Partial recipeSource: Both
Route 1: Solvothermal
3; SI S6 · 2.1 Synthesis of GTUB3; SI 3. Synthesis · Figure S3
Metal precursors0.03 mmol Zn(NO3)2.6H2O; Cu-p-H8TPPA metalloporphyrin linker contains Cu
Linker precursors0.01 mmol {Cu-p-H8TPPA}; 1.5 mmol phenylphosphonic acid
Solvents10 mL DMF and 7.5 mL H2O
Additivesphenylphosphonic acid; pH controlled between 1.7 and 7 to ensure limited deprotonation
Atmospherenot reported
Temperature80
Timenot reported
Work-upyield 90%; purity confirmed by EDX elemental analysis, ICP-MS and powder XRD; isolation/washing/drying not reported
Activationnot reported
Scalability contextMain text reports high-yield synthesis but no scale-up assessment.
Show 5 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | Zn(NO3)2.6H2O | 0.03 mmol | 3; SI S6 · 2.1 Synthesis of GTUB3; SI 3. Synthesis · Figure S3 |
| Linker | {Cu-p-H8TPPA} | 0.01 mmol | 3; SI S6 · 2.1 Synthesis of GTUB3; SI 3. Synthesis · Figure S3 |
| Additive | phenylphosphonic acid | 1.5 mmol | 3; SI S6 · 2.1 Synthesis of GTUB3; SI 3. Synthesis · Figure S3 |
| Solvent | DMF | 10 mL | 3; SI S6 · 2.1 Synthesis of GTUB3; SI 3. Synthesis · Figure S3 |
| Solvent | H2O | 7.5 mL | 3; SI S6 · 2.1 Synthesis of GTUB3; SI 3. Synthesis · Figure S3 |