Complete recipeSource: Both
Route 1: Solvothermal
7 · Synthesis of PTC-Fe 2D MOFs
Metal precursorsanhydrous Fe(OAc)2, 7.5 mg, 0.043 mmol
Linker precursorsPTC, 10.0 mg, 0.014 mmol
SolventsDMF 0.5 mL; water 0.5 mL
Additivesaqueous ammonia, NH4OH, 6 M, 0.1 mL; dilute HCl 0.1 M used in workup
Atmospheredegassed solutions, deoxygenated wash solvent; sealed vial; product stored in Ar
Temperature120
Time48
Work-upsonicated 5 min at 0 C; natural cooling; solid collected and washed three times with deoxygenated DMF, 0.1 M HCl, water and acetone
Activationdried at 100 C under vacuum for 24 h
Scalability contextReported yield about 12 mg black crystals from 10 mg PTC.
Show 6 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Linker | PTC | 10.0 mg; 0.014 mmol | 7 · Synthesis of PTC-Fe 2D MOFs |
| Metal Source | anhydrous Fe(OAc)2 | 7.5 mg; 0.043 mmol | 7 · Synthesis of PTC-Fe 2D MOFs |
| Solvent | DMF | 0.5 mL | 7 · Synthesis of PTC-Fe 2D MOFs |
| Solvent | water | 0.5 mL | 7 · Synthesis of PTC-Fe 2D MOFs |
| Base | aqueous ammonia (NH4OH) | 0.1 mL · 6 M | 7 · Synthesis of PTC-Fe 2D MOFs |
| Acid | HCl | wash solvent · 0.1 M | 7 · Synthesis of PTC-Fe 2D MOFs |