Synthesis · Oriented Thin Films of Electroactive Triphenylene Catecholate-Based Two-Dimensional MetalOrganic Frameworks

17 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Complete recipeSource: SI

Route 1: Solvothermal

S6 · Bulk Synthesis - Co-CAT-1

Metal precursorscobalt(II) acetate tetrahydrate (0.0207 mmol, 5 mg)

Linker precursors2,3,6,7,10,11-hexahydroxytriphenylene (0.0107 mmol, 3.5 mg)

Solvents1 mL 1-propanol + 1 mL distilled water (1:1 v:v)

Additives1-propanol acts as solvent/modulator

Atmosphereambient atmosphere loading; tightly capped culture tube

Temperature85

Time18

Oxidant / reductantnone reported

Work-upwashed three times with 10 mL dry acetone; isolated by centrifugation

Activationdried under dynamic vacuum prior to analysis

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	2,3,6,7,10,11-hexahydroxytriphenylene	0.0107 mmol; 3.5 mg	S6 · Bulk Synthesis - Co-CAT-1
Metal Source	cobalt(II) acetate tetrahydrate	0.0207 mmol; 5 mg	S6 · Bulk Synthesis - Co-CAT-1
Solvent	1-propanol	1 mL	S6 · Bulk Synthesis - Co-CAT-1
Solvent	distilled water	1 mL	S6 · Bulk Synthesis - Co-CAT-1

Complete recipeSource: SI

Route 2: Other

S9 · Transparent/oxide-substrate VAC synthesis

Metal precursorscobalt acetate (11.0 x 10^-3 mmol; 3 mg)

Linker precursorsHHTP precursor (5.4 x 10^-3 mmol; 1.75 mg)

Solventswater and 1-propanol (1 mL : 1 mL) precursor solution; autoclave reservoir water and 1-propanol (2.5 mL : 2.5 mL)

Additives50 uL salicylic-acid solution (0.89 mmol; 125 mg); salicylic acid 11.23 mmol L^-1

Atmospheresealed autoclave; materials generally handled in air unless otherwise noted

Temperature85

Time18

Substrate orientationclean 1.2 x 1.0 cm glass substrate

Oxidant / reductantnone reported

Work-upcool 10 min, rinse with dry acetone; ITO films further dried under dynamic vacuum in main text

Activationnone reported after synthesis except electrochemical samples activated separately

Scalability contextFour set-ups were placed in the autoclave.

Show 5 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	HHTP precursor	5.4 x 10^-3 mmol; 1.75 mg · 5.35 mmol L^-1 in deposited precursor solution	S9 · Transparent/oxide-substrate VAC synthesis
Metal Source	cobalt acetate	as listed in precursor_metals · NiAc 10.7 mmol L^-1 or CoAc 12.85 mmol L^-1 where reported	S9 · Transparent/oxide-substrate VAC synthesis
Acid	50 uL salicylic-acid solution	50 uL salicylic-acid solution (0.89 mmol; 125 mg); salicylic acid 11.23 mmol L^-1 · as listed in additives	S9 · Transparent/oxide-substrate VAC synthesis
Solvent	water	1 mL precursor + 2.5 mL reservoir	S9 · Transparent/oxide-substrate VAC synthesis
Solvent	1-propanol	1 mL precursor + 2.5 mL reservoir	S9 · Transparent/oxide-substrate VAC synthesis

Complete recipeSource: Both

Route 3: Other

S8 · Synthesis of Ni-, Co- and Cu-CAT-1 films on gold surfaces · Figure S2.1

Metal precursorscobalt acetate (5.0 x 10^-3 mmol; 1.25 mg)

Linker precursorsHHTP precursor (2.69 x 10^-3 mmol; 0.875 mg)

SolventsPrecursor solution: water and 1-propanol (1.5 mL : 1.5 mL); vapour reservoir: water and 1-propanol (2.5 mL : 2.5 mL)

Additivesnone beyond 1-propanol; no acid modulator for Au route

Atmospheresealed glass autoclave/bottle; materials generally handled in air unless noted

Temperature85

Time3.5

Substrate orientation1.2 x 1.0 cm gold substrate on Raschig-ring/glass-spacer platform above solvent bath

