Spectroscopy — Unleashing the room temperature boronization: Blooming of Ni-ZIF nanobuds for efficient photo/electro catalysis of water

5 measurement groups · 35 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

24-BNZ powder / 24 h boronized Ni-ZIF · Powder

Pure 24-BNZ coated on Al foil; weight percent and atom percent table in SI.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
24BNZ EDS B atom percent	7.130 atom%	—	—	SI Table Exact Reported	4 · Supporting data · Fig. S3
24BNZ EDS B weight percent	3.463 wt%	—	—	SI Table Exact Reported	4 · Supporting data · Fig. S3
24BNZ EDS C atom percent	35.363 atom%	—	—	SI Table Exact Reported	4 · Supporting data · Fig. S3
24BNZ EDS C weight percent	19.085 wt%	—	—	SI Table Exact Reported	4 · Supporting data · Fig. S3
24BNZ EDS N atom percent	16.275 atom%	—	—	SI Table Exact Reported	4 · Supporting data · Fig. S3
24BNZ EDS N weight percent	10.243 wt%	—	—	SI Table Exact Reported	4 · Supporting data · Fig. S3
24BNZ EDS Ni atom percent	19.577 atom%	—	—	SI Table Exact Reported	4 · Supporting data · Fig. S3
24BNZ EDS Ni weight percent	51.643 wt%	—	—	SI Table Exact Reported	4 · Supporting data · Fig. S3
24BNZ EDS O atom percent	21.654 atom%	—	—	SI Table Exact Reported	4 · Supporting data · Fig. S3
24BNZ EDS O weight percent	15.567 wt%	—	—	SI Table Exact Reported	4 · Supporting data · Fig. S3

48-BNZ powder / 48 h boronized Ni-ZIF · Powder

Pure 48-BNZ coated on Al foil; weight percent and atom percent table in SI.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
48BNZ EDS B atom percent	2.971 atom%	—	—	SI Table Exact Reported	5 · Supporting data · Fig. S4
48BNZ EDS B weight percent	1.040 wt%	—	—	SI Table Exact Reported	5 · Supporting data · Fig. S4
48BNZ EDS C atom percent	20.847 atom%	—	—	SI Table Exact Reported	5 · Supporting data · Fig. S4
48BNZ EDS C weight percent	8.112 wt%	—	—	SI Table Exact Reported	5 · Supporting data · Fig. S4
48BNZ EDS N atom percent	9.762 atom%	—	—	SI Table Exact Reported	5 · Supporting data · Fig. S4
48BNZ EDS N weight percent	4.430 wt%	—	—	SI Table Exact Reported	5 · Supporting data · Fig. S4
48BNZ EDS Ni atom percent	37.573 atom%	—	—	SI Table Exact Reported	5 · Supporting data · Fig. S4
48BNZ EDS Ni weight percent	71.465 wt%	—	—	SI Table Exact Reported	5 · Supporting data · Fig. S4
48BNZ EDS O atom percent	28.847 atom%	—	—	SI Table Exact Reported	5 · Supporting data · Fig. S4
48BNZ EDS O weight percent	14.952 wt%	—	—	SI Table Exact Reported	5 · Supporting data · Fig. S4

NZ powder / bare Ni-ZIF nanobuds · Powder

Pure Ni-ZIF (NZ) coated on Al foil; weight percent and atom percent table in SI.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
NZ EDS C atom percent	29.498 atom%	—	—	SI Table Exact Reported	3 · Supporting data · Fig. S2
NZ EDS C weight percent	12.470 wt%	—	—	SI Table Exact Reported	3 · Supporting data · Fig. S2
NZ EDS N atom percent	17.739 atom%	—	—	SI Table Exact Reported	3 · Supporting data · Fig. S2
NZ EDS N weight percent	8.745 wt%	—	—	SI Table Exact Reported	3 · Supporting data · Fig. S2
NZ EDS Ni atom percent	32.646 atom%	—	—	SI Table Exact Reported	3 · Supporting data · Fig. S2
NZ EDS Ni weight percent	67.458 wt%	—	—	SI Table Exact Reported	3 · Supporting data · Fig. S2
NZ EDS O atom percent	20.116 atom%	—	—	SI Table Exact Reported	3 · Supporting data · Fig. S2
NZ EDS O weight percent	11.327 wt%	—	—	SI Table Exact Reported	3 · Supporting data · Fig. S2

24-BNZ powder / 24 h boronized Ni-ZIF · Powder

NZ and 24-BNZ optical absorption and band-gap comparison; SI Fig. S14.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
24-BNZ optical band gap from Tauc plotMarked as a best value within this paper	3.3 eV	—	—	Figure Axis Exact Reported	15 · Supporting data · Fig. S14
NZ optical band gap from Tauc plot	3.5 eV	—	—	Figure Axis Exact Reported	15 · Supporting data · Fig. S14
24-BNZ band-gap change	Boronization reduces band gap relative to NZ	—	—	Qualitative Qualitative	15 · Supporting data · Fig. S14
NZ and 24-BNZ absorption peak ranges	approximately 260-300 nm, 350-490 nm, and 500-800 nm	—	—	Text Range	15 · Supporting data · Fig. S14

24-BNZ powder / 24 h boronized Ni-ZIF · Powder

Survey and high-resolution Ni 2p, O 1s, C 1s and B 1s spectra for NZ and 24-BNZ.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
24-BNZ B 1s B-metal peak	191.24 eV	—	—	Text Exact Reported	7 · 3.1 · Fig. 5e
24-BNZ B 1s oxidized borate peak	191.85 eV	—	—	Text Exact Reported	7 · 3.1 · Fig. 5e
24-BNZ O-B XPS peak	532.97 eV	—	—	Text Exact Reported	7 · 3.1 · Fig. 5c