Spectroscopy — Upgrading Structural Conjugation in Three-Dimensional Ni-Based Metal-Organic Frameworks for Promoting Electrical Conductivity and Specific Capacitance

5 measurement groups · 4 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

as-synthesised Ni-BPE crystals · Single Crystal

Bruker VERTEX70; KBr pellets; 4000-400 cm-1

Geometry: KBr pellet
Context: pristine target MOF
Measurement source: p. 18084 · Experimental Section - Materials and Methods · Figure 2b

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Pyridyl C-N stretching shift after coordination	from around 1400 to 1380 cm-1	—	—	Text Approximate	p. 18087 · XPS, PXRD, IR, and TGA Characterization · Figure 2b

as-synthesised Ni-BPY crystals · Single Crystal

Bruker VERTEX70; KBr pellets; 4000-400 cm-1

Geometry: KBr pellet
Context: pristine control MOF
Measurement source: p. 18087 · XPS, PXRD, IR, and TGA Characterization · Figure 2b

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source

as-synthesised Ni-BPE crystals · Single Crystal

PERKINELMER LAMBDA750

Geometry: solid sample
Context: pristine target MOF
Measurement source: p. 18087 · UV-Vis Spectra, Electrical Conductivity, BET, and SEM Characterization · Figure 2d

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Relative UV-vis absorption wavelength	Ni-BPE absorbs light at longer wavelengths than Ni-BPY	—	—	Text Qualitative	p. 18087 · UV-Vis Spectra, Electrical Conductivity, BET, and SEM Characterization · Figure 2d

as-synthesised Ni-BPY crystals · Single Crystal

PERKINELMER LAMBDA750

Geometry: solid sample
Context: pristine control MOF
Measurement source: p. 18087 · UV-Vis Spectra, Electrical Conductivity, BET, and SEM Characterization · Figure 2d

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source

as-synthesised Ni-BPE crystals · Single Crystal

Thermo Scientific Escalab Xi; monochromatic Al Kalpha radiation

Geometry: powder/surface
Context: pristine target MOF
Measurement source: p. 18086 · XPS, PXRD, IR, and TGA Characterization · Figure S4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ni-BPE XPS Ni 2p1/2 binding energy as printed	855.7 eV	—	—	Text Rounded Reported	p. 18086 · XPS, PXRD, IR, and TGA Characterization · Figure S4
Ni-BPE XPS Ni 2p3/2 binding energy as printed	around 873.3 eV	—	—	Text Approximate	p. 18086 · XPS, PXRD, IR, and TGA Characterization · Figure S4