Oxidant / reductantnone reported

Work-upcool 10 min, rinse substrate with dry acetone

Activationnone reported for Au film after synthesis

Scalability contextFour set-ups were placed in the autoclave for each run.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	HHTP precursor	2.69 x 10^-3 mmol; 0.875 mg · 0.899 mmol L^-1 in deposited solution	S8 · Synthesis of Ni-, Co- and Cu-CAT-1 films on gold surfaces · Figure S2.1
Metal Source	cobalt acetate	5.0 x 10^-3 mmol; 1.25 mg · 1.674 mmol L^-1 MOAc in deposited solution	S8 · Synthesis of Ni-, Co- and Cu-CAT-1 films on gold surfaces · Figure S2.1
Solvent	water	1.5 mL precursor + 2.5 mL reservoir	S8 · Synthesis of Ni-, Co- and Cu-CAT-1 films on gold surfaces · Figure S2.1
Solvent	1-propanol	1.5 mL precursor + 2.5 mL reservoir	S8 · Synthesis of Ni-, Co- and Cu-CAT-1 films on gold surfaces · Figure S2.1

Partial recipeSource: Both

Route 4: Other

p005 · Transparent/oxide-substrate VAC synthesis

Metal precursorscobalt acetate, amount not separately given for ITO in SI

Linker precursorsHHTP precursor (5.4 x 10^-3 mmol; 1.75 mg)

Solventswater and 1-propanol (1 mL : 1 mL) precursor solution; autoclave reservoir water and 1-propanol (2.5 mL : 2.5 mL)

Additivessalicylic acid modulator, inferred from main text

Atmospheresealed autoclave; materials generally handled in air unless otherwise noted

Temperature85

Time18

Substrate orientationITO-coated glass

Oxidant / reductantnone reported

Work-upcool 10 min, rinse with dry acetone; ITO films further dried under dynamic vacuum in main text

Activationnone reported after synthesis except electrochemical samples activated separately

Scalability contextFour set-ups were placed in the autoclave.

Show 5 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	HHTP precursor	5.4 x 10^-3 mmol; 1.75 mg · 5.35 mmol L^-1 in deposited precursor solution	p005 · Transparent/oxide-substrate VAC synthesis
Metal Source	cobalt acetate, amount not separately given for ITO in SI	as listed in precursor_metals · NiAc 10.7 mmol L^-1 or CoAc 12.85 mmol L^-1 where reported	p005 · Transparent/oxide-substrate VAC synthesis
Acid	salicylic acid modulator, inferred from main text	salicylic acid modulator, inferred from main text · as listed in additives	p005 · Transparent/oxide-substrate VAC synthesis
Solvent	water	1 mL precursor + 2.5 mL reservoir	p005 · Transparent/oxide-substrate VAC synthesis
Solvent	1-propanol	1 mL precursor + 2.5 mL reservoir	p005 · Transparent/oxide-substrate VAC synthesis

Complete recipeSource: Both

Route 5: Other

p007 · Transparent/oxide-substrate VAC synthesis

Metal precursorscobalt acetate (11.0 x 10^-3 mmol; 3 mg)

Linker precursorsHHTP precursor (5.4 x 10^-3 mmol; 1.75 mg)

Solventswater and 1-propanol (1 mL : 1 mL) precursor solution; autoclave reservoir water and 1-propanol (2.5 mL : 2.5 mL)

Additives50 uL salicylic-acid solution (0.89 mmol; 125 mg); salicylic acid 11.23 mmol L^-1

Atmospheresealed autoclave; materials generally handled in air unless otherwise noted

Temperature85

Time18

Substrate orientationquartz substrate, 2.0 x 1.5 cm prepared by cutting/cleaning

Oxidant / reductantnone reported

Work-upcool 10 min, rinse with dry acetone; ITO films further dried under dynamic vacuum in main text

Activationnone reported after synthesis except electrochemical samples activated separately

Scalability contextFour set-ups were placed in the autoclave.

