cMOF Evidence Base
Spectroscopy — Chromone-Based Cd(II) Fluorescent Coordination Polymer Fabricated to Study Optoelectronic and Explosive Sensing Properties

Measurement evidence

Spectroscopy

Chromone-Based Cd(II) Fluorescent Coordination Polymer Fabricated to Study Optoelectronic and Explosive Sensing Properties · Mandal J., Dey A., Sarkar S. et al. · Inorganic Chemistry · 2024 · 4527-4544

2 measurement groups · 12 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Time-resolved fluorescence lifetime

Photoluminescence and fluorescence spectroscopy

Complex 1 light-yellow X-ray-quality crystals · Single Crystal

Lifetime of free CP dispersions and in the presence of TNP or DNP.

Context
pristine CP dispersions
Measurement source
S66 · Table S7 · Table S7
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
CP1 lifetime free3.97 ns——SI Table
Exact Reported		S66 · Table S7 · Table S7
CP1 lifetime with TNP3.03 ns——SI Table
Exact Reported		S66 · Table S7 · Table S7
CP2 lifetime free4.15 ns——SI Table
Exact Reported		S66 · Table S7 · Table S7
CP2 lifetime with TNP3.75 ns——SI Table
Exact Reported		S66 · Table S7 · Table S7
CP3 lifetime free4.08 ns——SI Table
Exact Reported		S66 · Table S7 · Table S7
CP3 lifetime with TNP3.37 ns——SI Table
Exact Reported		S66 · Table S7 · Table S7
CP4 lifetime freeMarked as a best value within this paper4.25 ns——SI Table
Exact Reported		S66 · Table S7 · Table S7
CP4 lifetime with TNPMarked as a best value within this paper3.90 ns——SI Table
Exact Reported		S66 · Table S7 · Table S7

UV-vis absorption spectroscopy and Tauc plot

UV-visible and optical absorption spectroscopy

Complex 1 light-yellow X-ray-quality crystals · Single Crystal

Absorption range 270-500 nm; direct optical band gap calculated with n = 1/2.

Context
pristine CP optical characterisation
Measurement source
S19 · Optical Characterization · Figure S30; Figure 5
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
CP1 optical direct band gap3.28 eV——Text
Exact Reported		S19 · Optical Characterization · Figure 5; Figure S30
CP2 optical direct band gap3.29 eV——Text
Exact Reported		S19 · Optical Characterization · Figure 5; Figure S30
CP3 optical direct band gapMarked as a best value within this paper3.30 eV——Text
Exact Reported		S19 · Optical Characterization · Figure 5; Figure S30
CP4 optical direct band gap3.29 eV——Text
Exact Reported		S19 · Optical Characterization · Figure 5; Figure S30