Spectroscopy — Synthesis of a Cd(ii) based 1D coordination polymer by: In situ ligand generation and fabrication of a photosensitive electronic device

3 measurement groups · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Yellow needle crystals / bulk compound 1 · Single Crystal

4500-500 cm^-1 range.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
S-H deprotonation IR feature disappears	2516 cm^-1 peak disappeared	—	—	Text Exact Reported	2000 · IR, TGA and PXRD analysis · Fig. S2
S-S bond IR peak	471 cm^-1	—	—	Text Exact Reported	2000 · IR, TGA and PXRD analysis · Fig. S2

Yellow needle crystals / bulk compound 1 · Single Crystal

Room-temperature luminescence relative to free 4-nvp ligand; lifetime by time-correlated single photon counting.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
compound 1 emission intensity relative to free ligand	emission intensity of 1 lowered with respect to free ligand	—	—	Text Qualitative	2001 · Photophysical properties · Fig. S5
compound 1 average lifetime relative to 4-nvp	average lifetime of compound 1 enhanced with respect to 4-nvp ligand	—	—	Text Qualitative	2001 · Photophysical properties · Fig. S6
free 4-nvp emission maximum	418 nm	—	—	Text Exact Reported	2001 · Photophysical properties · Fig. S5

Yellow needle crystals / bulk compound 1 · Single Crystal

Absorption spectrum measured in DMF medium over 300-800 nm.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
maximum energy absorption	~382 nm	—	—	Text Approximate	2001 · Optical characterization · Fig. 2
optical band gap from Tauc plot	Eg = 3.28 eV	—	—	Text Exact Reported	2001 · Optical characterization · Fig. 2