Spectroscopy — Facile interfacial charge transfer across hole doped cobalt-based MOFs/TiO2 nano-hybrids making MOFs light harvesting active layers in solar cells

Measurement evidence

Spectroscopy

Facile interfacial charge transfer across hole doped cobalt-based MOFs/TiO2 nano-hybrids making MOFs light harvesting active layers in solar cells · Lee D.Y., Lim I., Shin C.Y. et al. · Journal of Materials Chemistry A · 2015 · 22669-22676

2 measurement groups · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Photoluminescence spectroscopy

Iodine-treated Co-NDC/TiO2/FTO photoanode · Electrode

Emission spectra of Co-based MOF LBL/TiO2/FTO photoanodes before and after iodine treatment.

Geometry
photoanode on FTO
Context
iodine-doped and pristine MOF/TiO2 composites
Measurement source
p005 / article p.22673 · Results and discussion · Fig. 5A
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Pristine MOF/TiO2 photoluminescence quenchingno quenching phenomenon observedText
Qualitative
p005 / article p.22673 · Results and discussion · Fig. 5A
Photoluminescence quenching after iodine treatmentMarked as a best value within this paperabout 97% quenchingText
Approximate
p005 / article p.22673 · Results and discussion · Fig. 5A

UV/visible absorption spectroscopy and solution spectrophotometric iodine uptake analysis

Iodine-treated Co-NDC LBL film on amine-functionalised glass · Thin Film

Co-BDC and Co-NDC LBL films before and after iodine treatment.

Context
iodine-doped framework films
Measurement source
p003 / article p.22671 · Results and discussion · Fig. 3A
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Iodine uptake in Co-BDC0.056 molecules of I2 per unit cellText
Exact Reported
p003 / article p.22671 · Results and discussion · Fig. 3A
Iodine uptake in Co-NDCMarked as a best value within this paper0.348 molecules of I2 per unit cellText
Exact Reported
p003 / article p.22671 · Results and discussion · Fig. 3A
Cobalt d-d absorption peak548 nmText
Rounded Reported
p003 / article p.22671 · Results and discussion · Fig. 3A
Iodine absorption peak after dopingabout 438 nmText
Approximate
p003 / article p.22671 · Results and discussion · Fig. 3A