cMOF Evidence Base
Diffraction Structure — Chromone-Based Cd(II) Fluorescent Coordination Polymer Fabricated to Study Optoelectronic and Explosive Sensing Properties

Measurement evidence

Diffraction Structure

Chromone-Based Cd(II) Fluorescent Coordination Polymer Fabricated to Study Optoelectronic and Explosive Sensing Properties · Mandal J., Dey A., Sarkar S. et al. · Inorganic Chemistry · 2024 · 4527-4544

2 measurement groups · 10 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Powder X-ray diffraction (PXRD)

X-ray diffraction and scattering

Complex 1 light-yellow X-ray-quality crystals · Single Crystal

PXRD patterns of complexes 1-4 compared with theoretical patterns from CIF files.

Context
pristine CP bulk phase purity
Measurement source
4530 · Synthesis and Characterization · Figures S13-S16
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
PXRD bulk purityExperimental PXRD patterns of complexes 1-4 compared with theoretical patterns from CIF files——Caption
Qualitative		S10-S12 · PXRD figures · Figures S13-S16
Water/sensing stability by PXRDNo changes observed in PXRD after DNP/TNP exposure for 4 days——Text
Qualitative		4536 · Sensing · Figures S102-S105

Single-crystal X-ray diffraction; Bruker SMART APEX-II CCD; Mo Kalpha radiation

X-ray diffraction and scattering

Complex 1 light-yellow X-ray-quality crystals · Single Crystal

Crystal data for complexes 1-4; data collected at 273(2) K for 1, 2 and 4 and 293(2) K for 3.

Temperature
273(2) or 293(2)
Context
pristine CP crystal structures
Measurement source
4539 · X-ray Crystallography · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
CP1 space groupP21/n——SI Table
Exact Reported		S62 · Table S1 · Table S1
CP1 unit cell volume2271.4(4)—(4)SI Table
Exact Reported		S62 · Table S1 · Table S1
CP2 space groupP21/c——SI Table
Exact Reported		S62 · Table S1 · Table S1
CP2 unit cell volume2545.0(4)—(4)SI Table
Exact Reported		S62 · Table S1 · Table S1
CP3 space groupP21/c——SI Table
Exact Reported		S62 · Table S1 · Table S1
CP3 unit cell volume1862.9(9)—(9)SI Table
Exact Reported		S62 · Table S1 · Table S1
CP4 space groupP21/c——SI Table
Exact Reported		S62 · Table S1 · Table S1
CP4 unit cell volume2402.5(2)—(2)SI Table
Exact Reported		S62 · Table S1 · Table S1