Spectroscopy — Orientation Control of a Two-Dimensional Conductive Metal-Organic Framework Thin Film by a Pyridine Vapor-Assisted Dry Process

4 measurement groups · 8 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

as-deposited Cu3(HHTP)2-like thin film on alpha-Al2O3 (001) · Thin Film

IR spectrum of as-deposited thin film compared with Cu3(HHTP)2 powder, HHTP powder and Cu(OAc)2 powder.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
as-deposited IR broad C-C/C-O framework band lower peak	broad absorption peak at 1190 cm^-1	—	—	Text Rounded Reported	p003 · Results and Discussion · Figure 2a
as-deposited IR broad C-C/C-O framework band upper peak	broad absorption peak at 1490 cm^-1	—	—	Text Rounded Reported	p003 · Results and Discussion · Figure 2a

(001)-oriented Cu3(HHTP)2 thin film annealed with 3 uL pyridine · Thin Film

IR spectra after postdeposition annealing with 1, 3, and 5 uL pyridine; 3 uL target discussed as comparable to Cu3(HHTP)2 powder.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
adsorbed pyridine-related IR peak	small absorption peak near 1630 cm^-1 after annealing with 3 and 5 uL pyridine	—	—	Text Approximate	p002 · Figure caption · Figure S1
3 uL pyridine annealing sharpens framework IR peaks	IR spectrum after annealing with 3 uL pyridine is comparable to Cu3(HHTP)2 powder	—	—	Qualitative Qualitative	p003 · Results and Discussion · Figure 2a

(001)-oriented Cu3(HHTP)2 thin film annealed with 3 uL pyridine · Thin Film

UV-vis spectrum of 3 uL pyridine-vapour annealed film.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
3 uL annealed LMCT absorption band	around 630 nm	—	—	Text Approximate	p004 · Results and Discussion · Figure 2b
*3 uL annealed pi-pi absorption band**	around 380 nm	—	—	Text Approximate	p004 · Results and Discussion · Figure 2b

as-deposited Cu3(HHTP)2-like thin film on alpha-Al2O3 (001) · Thin Film

UV-vis spectrum of as-deposited film.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
as-deposited LMCT absorption band	approximately 610 nm	—	—	Text Approximate	p003 · Results and Discussion · Figure 2b
*as-deposited pi-pi absorption band**	approximately 380 nm	—	—	Text Approximate	p003 · Results and Discussion · Figure 2b