Complete recipeSource: Both
Route 1: Liquid Liquid Interface
SI p.2 · Interface synthesis of Ag4TTBQ
Metal precursorssilver nitrate (AgNO3)
Linker precursorsTTHQ, oxidised in situ to TTBQ
Solventschlorobenzene and water
Additiveswater buffer layer
Atmospherenot specified for the interfacial reaction; solvents degassed before use
Temperature70
Time48
Substrate orientationchlorobenzene/water liquid-liquid interface
Oxidant / reductantIn situ HNO3 generated from AgNO3/protons oxidises TTHQ to TTBQ before coordination.
Work-upBlack interfacial film sonicated into nanocrystals; washed with DMF, water, methanol and diethyl ester.
Scalability context85 mg product, 63% yield.
Show 5 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Linker | TTHQ | 48mg, 0.2mmol | SI p.2 · Interface synthesis of Ag4TTBQ |
| Metal Source | AgNO3 | 116.8 mg, 0.7 mmol in 5 mL aqueous solution | SI p.2 · Interface synthesis of Ag4TTBQ |
| Solvent | chlorobenzene | 50 ml | SI p.2 · Interface synthesis of Ag4TTBQ |
| Solvent | pure water | 100 ml buffer layer | SI p.2 · Interface synthesis of Ag4TTBQ |
| Oxidant | in situ generated HNO3 from AgNO3/protons | dilute | SI p.2 · Interface synthesis of Ag4TTBQ |