Su A.Y., Apostol P., Wang J. et al. · Angewandte Chemie - International Edition · 2024 · e202402526
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
Molar and gravimetric capacitance increase from H-MOF to Bu-MOF and then decrease for Pent-MOF, making Bu-MOF the best member under the reported 5 mV/s comparison.
Caveat: Capacitance values are read from plotted data; Bu-MOF peak is clear but exact values derive from figure labels/visual estimates.
3 · Electrochemical characterization · Figure 2b,c · Linked to 5 structured results
The four HATAT-based MOFs are isostructural hexagonal 2D layered conductive frameworks with comparable in-plane structural order.
Caveat: H-MOF synthesis details are imported by reference rather than fully repeated in this paper.
2 · Results · Figure 1; Figure S4; Table S1 · Linked to 4 structured results
Longer N-alkyl substituents increase interlayer spacing while decreasing BET surface area and total pore volume.
Caveat: BET values are apparent surface areas and pore volumes are single-point desorption values.
2 · Results · Figure 1c,e; Table S2 · Linked to 12 structured results
Partial exfoliation of Bu-MOF and Pent-MOF increases access to redox-active ligand planes and strengthens faradaic contributions, supporting an accessibility rather than ion-confinement explanation.
Caveat: Exfoliation route is partial; quantitative exfoliation yield and sheet thickness are not reported.
4 · Exfoliation EIS · Figure 5; Figure S14 · Linked to 4 structured results
Increasing alkyl chain length attenuates pi-pi stacking and decreases c-direction electronic coupling, lowering electrical conductivity across the series.
Caveat: SI notes conductivities degraded by up to one order of magnitude over months, possibly due to humidity during measurement or storage.
2 · Results · Figure 1d · Linked to 4 structured results
Increasing interlayer spacing shifts charge storage from mostly double-layer capacitance toward larger faradaic pseudocapacitive contributions.
Caveat: Faradaic contribution is inferred from CV features and voltage-dependent EIS/Bode shapes rather than isolated redox quantification.
4 · Electrochemical analysis · Figure 3b; Figure 4; Figure 5 · Linked to 3 structured results
b-values decrease from H-MOF to Pent-MOF, indicating increasing mass-transfer limitations as alkyl chain length increases.
Caveat: b-values are fitted only over 3-20 mV/s.
3 · Electrochemical characterization · Figure 3a; Table S3 · Linked to 4 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Bu-MOF | Ni3(HIBu3-TAT)2Ni centres from nickel acetate coordinated in a hexagonal 2D layered conductive MOF. · n-butyl-substituted HIBu3-TAT ligand | 2D · PristineIsostructural HATAT-based hexagonal 2D layered conductive MOF; [100] reflections show comparable in-plane order and [001] reflections give layer stacking distance. | 2 · Results · Figure 1 |
| Et-MOF | Ni3(HIEt3-TAT)2Ni centres from nickel acetate coordinated in a hexagonal 2D layered conductive MOF. · ethyl-substituted HIEt3-TAT ligand | 2D · PristineIsostructural HATAT-based hexagonal 2D layered conductive MOF; [100] reflections show comparable in-plane order and [001] reflections give layer stacking distance. | 2 · Results · Figure 1 |
| H-MOF | Ni3(HIH3-TAT)2 / Ni3(HI-TAT)2Ni centres from nickel acetate coordinated in a hexagonal 2D layered conductive MOF. · unalkylated hexaaminotriazatruxene-derived HI-TAT ligand | 2D · PristineIsostructural HATAT-based hexagonal 2D layered conductive MOF; [100] reflections show comparable in-plane order and [001] reflections give layer stacking distance. | 2 · Results · Figure 1 |
| Pent-MOF | Ni3(HIPent3-TAT)2Ni centres from nickel acetate coordinated in a hexagonal 2D layered conductive MOF. · n-pentyl-substituted HIPent3-TAT ligand | 2D · PristineIsostructural HATAT-based hexagonal 2D layered conductive MOF; [100] reflections show comparable in-plane order and [001] reflections give layer stacking distance. | 2 · Results · Figure 1 |
