Spectroscopy — Effect on Schottky behaviour of 1D coordination polymers by altering para-substituents on benzoate ligands

Measurement evidence

Spectroscopy

Effect on Schottky behaviour of 1D coordination polymers by altering para-substituents on benzoate ligands · Islam S., Datta J., Ahmed F. et al. · New Journal of Chemistry · 2018 · 13971-13977

2 measurement groups · 4 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Solid-state UV-vis absorbance with Tauc analysis

Compound 1 yellow block crystals · Single Crystal

Absorbance measured with PerkinElmer LAMBDA 35; direct and indirect optical transitions evaluated.

Context
pristine framework
Measurement source
13973 · Optical characterisation · Fig. 4
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
direct optical band gap2.71 eVText
Exact Reported
13973 · Optical characterisation · Fig. 4b
indirect optical band gapMarked as a best value within this paper2.59 eVText
Exact Reported
13973 · Optical characterisation · Fig. 4c

Solid-state UV-vis absorbance with Tauc analysis

Compound 2 yellow block crystals · Single Crystal

Absorbance measured with PerkinElmer LAMBDA 35; direct and indirect optical transitions evaluated.

Context
pristine framework
Measurement source
13973 · Optical characterisation · Fig. 4
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
direct optical band gap2.85 eVText
Exact Reported
13973 · Optical characterisation · Fig. 4b
indirect optical band gapMarked as a best value within this paper2.73 eVText
Exact Reported
13973 · Optical characterisation · Fig. 4c