cMOF Evidence Base

Synthesis evidence

Electrochemical Capacitance Traces with Interlayer Spacing in Two-dimensional Conductive Metal–Organic Frameworks

Su A.Y., Apostol P., Wang J. et al. · Angewandte Chemie - International Edition · 2024 · e202402526

6 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Partial recipeSource: Both

Route 1: Other

4 · Exfoliation

Linker precursorsBu-MOF bulk powder
Solventsethanol
Atmosphereambient
Time5
Work-upcentrifugation to remove larger particles
Activationnone reported
Show 2 structured reagent records
RoleReagentAmount / concentrationSource
OtherBu-MOFNot specified4 · Exfoliation
SolventethanolNot specified4 · Exfoliation
Complete recipeSource: SI

Route 2: Solvothermal

6 · MOF synthesis

Metal precursorsNi(OAc)2.6H2O, 5.05 mg
Linker precursorshexaamino-TAT ligand, 10 mg
Solvents3 mL DMF, 3 mL DMA, 1.5 mL water, 2 mL aqueous NaOAc solution
Additives2 M NaOAc, 2 mL
Temperature65
Timeovernight
Work-upblack powder washed with water and MeOH
Activationnone reported
Show 5 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceNi(OAc)2.6H2O5.05 mg6 · MOF synthesis
SolventDMF3 mL6 · MOF synthesis
SolventDMA3 mL6 · MOF synthesis
Baseaqueous NaOAc solution2 mL · 2 M6 · MOF synthesis
Linkerhexaamino-TAT ligand (HIBu3-TAT precursor)10 mg in 1.5 mL water6 · MOF synthesis
Complete recipeSource: SI

Route 3: Solvothermal

6 · MOF synthesis

Metal precursorsNi(OAc)2.6H2O, 5.05 mg
Linker precursorshexaamino-TAT ligand, 10 mg
Solvents3 mL DMF, 3 mL DMA, 1.5 mL water, 2 mL aqueous NaOAc solution
Additives2 M NaOAc, 2 mL
Temperature65
Timeovernight
Work-upblack powder washed with water and MeOH
Activationnone reported
Show 5 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceNi(OAc)2.6H2O5.05 mg6 · MOF synthesis
SolventDMF3 mL6 · MOF synthesis
SolventDMA3 mL6 · MOF synthesis
Baseaqueous NaOAc solution2 mL · 2 M6 · MOF synthesis
Linkerhexaamino-TAT ligand (HIEt3-TAT precursor)10 mg in 1.5 mL water6 · MOF synthesis
Vague recipeSource: Both

Route 4: Solvothermal

6 · MOF synthesis

Metal precursorsnickel acetate / Ni(OAc)2; exact local amount not repeated
Linker precursorsHI-TAT / unalkylated hexaamino-TAT ligand; exact local amount not repeated
Solventsaqueous sodium acetate / DMF / DMA (series-level main text)
Additivessodium acetate
Work-upnot reported in this paper; referred to published procedure
Activationnot reported
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal Sourcenickel acetateNot specified6 · MOF synthesis
LinkerHI-TAT / hexaamino-TAT ligandNot specified6 · MOF synthesis
Additivesodium acetateNot specified6 · MOF synthesis
SolventDMF/DMA/waterNot specified6 · MOF synthesis
Partial recipeSource: Both

Route 5: Other

4 · Exfoliation

Linker precursorsPent-MOF bulk powder
Solventsethanol
Atmosphereambient
Time5
Work-upcentrifugation to remove larger particles
Activationnone reported
Show 2 structured reagent records
RoleReagentAmount / concentrationSource
OtherPent-MOFNot specified4 · Exfoliation
SolventethanolNot specified4 · Exfoliation
Complete recipeSource: SI

Route 6: Solvothermal

6 · MOF synthesis

Metal precursorsNi(OAc)2.6H2O, 5.05 mg
Linker precursorshexaamino-TAT ligand, 10 mg
Solvents3 mL DMF, 3 mL DMA, 3.5 mL aqueous NaOAc solution
Additives2 M NaOAc, 3.5 mL
Temperature65
Timeovernight
Work-upblack powder washed with water and MeOH
Activationnone reported
Show 5 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceNi(OAc)2.6H2O5.05 mg6 · MOF synthesis
SolventDMF3 mL6 · MOF synthesis
SolventDMA3 mL6 · MOF synthesis
Baseaqueous NaOAc solution3.5 mL · 2 M6 · MOF synthesis
Linkerhexaamino-TAT ligand (HIPent3-TAT precursor)10 mg6 · MOF synthesis