cMOF Evidence Base
Porosity — From 2D to 3D: Postsynthetic Pillar Insertion in Electrically Conductive MOF

Measurement evidence

Porosity

From 2D to 3D: Postsynthetic Pillar Insertion in Electrically Conductive MOF · Choi J.Y., Flood J., Stodolka M. et al. · ACS Nano · 2022 · 3145-3151

2 measurement groups · 9 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

N2 adsorption/desorption and BET analysis

Gas sorption and porosity

As-synthesised Cu-THQ powder · Powder

Sample evacuated under vacuum at 30 C for 30 min, then 45 C for 8 h; Micromeritics ASAP 2020 PLUS; N2-DFT pore-width distribution.

Atmosphere
N2 adsorption
Geometry
Powder sample
Context
Pristine Cu-THQ.
Measurement source
SI p.S10 · BET measurement · Figure S9; Table S3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface area, Cu-THQMarked as a best value within this paper139.5 m2 g-1——SI Table
Exact Reported		SI p.S10 · BET measurement · Table S3
DFT calculated pore volume, Cu-THQ0.013 cm3 g-1——SI Table
Exact Reported		SI p.S10 · BET measurement · Table S3
t-Plot pore area, Cu-THQ11.79 m2 g-1——SI Table
Exact Reported		SI p.S10 · BET measurement · Table S3
t-Plot pore volume, Cu-THQ0.0029 cm3 g-1——SI Table
Exact Reported		SI p.S10 · BET measurement · Table S3

N2 adsorption/desorption, BET analysis and N2-DFT pore-size distribution

Gas sorption and porosityDensity functional theory

Cu-THQ-BPY, Cu2+:BPY feed ratio 1:1 · Powder

Sample evacuated under vacuum at 30 C for 30 min, then 45 C for 8 h; Micromeritics ASAP 2020 PLUS; N2-DFT pore-width distribution.

Atmosphere
N2 adsorption
Geometry
Powder sample
Context
Cu-THQ-BPY compared with pristine Cu-THQ.
Measurement source
SI p.S10 · BET measurement · Figure S9; Table S3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface area, Cu-THQ-BPYMarked as a best value within this paper196.9 m2 g-1——SI Table
Exact Reported		SI p.S10 · BET measurement · Table S3
DFT calculated pore volume, Cu-THQ-BPY0.039 cm3 g-1——SI Table
Exact Reported		SI p.S10 · BET measurement · Table S3
New pore width after BPY insertionapproximately 7.3 Angstrom——Text
Approximate		main p.4 · Results and Discussion · Figure 3d
t-Plot pore area, Cu-THQ-BPY91.38 m2 g-1——SI Table
Exact Reported		SI p.S10 · BET measurement · Table S3
t-Plot pore volume, Cu-THQ-BPY0.040 cm3 g-1——SI Table
Exact Reported		SI p.S10 · BET measurement · Table S3