Spectroscopy — Synthesis and Electric Properties of a Two-Dimensional Metal-Organic Framework Based on Phthalocyanine

3 measurement groups · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

as-synthesised/activated Cu-CuPc black powder · Powder

Cu-CuPc compared with CuPcOH to confirm catecholate coordination

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
uncoordinated catechol C-O-H bend disappearance	disappearance of a peak at 629 cm-1 after complexation	—	—	Text Exact Reported	1806-1807 · main text · Figure S2
coordinated catecholate C-O stretch in Cu-CuPc	peak shifted from 1288 to 1271 cm-1 after complexation	—	—	Text Exact Reported	1806-1807 · main text · Figure S2

CuPcOH dark purple powder · Powder

CuPcOH compared with octakisoctyloxy precursor after dealkylation

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
alkyl-chain FTIR band disappearance	peak around 3000 cm-1 disappeared	—	—	Caption Approximate	S3 · Figure S1 caption · Figure S1
hydroxyl FTIR band appearance	broad peak around 3500 cm-1 appeared	—	—	Caption Approximate	S3 · Figure S1 caption · Figure S1

CuPcOH dark purple powder · Powder

dithranol matrix; used to confirm CuPcOH formation

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CuPcOH synthesis yield	75% yield	—	—	Text Exact Reported	S1 · Synthesis of CuPcOH
CuPcOH MALDI-TOF molecular ion	found m/z = 702.99 ([M]+); calculated 703.04	—	—	Text Exact Reported	S1 · Synthesis of CuPcOH