Show 5 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	HHTP precursor	5.4 x 10^-3 mmol; 1.75 mg · 5.35 mmol L^-1 in deposited precursor solution	p007 · Transparent/oxide-substrate VAC synthesis
Metal Source	cobalt acetate	as listed in precursor_metals · NiAc 10.7 mmol L^-1 or CoAc 12.85 mmol L^-1 where reported	p007 · Transparent/oxide-substrate VAC synthesis
Acid	50 uL salicylic-acid solution	50 uL salicylic-acid solution (0.89 mmol; 125 mg); salicylic acid 11.23 mmol L^-1 · as listed in additives	p007 · Transparent/oxide-substrate VAC synthesis
Solvent	water	1 mL precursor + 2.5 mL reservoir	p007 · Transparent/oxide-substrate VAC synthesis
Solvent	1-propanol	1 mL precursor + 2.5 mL reservoir	p007 · Transparent/oxide-substrate VAC synthesis

Complete recipeSource: SI

Route 6: Other

S7 · Preparation of Ni-, Co-, Cu-CAT-1 pellets

Metal precursorspre-synthesised M-CAT-1 bulk powder

Linker precursorspre-synthesised M-CAT-1 bulk powder

Atmosphereambient not specified

Oxidant / reductantnone

Work-uppressed with standard Paul-Weber KBr press at 45 kg cm^-2

Activationnone reported for pellet pressing

Scalability contextPellet made from several bulk batches.

Show 1 structured reagent record

Role	Reagent	Amount / concentration	Source
Other	M-CAT-1 powder	95.8 mg	S7 · Preparation of Ni-, Co-, Cu-CAT-1 pellets

Complete recipeSource: SI

Route 7: Solvothermal

S7 · Bulk Synthesis - Cu-CAT-1

Metal precursorscopper(II) trifluoroacetylacetonate (0.0162 mmol, 6 mg)

Linker precursors2,3,6,7,10,11-hexahydroxytriphenylene (0.0107 mmol, 3.5 mg)

Solvents1 mL 1-propanol + 1 mL distilled water (1:1 v:v)

Additives1-propanol acts as solvent/modulator

Atmosphereambient atmosphere loading; tightly capped culture tube

Temperature85

Time18

Oxidant / reductantnone reported

Work-upwashed three times with 10 mL dry acetone; isolated by centrifugation

Activationdried under dynamic vacuum prior to analysis

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	2,3,6,7,10,11-hexahydroxytriphenylene	0.0107 mmol; 3.5 mg	S7 · Bulk Synthesis - Cu-CAT-1
Metal Source	copper(II) trifluoroacetylacetonate	0.0162 mmol; 6 mg	S7 · Bulk Synthesis - Cu-CAT-1
Solvent	1-propanol	1 mL	S7 · Bulk Synthesis - Cu-CAT-1
Solvent	distilled water	1 mL	S7 · Bulk Synthesis - Cu-CAT-1

Partial recipeSource: Both

Route 8: Other

p004 · Highly Oriented Thin M-CAT-1 Films on Gold Surfaces · Figure S4.13

Metal precursorscopper nitrate trihydrate (amount not provided in accessible text)

Linker precursorsHHTP precursor, inferred from same Cu-CAT-1 VAC screening

Solventsnot fully restated; described as same VAC conditions

Additivesnot reported

Atmospheresealed autoclave inferred

Temperature85

Substrate orientationgold substrate; rods aligned perpendicularly to surface

Oxidant / reductantnone reported

Work-upnot fully restated; likely acetone rinse as for Au VAC route

Activationnone reported

Scalability contextScreening route improved Cu film packing and roughness.

Show 2 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	copper nitrate trihydrate	not reported	p004 · Highly Oriented Thin M-CAT-1 Films on Gold Surfaces · Figure S4.13
Linker	HHTP	not fully restated	p004 · Highly Oriented Thin M-CAT-1 Films on Gold Surfaces · Figure S4.13

Complete recipeSource: Both

Route 9: Other

S8 · Synthesis of Ni-, Co- and Cu-CAT-1 films on gold surfaces · Figure S2.1

Metal precursorscopper trifluoroacetylacetonate (5.0 x 10^-3 mmol; 1.25 mg)

Linker precursorsHHTP precursor (2.69 x 10^-3 mmol; 0.875 mg)

SolventsPrecursor solution: water and 1-propanol (1.5 mL : 1.5 mL); vapour reservoir: water and 1-propanol (2.5 mL : 2.5 mL)

Additivesnone beyond 1-propanol; no acid modulator for Au route

Atmospheresealed glass autoclave/bottle; materials generally handled in air unless noted

