Measurement evidence
Synthesis and Electric Properties of a Two-Dimensional Metal-Organic Framework Based on Phthalocyanine · Nagatomi H., Yanai N., Yamada T. et al. · Chemistry - A European Journal · 2018 · 1806-1810
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
Cu-CuPc/carbon black/PTFE cathode on stainless mesh · Electrode
2.0-4.4 V vs Li/Li+; scan rate 1 mV s-1; Li foil counter electrode; 1 M LiPF6 in EC/DMC (1:2)
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| broad CV redox peaks | approximately 3.0 V vs Li/Li+ | — | — | Text Approximate | 1808 · main text · Figure 4 |
| CV scan rate | 1 mV s-1 | 0.001 V s-1 | — | Caption Exact Reported | 1808 · Figure 4 caption · Figure 4 |
Cu-CuPc/carbon black/PTFE cathode on stainless mesh · Electrode
0.4 C, 0.13 A g-1; 2.0-4.4 V vs Li/Li+; repeated up to 200 cycles
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| coulombic efficiency over repeated cyclingMarked as a best value within this paper | >95% for repeated charge/discharge up to 200 cycles | — | — | Text Approximate | 1809 · main text · Figure 5b |
| discharge capacity at 200th cycle | approximately 53 mAh g-1 at 200 cycles | — | visual estimate from Figure 5b | Figure Axis Approximate | 1809 · Figure 5b · Figure 5b |
| maximum discharge capacity during 0.4 C cycling | 55 mAh g-1 at around 70th cycle | — | — | Text Rounded Reported | 1809 · main text · Figure 5b |
Cu-CuPc/carbon black/PTFE cathode on stainless mesh · Electrode
0.04 C, 13 mA g-1; 2.0-4.4 V vs Li/Li+; cut-off time 1440 min discharge and 1440 min charge
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| charge capacity at 0.04 CMarked as a best value within this paper | 151 mAh g-1 | — | — | Text Exact Reported | 1808 · main text · Figure 5a |
| charge/discharge plateau voltages | modest plateau regions at 3.0 and 3.8 V | — | — | Text Approximate | 1808 · main text · Figure 5a |
| discharge capacity at 0.04 CMarked as a best value within this paper | 128 mAh g-1 | — | — | Text Exact Reported | 1808 · main text · Figure 5a |
| redox electron count from observed capacity | n = 4.9 | — | — | Calculated From Reported Rounded Reported | 1808 · main text · Figure 5a |
| theoretical capacity assuming 10 electrons | 304.3 mAh g-1 | — | — | Text Exact Reported | S2 · Discharge and charge measurement |
| fraction of theoretical capacity available at 0.04 C | 49% | — | — | Calculated From Reported Rounded Reported | 1808 · main text · Figure 5a |
Cu-CuPc/carbon black/PTFE cathode on stainless mesh · Electrode
various C-rates from 0.04 C (13 mA g-1) to 17 C (5.2 A g-1), 2.0-4.4 V vs Li/Li+
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| discharge capacity at 0.04 C from rate plot | approximately 128 mAh g-1 at 0.04 C | — | visual estimate consistent with text-reported Figure 5a value | Figure Axis Approximate | S5 · Figure S5 · Figure S5 |
| discharge capacity at 0.09 C | approximately 108 mAh g-1 at 0.09 C | — | visual estimate from Figure S5 | Figure Axis Approximate | S5 · Figure S5 · Figure S5 |
| discharge capacity at 0.2 C | approximately 91 mAh g-1 at 0.2 C | — | visual estimate from Figure S5 | Figure Axis Approximate | S5 · Figure S5 · Figure S5 |
| discharge capacity at 0.4 C | approximately 80 mAh g-1 at 0.4 C in rate test | — | visual estimate from Figure S5 | Figure Axis Approximate | S5 · Figure S5 · Figure S5 |
| discharge capacity at 0.9 C | approximately 69 mAh g-1 at 0.9 C | — | visual estimate from Figure S5 | Figure Axis Approximate | S5 · Figure S5 · Figure S5 |
| discharge capacity at 17 C | approximately 17 mAh g-1 at 17 C | — | visual estimate from Figure S5 | Figure Axis Approximate | S5 · Figure S5 · Figure S5 |
| discharge capacity at 2 C | approximately 57 mAh g-1 at 2 C | — | visual estimate from Figure S5 | Figure Axis Approximate | S5 · Figure S5 · Figure S5 |
| discharge capacity at 4 C | approximately 45 mAh g-1 at 4 C | — | visual estimate from Figure S5 | Figure Axis Approximate | S5 · Figure S5 · Figure S5 |
| discharge capacity at 9 C | approximately 31 mAh g-1 at 9 C | — | visual estimate from Figure S5 | Figure Axis Approximate | S5 · Figure S5 · Figure S5 |