| Ni3(HIR3-TAT)2 conductive MOF series | Ni3(HIR3-TAT)2; R = H, Et, n-Bu, n-PentNi centres from nickel acetate. · N-functionalized hexaaminotriazatruxene / HIR3-TAT ligands. | 2D · PristineHATAT-based hexagonal 2D layered conductive MOF family with alkyl substituents controlling interlayer spacing and pore occupancy. | 2 · Results · Figure 1 |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Bu-MOF 9:1 c-MOF/carbon electroderesearch_0829__mat__bu_mof | Electrode · Target Sample · Composite | bulk material pressed directly onto Ni-foam using 3.0 ton force/cm2; mass loading 0.5-1.5 mgMOF/cm2. | 4 · Electrochemical characterization |
| exfoliated Bu-MOF ethanol colloidresearch_0829__mat__bu_mof | Nanosheet · Target Sample · Pristine Framework | Bu-MOF subjected to 5 h sonication in ethanol; centrifuged to remove larger particles, yielding a stable blue colloidal solution. | 4 · Exfoliation · Figure S11-S13 |
| exfoliated Bu-MOF 9:1 electroderesearch_0829__mat__bu_mof | Electrode · Target Sample · Composite | exfoliated Bu-MOF electrode with the same c-MOF/conductive-carbon composition as bulk electrodes. | 4 · Exfoliation EIS · Figure 5 |
| Bu-MOF pressed pelletresearch_0829__mat__bu_mof | Pellet · Target Sample · Pristine Framework | pressed pellet used for linear four-point-probe conductivity. | 3 · Electrical conductivity |
| Bu-MOF as-synthesised powderresearch_0829__mat__bu_mof | Powder · Target Sample · Pristine Framework | black powder after MOF synthesis; washed with water and methanol where reported. | 6 · MOF synthesis |
| Et-MOF 9:1 c-MOF/carbon electroderesearch_0829__mat__et_mof | Electrode · Target Sample · Composite | bulk material pressed directly onto Ni-foam using 3.0 ton force/cm2; mass loading 0.5-1.5 mgMOF/cm2. | 4 · Electrochemical characterization |
| Et-MOF pressed pelletresearch_0829__mat__et_mof | Pellet · Target Sample · Pristine Framework | pressed pellet used for linear four-point-probe conductivity. | 3 · Electrical conductivity |
| Et-MOF as-synthesised powderresearch_0829__mat__et_mof | Powder · Target Sample · Pristine Framework | black powder after MOF synthesis; washed with water and methanol where reported. | 6 · MOF synthesis |
| H-MOF 9:1 c-MOF/carbon electroderesearch_0829__mat__h_mof | Electrode · Target Sample · Composite | bulk material pressed directly onto Ni-foam using 3.0 ton force/cm2; mass loading 0.5-1.5 mgMOF/cm2. | 4 · Electrochemical characterization |
| H-MOF pressed pelletresearch_0829__mat__h_mof | Pellet · Target Sample · Pristine Framework | pressed pellet used for linear four-point-probe conductivity. | 3 · Electrical conductivity |
| H-MOF as-synthesised powderresearch_0829__mat__h_mof | Powder · Target Sample · Pristine Framework | black powder after MOF synthesis; washed with water and methanol where reported. | 6 · MOF synthesis |
| Pent-MOF 9:1 c-MOF/carbon electroderesearch_0829__mat__pent_mof | Electrode · Target Sample · Composite | bulk material pressed directly onto Ni-foam using 3.0 ton force/cm2; mass loading 0.5-1.5 mgMOF/cm2. | 4 · Electrochemical characterization |
| exfoliated Pent-MOF ethanol colloidresearch_0829__mat__pent_mof | Nanosheet · Target Sample · Pristine Framework | Pent-MOF subjected to sonochemical treatment in ethanol; used for UV/Vis and EIS comparison. | 4 · Exfoliation · Figure S11, Figure S14 |
| exfoliated Pent-MOF 9:1 electroderesearch_0829__mat__pent_mof | Electrode · Target Sample · Composite | exfoliated Pent-MOF electrode used for Bode-style EIS comparison. | 4 · Exfoliation EIS · Figure S14 |
| Pent-MOF pressed pelletresearch_0829__mat__pent_mof | Pellet · Target Sample · Pristine Framework | pressed pellet used for linear four-point-probe conductivity. | 3 · Electrical conductivity |
| Pent-MOF as-synthesised powderresearch_0829__mat__pent_mof | Powder · Target Sample · Pristine Framework | black powder after MOF synthesis; washed with water and methanol where reported. | 6 · MOF synthesis |
| H-/Et-/Bu-/Pent-MOF electrochemical electrode seriesresearch_0829__mat__tat_mof_series | Electrode · Paper Level Unspecified · Composite | c-MOF/conductive carbon 9:1 mixture pressed onto nickel foam. | 2 · Electrochemical characterization |
| H-/Et-/Bu-/Pent-MOF powder seriesresearch_0829__mat__tat_mof_series | Powder · Paper Level Unspecified · Pristine Framework | As-synthesised black powder series used for structural, porosity, and morphology comparison. | 2 · Results · Figure 1 |