Temperature85

Time3.5

Substrate orientation1.2 x 1.0 cm gold substrate on Raschig-ring/glass-spacer platform above solvent bath

Oxidant / reductantnone reported

Work-upcool 10 min, rinse substrate with dry acetone

Activationnone reported for Au film after synthesis

Scalability contextFour set-ups were placed in the autoclave for each run.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	HHTP precursor	2.69 x 10^-3 mmol; 0.875 mg · 0.899 mmol L^-1 in deposited solution	S8 · Synthesis of Ni-, Co- and Cu-CAT-1 films on gold surfaces · Figure S2.1
Metal Source	copper trifluoroacetylacetonate	5.0 x 10^-3 mmol; 1.25 mg · 1.674 mmol L^-1 MOAc in deposited solution	S8 · Synthesis of Ni-, Co- and Cu-CAT-1 films on gold surfaces · Figure S2.1
Solvent	water	1.5 mL precursor + 2.5 mL reservoir	S8 · Synthesis of Ni-, Co- and Cu-CAT-1 films on gold surfaces · Figure S2.1
Solvent	1-propanol	1.5 mL precursor + 2.5 mL reservoir	S8 · Synthesis of Ni-, Co- and Cu-CAT-1 films on gold surfaces · Figure S2.1

Complete recipeSource: SI

Route 10: Other

S7 · Preparation of Ni-, Co-, Cu-CAT-1 pellets

Metal precursorspre-synthesised M-CAT-1 bulk powder

Linker precursorspre-synthesised M-CAT-1 bulk powder

Atmosphereambient not specified

Oxidant / reductantnone

Work-uppressed with standard Paul-Weber KBr press at 45 kg cm^-2

Activationnone reported for pellet pressing

Scalability contextPellet made from several bulk batches.

Show 1 structured reagent record

Role	Reagent	Amount / concentration	Source
Other	M-CAT-1 powder	110.3 mg	S7 · Preparation of Ni-, Co-, Cu-CAT-1 pellets

Complete recipeSource: SI

Route 11: Solvothermal

S6 · Bulk Synthesis - Ni-CAT-1

Metal precursorsnickel(II) acetate tetrahydrate (0.0201 mmol, 5 mg)

Linker precursors2,3,6,7,10,11-hexahydroxytriphenylene (0.0107 mmol, 3.5 mg)

Solvents1 mL 1-propanol + 1 mL distilled water (1:1 v:v)

Additives1-propanol acts as solvent/modulator

Atmosphereambient atmosphere loading; tightly capped culture tube

Temperature85

Time18

Oxidant / reductantnone reported

Work-upwashed three times with 10 mL dry acetone; isolated by centrifugation

Activationdried under dynamic vacuum prior to analysis

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	2,3,6,7,10,11-hexahydroxytriphenylene	0.0107 mmol; 3.5 mg	S6 · Bulk Synthesis - Ni-CAT-1
Metal Source	nickel(II) acetate tetrahydrate	0.0201 mmol; 5 mg	S6 · Bulk Synthesis - Ni-CAT-1
Solvent	1-propanol	1 mL	S6 · Bulk Synthesis - Ni-CAT-1
Solvent	distilled water	1 mL	S6 · Bulk Synthesis - Ni-CAT-1

Complete recipeSource: Both

Route 12: Other

S9-S10 · Solar Cell device fabrication · Figure S2.2

Metal precursorspre-grown Ni-CAT-1 film on ITO; aluminium top electrode

Linker precursorspre-grown Ni-CAT-1 film

Atmospherethermal evaporation conditions not specified

Substrate orientationITO bottom electrode / Ni-CAT-1 / Al

Oxidant / reductantnone

Work-up40 nm aluminium thermally evaporated as top electrode and electron contact

Activationnone reported for completed device

Scalability contextBasic device architecture used for proof-of-principle charge extraction.

