Spectroscopy — Electrochemical Capacitance Traces with Interlayer Spacing in Two-dimensional Conductive Metal–Organic Frameworks

Measurement evidence

Spectroscopy

Electrochemical Capacitance Traces with Interlayer Spacing in Two-dimensional Conductive Metal–Organic Frameworks · Su A.Y., Apostol P., Wang J. et al. · Angewandte Chemie - International Edition · 2024 · e202402526

4 measurement groups · 4 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Raman spectroscopy

exfoliated Bu-MOF ethanol colloid · Nanosheet

Bulk Bu-MOF powder compared with drop-cast exfoliated Bu-MOF on silicon substrate; 532 nm excitation.

Context
bulk vs exfoliated pristine framework
Measurement source
19 · Raman spectra · Figure S13
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Raman band sharpening upon exfoliationbands sharpen upon exfoliationQualitative
Qualitative
4 · Exfoliation · Figure S13

solution UV/Vis and diffuse reflectance comparison

exfoliated Bu-MOF ethanol colloid · Nanosheet

Exfoliated Bu-MOF in ethanol compared with diffuse reflectance of bulk Bu-MOF; sonication progress compared after 0.5 h and 5 h.

Context
exfoliated pristine framework colloid
Measurement source
17 · UV/Vis and diffuse reflectance spectra · Figure S11
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
UV/Vis match to bulk diffuse reflectancematchedQualitative
Qualitative
4 · Exfoliation · Figure S11

solution UV/Vis and diffuse reflectance comparison

exfoliated Pent-MOF ethanol colloid · Nanosheet

Exfoliated Pent-MOF in ethanol compared with diffuse reflectance of bulk Pent-MOF.

Context
exfoliated pristine framework colloid
Measurement source
17 · UV/Vis and diffuse reflectance spectra · Figure S11
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
UV/Vis match to bulk diffuse reflectancematchedQualitative
Qualitative
4 · Exfoliation · Figure S11

ATR-IR

H-/Et-/Bu-/Pent-MOF powder series · Powder

Full ATR-IR spectra and zoomed alkyl C-H stretch region for the MOF series.

Context
pristine framework powders
Measurement source
9 · IR spectra · Figure S3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
alkyl C-H stretch trendrelative intensity increases from H-MOF to Pent-MOFText
Qualitative
2 · Results · Figure S3