Dutta B., Jana R., Sinha C. et al. · Inorganic Chemistry Frontiers · 2018 · 1998-2005
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
The pristine compound 1 thin film forms an Al/compound 1/ITO Schottky barrier diode with enhanced conductivity, rectification ratio, mobility, and carrier concentration under illumination.
Caveat: Light intensity and spectral conditions are not specified in the main text.
2004 · Conclusions · Linked to 11 structured results
Compound 1 is classified by the authors as a wide-band-gap semiconductor based on a 3.28 eV optical band gap.
Caveat: Optical gap is from a Tauc plot; no uncertainty is reported.
2001 · Optical characterization · Fig. 2 · Linked to 2 structured results
The authors attribute the material's electrical conductivity and photosensitivity partly to structural flexibility arising from S-S bond formation.
Caveat: The link is an author interpretation; no direct structure-property perturbation experiment is reported.
1998 · Abstract · Linked to 4 structured results
The monomeric 2-mba ligand dimerises in situ through S-S bond formation to generate the 2,2'-dsb linker, producing the zigzag 1D Cd(II) coordination polymer.
Caveat: Supported by SCXRD, IR peak assignments, and SI structural tables; the oxidation medium is described qualitatively without a separate oxidant.
2000 · Structural descriptions · Scheme 1 · Linked to 4 structured results
Forward-bias transport is assigned to ohmic/thermionic behaviour at low bias and SCLC at higher bias.
Caveat: The paper does not tabulate fitted slopes from Fig. 6; mechanism assignment is based on the authors' qualitative region analysis.
2003 · Electrical characterization and photosensitivity · Fig. 6 · Linked to 3 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| [Cd(2,2'-dsb)(4-nvp)(DMF)(H2O)] (compound 1) | [Cd(2,2'-dsb)(4-nvp)(DMF)(H2O)]; elemental formula reported as C34H30CdN2O6S2Cd(II) centres · 2,2'-disulfanediyldibenzoate generated in situ from 2-mercaptobenzoic acid; 4-(1-naphthylvinyl)pyridine; coordinated DMF and water | 1D · PristineZigzag one-dimensional coordination polymer; 1D chains assemble into a 3D supramolecular architecture by hydrogen bonding, C-H...pi, and pi...pi interactions. | 1998 · Abstract |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Yellow needle crystals / bulk compound 1research_0197__mat__compound_1_cd_cp | Single Crystal · Target Sample · Pristine Framework | As-synthesised crystals; bulk sample used for PXRD, SCXRD, IR, TGA, and optical measurements. | 1999 · Synthesis of compound |
| DFT optimised coordination unit of compound 1research_0197__mat__compound_1_cd_cp | Model · Model System · Model | Single coordination unit used for Gaussian 09 DFT and TDDFT calculations. | 1999 · Computational study |
| Al/compound 1/ITO Schottky barrier diode thin filmresearch_0197__mat__compound_1_cd_cp | Thin Film · Target Sample · Pristine Framework | Compound 1 dispersed in DMF, spin-coated on cleaned ITO at 1200 rpm for 2 min, dried in vacuum at 50 deg C, then contacted with Al.ITO-coated glass with thermally evaporated Al top electrode · ~1 um | 1999 · Device fabrication and characterization |