Show 2 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	aluminium	40 nm thermally evaporated	S9-S10 · Solar Cell device fabrication · Figure S2.2
Other	ITO/Ni-CAT-1 substrate	one device substrate	S9-S10 · Solar Cell device fabrication · Figure S2.2

Complete recipeSource: SI

Route 13: Other

S9 · Transparent/oxide-substrate VAC synthesis

Metal precursorsnickel acetate (10.0 x 10^-3 mmol; 2.5 mg)

Linker precursorsHHTP precursor (5.4 x 10^-3 mmol; 1.75 mg)

Solventswater and 1-propanol (1 mL : 1 mL) precursor solution; autoclave reservoir water and 1-propanol (2.5 mL : 2.5 mL)

Additivesacetic acid (50 uL); HOAc 1.745 mol L^-1 in deposited precursor solution

Atmospheresealed autoclave; materials generally handled in air unless otherwise noted

Temperature85

Time18

Substrate orientationglass substrate per heading/main transparent-substrate discussion; SI recipe line appears to say ITO

Oxidant / reductantnone reported

Work-upcool 10 min, rinse with dry acetone; ITO films further dried under dynamic vacuum in main text

Activationnone reported after synthesis except electrochemical samples activated separately

Scalability contextFour set-ups were placed in the autoclave.

Show 5 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	HHTP precursor	5.4 x 10^-3 mmol; 1.75 mg · 5.35 mmol L^-1 in deposited precursor solution	S9 · Transparent/oxide-substrate VAC synthesis
Metal Source	nickel acetate	as listed in precursor_metals · NiAc 10.7 mmol L^-1 or CoAc 12.85 mmol L^-1 where reported	S9 · Transparent/oxide-substrate VAC synthesis
Acid	acetic acid	acetic acid (50 uL); HOAc 1.745 mol L^-1 in deposited precursor solution · as listed in additives	S9 · Transparent/oxide-substrate VAC synthesis
Solvent	water	1 mL precursor + 2.5 mL reservoir	S9 · Transparent/oxide-substrate VAC synthesis
Solvent	1-propanol	1 mL precursor + 2.5 mL reservoir	S9 · Transparent/oxide-substrate VAC synthesis

Complete recipeSource: Both

Route 14: Other

S8 · Synthesis of Ni-, Co- and Cu-CAT-1 films on gold surfaces · Figure S2.1

Metal precursorsnickel acetate (5.0 x 10^-3 mmol; 1.25 mg)

Linker precursorsHHTP precursor (2.69 x 10^-3 mmol; 0.875 mg)

SolventsPrecursor solution: water and 1-propanol (1.5 mL : 1.5 mL); vapour reservoir: water and 1-propanol (2.5 mL : 2.5 mL)

Additivesnone beyond 1-propanol; no acid modulator for Au route

Atmospheresealed glass autoclave/bottle; materials generally handled in air unless noted

Temperature85

Time3.5

Substrate orientation1.2 x 1.0 cm gold substrate on Raschig-ring/glass-spacer platform above solvent bath

Oxidant / reductantnone reported

Work-upcool 10 min, rinse substrate with dry acetone

Activationnone reported for Au film after synthesis

Scalability contextFour set-ups were placed in the autoclave for each run.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	HHTP precursor	2.69 x 10^-3 mmol; 0.875 mg · 0.899 mmol L^-1 in deposited solution	S8 · Synthesis of Ni-, Co- and Cu-CAT-1 films on gold surfaces · Figure S2.1
Metal Source	nickel acetate	5.0 x 10^-3 mmol; 1.25 mg · 1.674 mmol L^-1 MOAc in deposited solution	S8 · Synthesis of Ni-, Co- and Cu-CAT-1 films on gold surfaces · Figure S2.1
Solvent	water	1.5 mL precursor + 2.5 mL reservoir	S8 · Synthesis of Ni-, Co- and Cu-CAT-1 films on gold surfaces · Figure S2.1
Solvent	1-propanol	1.5 mL precursor + 2.5 mL reservoir	S8 · Synthesis of Ni-, Co- and Cu-CAT-1 films on gold surfaces · Figure S2.1

Complete recipeSource: SI

Route 15: Other

S8-S9 · Transparent/oxide-substrate VAC synthesis

Metal precursorsnickel acetate (10.0 x 10^-3 mmol; 2.5 mg)

Linker precursorsHHTP precursor (5.4 x 10^-3 mmol; 1.75 mg)

Solventswater and 1-propanol (1 mL : 1 mL) precursor solution; autoclave reservoir water and 1-propanol (2.5 mL : 2.5 mL)

Additivesacetic acid (50 uL); HOAc 1.745 mol L^-1 in deposited precursor solution

Atmospheresealed autoclave; materials generally handled in air unless otherwise noted

Temperature85

Time18

Substrate orientationclean 1.2 x 1.0 cm ITO substrate

Oxidant / reductantnone reported

Work-upcool 10 min, rinse with dry acetone; ITO films further dried under dynamic vacuum in main text

Activationnone reported after synthesis except electrochemical samples activated separately

Scalability contextFour set-ups were placed in the autoclave.

