74_ni | Thin Film · Target Sample · Pristine Framework | VAC-grown, nonorientedgold on glass (10 nm Ti / 40 nm Au) · not stated | 22 · Additional characterization of MOF-74(Ni) films · Figure S28 |
| MOF-74(Ni) thin film on quartzresearch_0715__mat__mof74_ni | Thin Film · Target Sample · Pristine Framework | VAC-grown; used for UV-vis and PL spectroscopyquartz · average film thickness 500 nm stated for MOF-74(M) films | 25 · Additional characterization · Figure S39 |
| MOF-74(Ni) thin film on siliconresearch_0715__mat__mof74_ni | Thin Film · Target Sample · Pristine Framework | VAC-grown, nonorientedsilicon · not stated | 22-23 · Additional characterization of MOF-74(Ni) films · Figures S28 and S31 |
| MOF-74(Zn) thin film on glassresearch_0715__mat__mof74_zn | Thin Film · Target Sample · Pristine Framework | VAC-grown, oriented, as-prepared unless activated for sorptionglass · 350-650 nm range reported for MOF-74(Zn) films on employed substrates; average film thickness 500 nm | 5898 · Highly Crystalline and Oriented MOF-74(Zn) Films · Figure 2 |
| MOF-74(Zn) thin film on goldresearch_0715__mat__mof74_zn | Thin Film · Target Sample · Pristine Framework | VAC-grown, oriented; activated at 120 deg C for 12 h for krypton sorptiongold on glass (10 nm Ti / 40 nm Au) · 350-650 nm range reported for MOF-74(Zn) films on employed substrates | 5898 · Highly Crystalline and Oriented MOF-74(Zn) Films · Figure 2 |
| MOF-74(Zn) thin film on quartzresearch_0715__mat__mof74_zn | Thin Film · Target Sample · Pristine Framework | VAC-grown; used for UV-vis and PL spectroscopyquartz · average film thickness 500 nm stated for MOF-74(M) films | 5901 · Optical Properties of the MOF-74(M) Films · Figure 6 |
| MOF-74(Zn) thin film on siliconresearch_0715__mat__mof74_zn | Thin Film · Target Sample · Pristine Framework | VAC-grown, orientedsilicon · 350-650 nm range reported for MOF-74(Zn) films on employed substrates | 5898 · Highly Crystalline and Oriented MOF-74(Zn) Films · Figure 2 |
| MOF-74(Zn) thin film from 70 nm ALD ZnO on glassresearch_0715__mat__mof74_zn | Thin Film · Target Sample · Pristine Framework | VAC conversion of immobilised ZnO metal precursor layer70 nm ALD ZnO layer on glass · ZnO precursor layer: 70 nm nominal in main text; SI describes 73 nm thick ALD films | 5898-5899 · Highly Crystalline and Oriented MOF-74(Zn) Films · Figures S10-S11 |