Spectroscopy — Colossal Increase in Electric Current and High Rectification Ratio in a Photoconducting, Self-Cleaning, and Luminescent Schottky Barrier NMOF Diode

2 measurement groups · 9 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

NMOF-1 bulk nanosheets/powder · Nanosheet

KBr pellet FT-IR; custom Raman with 632.8 nm HeNe laser, about 8 mW

Measurement source: 3-4, 13 · Physical Measurements; FT-IR; Raman Spectrum · Figures S3-S4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
asymmetric carboxylate stretch	1598 cm-1	—	—	Text Exact Reported	2 · Results and Discussion · Figure S3
carboxylate stretch separation	~198 cm-1	—	—	Text Approximate	2 · Results and Discussion · Figure S3
NMOF-1 FT-IR peak list	3460(s), 2917(s), 2834(s), 1695(s), 1598(s), 1400(s), 1215(s), 1014(w), 748(w), 504(w) cm-1	—	—	Text Exact Reported	10 · Synthesis of NMOF-1
symmetric carboxylate stretch	1400 cm-1	—	—	Text Exact Reported	2 · Results and Discussion · Figure S3

NMOF-1 bulk nanosheets/powder · Nanosheet

THF dispersion and solid-state emission/absorption measurements

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
THF PL excitation wavelength	lambda_ex = 390 nm	—	—	Text Exact Reported	3-4 · Results and Discussion · Figure S11
THF emission maximum	460 nm, lambda_ex = 390 nm	—	—	Text Exact Reported	3-4 · Results and Discussion · Figure S11
solid-state PL excitation wavelength	380 nm	—	—	Text Exact Reported	3-4 · Results and Discussion · Figure 2b
solid-state emission maximum	475 nm upon excitation at 380 nm	—	—	Text Exact Reported	3-4 · Results and Discussion · Figure 2b
solid-state UV peak maximum	375 nm	—	—	Text Exact Reported	3-4 · Results and Discussion · Figure S12