Chon S., Nakayama R., Iwamoto S. et al. · ACS Applied Materials and Interfaces · 2023 · 56057-56063
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
SEM-EDS and SIMS support homogeneous Cu3(HHTP)2 film distribution on and through the substrate-supported film, with negligible Si absorber incorporation.
Caveat: Depth is reported in sputtering time rather than calibrated physical thickness.
p004 · Results and Discussion · Figure 3 · Linked to 3 structured results
Pyridine-vapour annealing is critical for crystallisation and orientation control; the as-deposited film shows no noticeable XRD peaks while the annealed film is (001)-oriented.
Caveat: The exact role of moisture in the sealed-air setup is not isolated.
p004 · Results and Discussion · Figure S3 · Linked to 3 structured results
A two-step dry process combining IR-PLD multilayer deposition and pyridine-vapour-assisted annealing fabricates a (001)-oriented Cu3(HHTP)2 thin film on insulating alpha-Al2O3 (001).
Caveat: Final film thickness is not reported; route is demonstrated on small 5 mm x 5 mm substrates.
p001 · Abstract · Figure 4 · Linked to 5 structured results
Excess pyridine (5 uL) broadens IR bands and is interpreted as decomposing the local Cu3(HHTP)2 structure by strong coordination to Cu ions.
Caveat: The decomposition assignment is inferred from IR band broadening; no independent chemical quantification is reported for the 5 uL variant.
p003 · Results and Discussion · Figure 2a · Linked to 1 structured result
The noncrystalline as-deposited Cu3(HHTP)2-like film is also electrically conductive, with table values of 2.6-2.8 x 10^-2 S cm^-1 across the measured current range.
Caveat: Authors suggest this may indicate negligible anisotropy and/or small grain-boundary effects, but do not directly resolve the mechanism.
p005 · Results and Discussion · Table S1 · Linked to 4 structured results
The oriented Cu3(HHTP)2 thin film is electrically conductive at room temperature with an in-plane conductivity of 2.6 x 10^-2 S cm^-1 from SI Table S1.
Caveat: Main text states 2.7 x 10^-2 S cm^-1 for the (001)-oriented film, whereas SI Table S1 reports 2.6 x 10^-2 S cm^-1 at all listed currents; the table values are extracted as primary numeric results.
p004 · Table S1 · Table S1 · Linked to 5 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Cu3(HHTP)2 conductive metal-organic frameworkBrowse family: Cu₃(HHTP)₂ / Cu–HHTP | Cu3(HHTP)2; HHTP = 2,3,6,7,10,11-hexahydroxytriphenyleneCu(II) ions / copper acetate-derived Cu nodes · HHTP (2,3,6,7,10,11-hexahydroxytriphenylene) | 2D · PristineLayer-structured two-dimensional conductive MOF; pyridine-vapour annealed film is assigned as (001)-oriented with Cu3(HHTP)2 layers parallel to alpha-Al2O3 (001). | p001 · Abstract |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Cu3(HHTP)2 thin film annealed with 1 uL pyridineresearch_0260__mat__m_cu_hhtp | Thin Film · Target Sample · Pristine Framework | Postdeposition annealed with 1 uL pyridine in sealed 7 mL cell at 333 K for 24 h under air-sealed conditions.alpha-Al2O3 (001) · From common as-deposited multilayer; final film thickness not explicitly reported. | p002 · Experimental Section · Figure 2 |
| (001)-oriented Cu3(HHTP)2 thin film annealed with 3 uL pyridineresearch_0260__mat__m_cu_hhtp | Thin Film · Target Sample · Pristine Framework | Postdeposition annealed with 3 uL pyridine in sealed 7 mL cell at 333 K for 24 h; (001)-oriented crystalline film.alpha-Al2O3 (001) · From common as-deposited multilayer; final film thickness not explicitly reported. | p005 · Conclusions · Figures 3-4; Table S1 |
| Cu3(HHTP)2 thin film annealed with 5 uL pyridineresearch_0260__mat__m_cu_hhtp | Thin Film · Target Sample · Pristine Framework | Postdeposition annealed with 5 uL pyridine in sealed 7 mL cell at 333 K for 24 h.alpha-Al2O3 (001) · From common as-deposited multilayer; final film thickness not explicitly reported. | p003 · Results and Discussion · Figure 2 |
| as-deposited Cu3(HHTP)2-like thin film on alpha-Al2O3 (001)research_0260__mat__m_cu_hhtp | Thin Film · Pristine Control · Pristine Framework | Alternating HHTP/Cu(OAc)2 multilayer deposited by IR-PLD; noncrystalline and not oriented before pyridine-vapour annealing.alpha-Al2O3 (001), 5 mm x 5 mm x 0.5 mm · Five IR-PLD cycles of alternating 10 nm HHTP and 8 nm Cu(OAc)2 precursor layers; final film thickness not explicitly reported. | p002 · Experimental Section · Figure 1 |