Show 5 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	HHTP precursor	5.4 x 10^-3 mmol; 1.75 mg · 5.35 mmol L^-1 in deposited precursor solution	S8-S9 · Transparent/oxide-substrate VAC synthesis
Metal Source	nickel acetate	as listed in precursor_metals · NiAc 10.7 mmol L^-1 or CoAc 12.85 mmol L^-1 where reported	S8-S9 · Transparent/oxide-substrate VAC synthesis
Acid	acetic acid	acetic acid (50 uL); HOAc 1.745 mol L^-1 in deposited precursor solution · as listed in additives	S8-S9 · Transparent/oxide-substrate VAC synthesis
Solvent	water	1 mL precursor + 2.5 mL reservoir	S8-S9 · Transparent/oxide-substrate VAC synthesis
Solvent	1-propanol	1 mL precursor + 2.5 mL reservoir	S8-S9 · Transparent/oxide-substrate VAC synthesis

Partial recipeSource: Both

Route 16: Other

p007 · Experimental Methods - Synthesis of Ni-CAT-1 Films on Quartz and ITO Substrates

Metal precursorsnickel acetate (10.0 x 10^-3 mmol; 2.5 mg)

Linker precursorsHHTP precursor (5.4 x 10^-3 mmol; 1.75 mg)

Solventswater and 1-propanol (1 mL : 1 mL) precursor solution; autoclave reservoir water and 1-propanol (2.5 mL : 2.5 mL)

Additivesacetic acid (50 uL); HOAc 1.745 mol L^-1 in deposited precursor solution

Atmospheresealed autoclave; materials generally handled in air unless otherwise noted

Temperature85

Time18

Substrate orientationquartz substrate, 2.0 x 1.5 cm prepared by cutting/cleaning

Oxidant / reductantnone reported

Work-upcool 10 min, rinse with dry acetone; ITO films further dried under dynamic vacuum in main text

Activationnone reported after synthesis except electrochemical samples activated separately

Scalability contextFour set-ups were placed in the autoclave.

Show 5 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	HHTP precursor	5.4 x 10^-3 mmol; 1.75 mg · 5.35 mmol L^-1 in deposited precursor solution	p007 · Experimental Methods - Synthesis of Ni-CAT-1 Films on Quartz and ITO Substrates
Metal Source	nickel acetate	as listed in precursor_metals · NiAc 10.7 mmol L^-1 or CoAc 12.85 mmol L^-1 where reported	p007 · Experimental Methods - Synthesis of Ni-CAT-1 Films on Quartz and ITO Substrates
Acid	acetic acid	acetic acid (50 uL); HOAc 1.745 mol L^-1 in deposited precursor solution · as listed in additives	p007 · Experimental Methods - Synthesis of Ni-CAT-1 Films on Quartz and ITO Substrates
Solvent	water	1 mL precursor + 2.5 mL reservoir	p007 · Experimental Methods - Synthesis of Ni-CAT-1 Films on Quartz and ITO Substrates
Solvent	1-propanol	1 mL precursor + 2.5 mL reservoir	p007 · Experimental Methods - Synthesis of Ni-CAT-1 Films on Quartz and ITO Substrates

Complete recipeSource: SI

Route 17: Other

S7 · Preparation of Ni-, Co-, Cu-CAT-1 pellets

Metal precursorspre-synthesised M-CAT-1 bulk powder

Linker precursorspre-synthesised M-CAT-1 bulk powder

Atmosphereambient not specified

Oxidant / reductantnone

Work-uppressed with standard Paul-Weber KBr press at 45 kg cm^-2

Activationnone reported for pellet pressing

Scalability contextPellet made from several bulk batches.

Show 1 structured reagent record

Role	Reagent	Amount / concentration	Source
Other	M-CAT-1 powder	110.5 mg	S7 · Preparation of Ni-, Co-, Cu-CAT-1 pellets