Spectroscopy — Control of the Hydroquinone/Benzoquinone Redox State in High-Mobility Semiconducting Conjugated Coordination Polymers

3 measurement groups · 4 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

as-synthesised Ag4TTBQ black solid/nanocrystalline film product · Powder

Room-temperature UV-vis-NIR spectra collected with a UV-2000 Shimadzu spectrophotometer.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
optical band gap Eopt	0.5 eV	—	—	Text Rounded Reported	main p.2 · Results and Discussion · Figure 1d

as-synthesised Ag4TTHQ dark red/dark brown powder · Powder

Room-temperature UV-vis-NIR spectra collected with a UV-2000 Shimadzu spectrophotometer.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
optical band gap Eopt	1.5 eV	—	—	Text Rounded Reported	main p.2 · Results and Discussion · Figure 1d

as-synthesised Ag4TTHQ dark red/dark brown powder · Powder

IR and Raman spectra used to assign thiol deprotonation, hydroxyl retention and carbonyl formation.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ag4TTBQ carbonyl signal	sharp peak at approximately 1600 cm-1 assigned to C=O	—	approximately	Text Approximate	main p.3 · Results and Discussion · Figure 1e-f
Ag4TTHQ hydroxyl signal	hydroxy-group signal remains visible around 3300 cm-1 in Ag4TTHQ	—	approximately	Text Approximate	main p.3 · Results and Discussion · Figure 1e