Spectroscopy — Oriented Thin Films of Electroactive Triphenylene Catecholate-Based Two-Dimensional MetalOrganic Frameworks

4 measurement groups · 17 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Ni-CAT-1 thin film on quartz · Thin Film

100 fs pump-probe; pump 400 nm for Figure 5 and 350 nm control in SI; probe broad-band white light; time delay up to 3 ns.

Geometry: quartz-supported Ni-CAT-1 film
Context: pristine
Measurement source: p006 · Ultrafast transient absorption · Figure 5; Figure S5.6

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
350 nm excitation density	29 uJ cm^-2	—	—	Caption Exact Reported	S35 · Transient absorption plots · Figure S5.6
control pump wavelength	350 nm	—	—	Caption Exact Reported	S35 · Transient absorption plots · Figure S5.6
excitation density	173 uJ cm^-2 per pulse	—	—	Caption Exact Reported	p005 · Figure caption · Figure 5
TA fitted lifetime at 116 uJ cm^-2	tau = 2.4 ns	—	+/- 0.5 ns	Visual Estimate Approximate	p005 · TA kinetics · Figure 5b
TA fitted lifetime at 173 uJ cm^-2	tau = 2.1 ns	—	+/- 0.3 ns	Visual Estimate Approximate	p005 · TA kinetics · Figure 5b
long-time fitted lifetime	longer than 2 ns	—	—	Text Approximate	p006 · TA dynamics · Figure 5b
pump wavelength	400 nm	—	—	Caption Exact Reported	p005 · Figure caption · Figure 5
signal remaining after 3 ns	nearly 15% of initial signal	—	—	Text Approximate	p006 · TA dynamics · Figure 5b

Ni-CAT-1 thin film on quartz · Thin Film

Excited at 378 nm, measured at 545 nm; PicoQuant FluoTime 300 setup.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
mono-exponential PL decay lifetime	81 ps	—	—	Caption Exact Reported	S36 · TSCPC data · Figure S5.7

Co-CAT-1 thin film on quartz · Thin Film

Transmission UV-vis/NIR with integrating sphere on quartz films; PL with 378 nm excitation.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
direct Tauc band gap	2.95 eV	—	—	Text Exact Reported	p006 · UV-vis spectroscopy · Figure 4b
broad absorption band	around 610 nm	—	—	Text Approximate	p006 · UV-vis spectroscopy · Figure 4a
absorption onset	around 420 nm	—	—	Text Approximate	p006 · UV-vis spectroscopy · Figure 4a
PL maximum	around 570 nm	—	—	Text Approximate	p006 · PL spectroscopy · Figure 4c

Ni-CAT-1 thin film on quartz · Thin Film

Transmission UV-vis/NIR with integrating sphere on quartz films; PL with 378 nm excitation.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
direct Tauc band gapMarked as a best value within this paper	2.98 eV	—	—	Text Exact Reported	p006 · UV-vis spectroscopy · Figure 4b
broad absorption band	around 610 nm	—	—	Text Approximate	p006 · UV-vis spectroscopy · Figure 4a
absorption onset	around 420 nm	—	—	Text Approximate	p006 · UV-vis spectroscopy · Figure 4a
PL maximum	around 550 nm	—	—	Text Approximate	p006 · PL spectroscopy · Figure 4c