Other — Electrically Conductive Photoluminescent Porphyrin Phosphonate Metal–Organic Frameworks

3 measurement groups · 13 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

GTUB3 single crystals / crystal powder · Single Crystal

EDX elemental mapping plus ICP-MS elemental ratio determination using Perkin Elmer standard solutions and internal standards.

Geometry: bulk crystal sample
Context: pristine GTUB3
Measurement source: S6,S15-S17 · 8. ICP-MS Measurements · Figures S4 and S11

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
ICP-MS Cu mass fraction	about 6.2%	—	—	Text Approximate	S15 · 8. ICP-MS Measurements
ICP-MS Cu concentration	62058.22 ppm	—	—	Text Exact Reported	S15 · 8. ICP-MS Measurements
ICP-MS P mass fraction	about 12.1%	—	—	Text Approximate	S15 · 8. ICP-MS Measurements
ICP-MS P concentration	121997.15 ppm	—	—	Text Exact Reported	S15 · 8. ICP-MS Measurements
ICP-MS Zn mass fraction	about 6.4%	—	—	Text Approximate	S15 · 8. ICP-MS Measurements
ICP-MS Zn concentration	64698.23 ppm	—	—	Text Exact Reported	S15 · 8. ICP-MS Measurements
EDS elemental distribution	even distribution of constituent elements	—	—	Caption Qualitative	S6 · Figure S4 · Figure S4

GTUB3 single crystals / crystal powder · Single Crystal

Scintillation-vial reaction at 80 deg C in DMF/H2O with pH 1.7-7.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
GTUB3 reaction yield	90%	—	—	Text Rounded Reported	3 · 2.1 Synthesis of GTUB3

GTUB3 single crystals / crystal powder · Single Crystal

Mettler Toledo TGA/SDTA 851; room temperature to 900 deg C; 10 deg C/min; nitrogen atmosphere.

Atmosphere: nitrogen
Geometry: powder/crystals
Context: pristine GTUB3
Measurement source: S1,S7 · 1. Chemicals and Instrumentation; Figure S5 · Figure S5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
thermal decomposition continues above	above 900 deg C	—	—	Text Approximate	5 · 2.5 Thermal Properties · Figure S5
TGA heating rate	10 deg C/min	—	—	Text Exact Reported	S1 · 1. Chemicals and Instrumentation
sharp linker decomposition onset	ca. 400 deg C	—	—	Text Approximate	5 · 2.5 Thermal Properties · Figure S5
solvent weight loss to ca. 300 deg C	12.4% observed; 13.8% calculated	—	13.8% calculated	Text Exact Reported	5 · 2.5 Thermal Properties · Figure S5
temperature for solvent loss	until ca. 300 deg C	—	—	Text Approximate	5 · 2.5 Thermal Properties · Figure S5