Elemental microanalysis, FT-IR, PXRD and TG-DSC/DTA general characterisation.
Infrared spectroscopyX-ray diffraction and scatteringBulk elemental and compositional analysisCalorimetry and thermal analysisThermogravimetric analysis
G@1 yellow crystals · Single Crystal
C/H/N microanalysis; IR 4000-400 cm-1; PXRD at 293 K using Cu-Kalpha; TG under dry N2 at 5 C/min.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Compound 1 elemental analysis carbon found | Found: C 18.46, H 1.45, N 4.08 | — | — | Text Exact Reported | p006 / SI p.5 · Syntheses of the compounds |
| G@1 elemental analysis carbon found | Found: C 19.52, H 1.79, N 4.58 | — | — | Text Exact Reported | p005 / SI p.4 · Syntheses of the compounds |
| First TG mass loss of G@1 assigned to two DMF molecules | exp. 3.6%; cal. 3.4% | 3.4 wt% calculated | — | Figure Axis Rounded Reported | p015 / SI p.14 · Figure/caption · Figure S3 |
| Second TG mass loss of G@1 assigned to three coordinated DMF molecules | exp. 5.4%; cal. 5.2% | 5.2 wt% calculated | — | Caption Exact Reported | p015 / SI p.14 · Figure caption · Figure S3 |
| G@1 isolated yield | ca. 87% based on Cu | — | — | Text Approximate | p005 / SI p.4 · Syntheses of the compounds |