Spectroscopy — Linker Defects Triggering Boosted Oxygen Reduction Activity of Co/Zn-ZIF Nanosheet Arrays for Rechargeable Zn–Air batteries

3 measurement groups · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

D-ZIF linker-deficient nanosheet array on Ni foam · Electrode

Raman and FTIR comparison of ZIF and D-ZIF.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
FTIR characteristic peaks of coordinated polymer	424, 1381, 1564, 1147 and 1305 cm-1	—	—	Text Exact Reported	3 · 2. Result and Discussion · Figure 2d
Raman peaks weakened in D-ZIF	D-ZIF Raman peaks substantially weaker than ZIF, especially at 178 and 688 cm-1	—	—	Text Qualitative	2 · 2. Result and Discussion · Figure 2c

ZIF nanosheet array on Ni foam · Electrode

TG under flowing air at 5 C min-1 from room temperature to 800 C; FTIR of thermal decomposition products near 200 C.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
TG mass loss by 200 C	-7.27 wt% at 200 C	—	—	Figure Axis Rounded Reported	3 · 2. Result and Discussion · Figure 2b
FTIR band of volatilised imidazole product	2931 cm-1 assigned to N-H groups at 200 C	—	—	Text Exact Reported	2 · 2. Result and Discussion · Figure S2

D-ZIF linker-deficient nanosheet array on Ni foam · Electrode

Synchrotron radiation measurements of local electronic and coordination structure for ZIF and D-ZIF.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
WT-EXAFS Co-N maximum	maximum at about 1.5 A associated with Co-N bonding	—	—	Text Approximate	3 · 2. Result and Discussion · Figure 3d,e
Co valence trend from XANES	D-ZIF absorption edge shifts slightly to lower energy than ZIF	—	—	Text Qualitative	3 · 2. Result and Discussion · Figure 3b