Spectroscopy — Electrically Conductive Photoluminescent Porphyrin Phosphonate Metal–Organic Frameworks

9 measurement groups · 16 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

diffuse reflectance spectroscopy and Tauc plot

UV-visible and optical absorption spectroscopy

GTUB3 single crystals / crystal powder · Single Crystal

Perkin Elmer Lambda 950 UV-Vis-NIR diffuse reflectance spectrum; Kubelka-Munk/Tauc treatment; indirect allowed transition factor n=2 best matched PL.

Geometry: crystal powder
Context: pristine GTUB3
Measurement source: S8 · 5. Band Gap Measurement · Figure 3B

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
DRS/Tauc optical bandgapMarked as a best value within this paper	1.45 eV	—	—	Text Exact Reported	4 · 2.3 Photoluminescence and Bandgap of GTUB3 · Figure 3B
bandgap transition assignment	indirect band gap	—	—	Text Qualitative	S8 · 5. Band Gap Measurement

FT-IR spectroscopy

Infrared spectroscopy

GTUB3 single crystals / crystal powder · Single Crystal

Perkin Elmer Spectrum 100 FT-IR with ATR zinc selenide crystal; 4000-650 cm-1; characteristic bands assigned for GTUB3 and linkers.

Geometry: ATR-FTIR
Context: pristine GTUB3
Measurement source: S20-S21 · 11. FT-IR spectroscopy · Table S3; Figure S16

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
GTUB3 P=O stretching vibration	1222 cm-1	—	—	SI Table Exact Reported	S20 · Table S3 · Table S3
GTUB3 P-O stretching vibration	1134 cm-1	—	—	SI Table Exact Reported	S20 · Table S3 · Table S3

transient photoluminescence decay

Photoluminescence and fluorescence spectroscopy

GTUB3 single crystals / crystal powder · Single Crystal

515 nm fast-switchable PhoxX+ laser, expanded beam; emission through 550 nm high-pass filter to PMA-Hybrid 07 photomultiplier and Picoquant TimeHarp 260.

Geometry: crystal powder
Context: pristine GTUB3
Measurement source: S18-S19 · 10. Photoluminescence measurements · Figure 2B; Figure S14

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
PL lifetime	40.6 ns	—	assuming a mono-exponential decay	Text Exact Reported	4 · 2.3 Photoluminescence and Bandgap of GTUB3 · Figure 2B

photoluminescence microscopy intensity

Photoluminescence and fluorescence spectroscopy

GTUB3 single crystals / crystal powder · Single Crystal

Red LED 623 nm peak wavelength at approximately 1 sun (100 mW cm-2); detected through 760 nm high-pass filter under PL microscope.

Geometry: PL microscope
Context: pristine GTUB3 compared with photovoltaic controls
Measurement source: 3 · 2.3 Photoluminescence and Bandgap of GTUB3 · Table 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
maximum PL intensity	64 744 detector counts, a.u.	—	—	Table Exact Reported	3 · Table 1 · Table 1

photoluminescence quantum yield

Photoluminescence and fluorescence spectroscopy

GTUB3 single crystals / crystal powder · Single Crystal

LuQY Pro system by QYB Quantum Yield Berlin; comparison values for GTUB3 powder and perovskite controls.

Geometry: powder/device samples
Context: pristine GTUB3 compared with controls
Measurement source: S20 · 10. Photoluminescence measurements · Figure S15

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
PL quantum yield	0.091%	—	—	Text Exact Reported	3 · 2.3 Photoluminescence and Bandgap of GTUB3
MAPbI3 powder PL quantum yieldMarked as a best value within this paper	0.698%	—	—	Text Exact Reported	3 · 2.3 Photoluminescence and Bandgap of GTUB3
perovskite solar cell PL quantum yield	0.044%	—	—	Text Exact Reported	3 · 2.3 Photoluminescence and Bandgap of GTUB3

photoluminescence spectrum

Photoluminescence and fluorescence spectroscopy

GTUB3 single crystals / crystal powder · Single Crystal

GTUB3 crystal powder excited with 532 nm ND:YAG frequency doubled laser; PL signal detected with Andor Kymera 193i spectrograph.

Geometry: crystal powder
Context: pristine GTUB3
Measurement source: S18 · 10. Photoluminescence measurements · Figure 2A

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
PL-derived bandgap / emission energy	1.48 eV	—	—	Text Exact Reported	1,4 · Abstract; 2.3 Photoluminescence and Bandgap of GTUB3 · Figure 2A
PL emission peak wavelength	837 nm	—	—	Text Exact Reported	4 · 2.3 Photoluminescence and Bandgap of GTUB3 · Figure 2A

photoluminescence microscopy intensity

Photoluminescence and fluorescence spectroscopy

highly efficient III-V (GaInAsP) solar cell · Electrode

Same Table 1 PL microscope red-LED/high-pass-filter condition as GTUB3.

Geometry: PL microscope
Context: non-MOF comparison control
Measurement source: 3 · 2.3 Photoluminescence and Bandgap of GTUB3 · Table 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
maximum PL intensity	11 085 detector counts, a.u.	—	—	Table Exact Reported	3 · Table 1 · Table 1

photoluminescence microscopy intensity

Photoluminescence and fluorescence spectroscopy

MAPbI3 perovskite crystal powder · Powder

Same Table 1 PL microscope red-LED/high-pass-filter condition as GTUB3.

Geometry: PL microscope
Context: non-MOF comparison control
Measurement source: 3 · 2.3 Photoluminescence and Bandgap of GTUB3 · Table 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
maximum PL intensityMarked as a best value within this paper	321 015 detector counts, a.u.	—	—	Table Exact Reported	3 · Table 1 · Table 1
MAPbI3 powder PL lifetime	93 ns	—	—	Text Exact Reported	4 · 2.3 Photoluminescence and Bandgap of GTUB3 · Figure S14

photoluminescence microscopy intensity

Photoluminescence and fluorescence spectroscopy

highly efficient perovskite solar cell · Electrode

Same Table 1 PL microscope red-LED/high-pass-filter condition as GTUB3.

Geometry: PL microscope
Context: non-MOF comparison control
Measurement source: 3 · 2.3 Photoluminescence and Bandgap of GTUB3 · Table 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
maximum PL intensity	28 217 detector counts, a.u.	—	—	Table Exact Reported	3 · Table 1 · Table 1
perovskite solar cell PL lifetime	211 ns	—	—	Text Exact Reported	4 · 2.3 Photoluminescence and Bandgap of GTUB3 · Figure S14