Fluorescence quenching titration in aqueous dispersion
Complex 1 light-yellow X-ray-quality crystals · Single Crystal
Each complex: 2 mg in 3 mL solvent, ultrasonic agitation for 1 h; analytes added by micropipette; emission monitored near 435 nm.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| CP1 DNP limit of detection | 78 uM | 0.000078 M | — | SI Table Exact Reported | S66 · Table S6 · Table S6 |
| CP1 DNP quenching efficiency | 40% | — | — | Text Exact Reported | 4535 and 4539 · Sensing; Conclusions · Figure S37 |
| CP1 TNP Stern-Volmer constant | 3.4 x 10^4 M-1 | — | — | SI Table Exact Reported | S66 · Table S6 · Table S6 |
| CP1 TNP limit of detection | 55 uM | 0.000055 M | — | SI Table Exact Reported | S66 · Table S6 · Table S6 |
| CP1 TNP quenching efficiency | 80% | — | — | Text Exact Reported | 4535 and 4539 · Sensing; Conclusions · Figure S37 |
| CP2 DNP limit of detection | 44 uM | 0.000044 M | — | SI Table Exact Reported | S66 · Table S6 · Table S6 |
| CP2 DNP quenching efficiency | 39% | — | — | Text Exact Reported | 4535 and 4539 · Sensing; Conclusions · Figure S37 |
| CP2 TNP Stern-Volmer constantMarked as a best value within this paper | 6.9 x 10^4 M-1 | — | — | SI Table Exact Reported | S66 · Table S6 · Table S6 |
| CP2 TNP limit of detection | 28 uM | 0.000028 M | — | SI Table Exact Reported | S66 · Table S6 · Table S6 |
| CP2 TNP quenching efficiencyMarked as a best value within this paper | 93% | — | — | Text Exact Reported | 4535 and 4539 · Sensing; Conclusions · Figure S37 |
| CP3 DNP limit of detectionMarked as a best value within this paper | 32 uM | 0.000032 M | — | SI Table Exact Reported | S66 · Table S6 · Table S6 |
| CP3 DNP quenching efficiency | 41% | — | — | Text Exact Reported | 4535 and 4539 · Sensing; Conclusions · Figure S37 |
| CP3 TNP Stern-Volmer constant | 2.3 x 10^4 M-1 | — | — | SI Table Exact Reported | S66 · Table S6 · Table S6 |
| CP3 TNP limit of detectionMarked as a best value within this paper | 27 uM | 0.000027 M | — | SI Table Exact Reported | S66 · Table S6 · Table S6 |
| CP3 TNP quenching efficiency | 68% | — | — | Text Exact Reported | 4535 and 4539 · Sensing; Conclusions · Figure S37 |
| CP4 DNP limit of detection | 41 uM | 0.000041 M | — | SI Table Exact Reported | S66 · Table S6 · Table S6 |
| CP4 DNP quenching efficiencyMarked as a best value within this paper | 45% | — | — | Text Exact Reported | 4535 and 4539 · Sensing; Conclusions · Figure S37 |
| CP4 TNP Stern-Volmer constant | 2.3 x 10^4 M-1 | — | — | SI Table Exact Reported | S66 · Table S6 · Table S6 |
| CP4 TNP limit of detection | 31 uM | 0.000031 M | — | SI Table Exact Reported | S66 · Table S6 · Table S6 |
| CP4 TNP quenching efficiency | 69% | — | — | Text Exact Reported | 4535 and 4539 · Sensing; Conclusions · Figure S37 |