Sensing Application — Direct Observation of Confined I−⋅⋅⋅I2⋅⋅⋅I− Interactions in a Metal–Organic Framework: Iodine Capture and Sensing

Measurement evidence

Sensing Application

Direct Observation of Confined I−⋅⋅⋅I2⋅⋅⋅I− Interactions in a Metal–Organic Framework: Iodine Capture and Sensing · Hu Y.-Q., Li M.-Q., Wang Y. et al. · Chemistry - A European Journal · 2017 · 8409-8413

2 measurement groups · 12 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Current response to different iodine/air concentrations.

Compound 1 iodine-sensing pellet device · Pellet

Current transients recorded for I2 vapour concentrations labelled 0.12, 0.10, 0.05 and 0.01 mg/mL at 50 C; inset linear fit of current to concentration.

Temperature
323
Atmosphere
I2/air mixed gas at multiple concentrations
Geometry
compound 1 pellet sensing circuit
Context
Pristine 1 pellet used as iodine sensor.
Measurement source
p003 / article p.8411 · Main text and caption · Figure 3c
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Highest Figure 3c iodine concentration label0.12 mg/mLFigure Axis
Rounded Reported
p003 / article p.8411 · Figure axis/labels · Figure 3c
Lowest Figure 3c iodine concentration label0.01 mg/mLFigure Axis
Rounded Reported
p003 / article p.8411 · Figure axis/labels · Figure 3c
Linear response intercept in Figure 3c insety = 3.99x + 0.01Figure Axis
Rounded Reported
p003 / article p.8411 · Figure inset · Figure 3c inset
Linear response R2 in Figure 3c insetR2 = 0.99Figure Axis
Rounded Reported
p003 / article p.8411 · Figure inset · Figure 3c inset
Linear response slope in Figure 3c insetMarked as a best value within this papery = 3.99x + 0.01Figure Axis
Rounded Reported
p003 / article p.8411 · Figure inset · Figure 3c inset

Chemiresistive iodine-vapour sensing with pellet, Keithley 2400/source meter, LED lamp and current-time monitoring.

Compound 1 iodine-sensing pellet device · Pellet

Pellet device exposed to iodine/air mixtures at 50 C; voltage 10 V; current scanned over time.

Temperature
323
Atmosphere
I2/air mixtures; about 0.1 mg mL-1 for Figure 3b
Geometry
pressed pellet connected with silver-coated copper wires and conductive silver paste; LED signal lamp in circuit
Context
Pristine 1 pellet responds by iodine uptake in situ.
Measurement source
p004 / SI p.3 · Iodine sensing measurements · Figure 3a-c; Figure S9
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Current after 10 min iodine sensingMarked as a best value within this paper5.82 uA within 10 minText
Exact Reported
p003 / article p.8411 · Main text · Figure 3b
Initial current during iodine sensing0.12 uAText
Exact Reported
p003 / article p.8411 · Main text · Figure 3b
Reversible current response cycle countmore than 6 cyclesText
Approximate
p003 / article p.8411 · Main text · Figure S9
Time for LED lamp to start glowingabout two minutesText
Approximate
p003 / article p.8411 · Main text · Figure 3b
Figure S9 repeated switching iodine concentration0.1 mg/mL I2/air mixed gasCaption
Exact Reported
p021 / SI p.20 · Figure caption · Figure S9
I2 vapour concentration for Figure 3b sensingabout 0.1 mg mL-1Text
Approximate
p003 / article p.8411 · Main text · Figure 3b
Applied voltage for iodine-sensing current-time test10 VText
Exact Reported
p003 / article p.8411 · Main text · Figure 3b