Spectroscopy — Catalytic Metal-Organic Framework-Functionalized Inverse-Opal Architectured Polymeric Separator for High-Performance Li-S Batteries

3 measurement groups · 10 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Li-S coin cell with ZIF-PIO separator · Electrode

Raman spectra recorded at 2.4, 2.1, 1.7, 2.4 and 2.6 V during LiSB discharge/charge.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Raman peak for Li2S	345 cm-1 assigned to Li2S	—	—	Text Exact Reported	11 · Results and Discussion · Figure 6e
Raman peak for Li2S2	370 cm-1 assigned to Li2S2	—	—	Text Exact Reported	11 · Results and Discussion · Figure 6e
Raman peak for Li2S4	423 cm-1 assigned to Li2S4	—	—	Text Exact Reported	11 · Results and Discussion · Figure 6e
Raman peak for Li2S6	388 cm-1 assigned to Li2S6	—	—	Text Exact Reported	11 · Results and Discussion · Figure 6e
Raman peak for S8/Li2S8	152 cm-1 assigned to S8 and Li2S8	—	—	Text Exact Reported	11 · Results and Discussion · Figure 6e
Raman peak for S8/Li2S8	218 cm-1 assigned to S8 and Li2S8	—	—	Text Exact Reported	11 · Results and Discussion · Figure 6e
Raman peak for S8/Li2S8	470 cm-1 assigned to S8 and Li2S8	—	—	Text Exact Reported	11 · Results and Discussion · Figure 6e

ZIF-PIO-3 separator · Thin Film

Separators immersed in 0.2 mM Li2S6 in DOL/DME 1/1 for 5 min, then solution absorbance analysed.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
LiPS adsorption UV-vis response	absorbance increases at 260 and 280 nm for ZIF-PIO series	—	—	Qualitative Qualitative	6 · Results and Discussion · Figure S11

ZIF-PIO-3 separator · Thin Film

ZIF-67 nanoparticles and ZIF-PIO separator after 4 h immersion in LiPS solution.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Co2+ binding energy after LiPS immersion	Co2+ at about 782 eV	—	—	Text Approximate	9 · Results and Discussion · Figure S20a
Co3+ binding energy after LiPS immersion	Co3+ at about 780 eV	—	—	Text Approximate	9 · Results and Discussion · Figure S20a