Electrochemistry Application — Oriented Thin Films of Electroactive Triphenylene Catecholate-Based Two-Dimensional MetalOrganic Frameworks

3 measurement groups · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

cyclic voltammetry

Voltammetry

Ni-CAT-1 film on FTO for electrochemistry · Electrode

Three-electrode CV cell assembled in argon-filled glove box; MOF/FTO working electrode, Pt wire counter, Ag wire reference; 0.1 M NBu4PF6 in methylene chloride; scan -0.2 to 1.4 V vs ferrocene at 20 mV s^-1; film activated at 120 degC in vacuum before use.

Atmosphere: argon-filled glove box
Geometry: MOF thin-film working electrode
Context: pristine
Measurement source: S32-S33 · Cyclic voltammetry analysis · Figure S5.3

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CV scan rate	20 mV s^-1	—	—	Text Exact Reported	S33 · Cyclic voltammetry analysis · Figure S5.3

differential pulsed voltammetry / energy-level assignment

Voltammetry

Oriented Ni-CAT-1 thin film on gold · Thin Film

Oriented thin Ni-CAT-1 film grown on gold substrate, immersed in 0.1 M NBu4PF6 in dichloromethane; HOMO extracted from differential pulsed voltammetry and LUMO calculated by adding Tauc band gap.

Atmosphere: not specified in main text for DPV measurement
Geometry: Au-supported oriented Ni-CAT-1 thin-film electrode
Context: pristine
Measurement source: p006 · Extraction of Charge Carriers · Figure S5.5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
HOMO level	-5.9 eV	—	—	Text Exact Reported	p006 · Extraction of Charge Carriers · Figure S5.5
LUMO level	-2.9 eV	—	—	Calculated From Reported Exact Reported	p006 · Extraction of Charge Carriers · Figure S5.5

current-voltage photovoltaic measurement

Electrical conductivity

ITO/Ni-CAT-1/Al photovoltaic device · Electrode

J-V under AM 1.5G illumination calibrated to 100 mW cm^-2 using Solar Light Model 16S simulator and Keithley 2400 SourceMeter.

Geometry: ITO/Ni-CAT-1/Al solar-cell stack
Context: application_device
Measurement source: p006 · Extraction of Charge Carriers · Figure 5c

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
fill factor	around 30%	—	—	Text Approximate	p006 · Extraction of Charge Carriers · Figure 5c
illumination intensity	100 mW cm^-2	—	—	Caption Exact Reported	p005 · Figure caption · Figure 5c
short-circuit current density Jsc	8.76 x 10^-4 mA cm^-2	—	—	Text Exact Reported	p006 · Extraction of Charge Carriers · Figure 5c
open-circuit voltage Voc	156 mV	—	—	Text Exact Reported	p006 · Extraction of Charge Carriers · Figure 5c