Diffraction Structure — Humidity-Mediated Dual Ionic-Electronic Conductivity Enables High Sensitivity in MOF Chemiresistors

3 measurement groups · 4 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

PXRD and SEM characterization of control cMOFs

X-ray diffraction and scattering Scanning electron microscopy

M3HHTP2 and M3HITP2 control sensors · Electrode

PXRD spectra and SEM images for M3HHTP2 and M3HITP2 (M = Co, Ni, Cu).

Context: pristine control frameworks
Measurement source: p011-p012 / SI pp.11-12 · Section S3 Characterization · Figures S4 and S5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source

Continuous humidity-dependent PXRD

X-ray diffraction and scattering

Cu3HHTT2 powder · Powder

PANalytical Empyrean Mo Kalpha with Anton Paar CHC+ heating/humidity stage; powders pre-activated at 80 C under dry air; spectra after 90 min humidity saturation; scan speed 4.5 deg/min.

Atmosphere: controlled humidity dry to 80% RH
Context: pristine target framework
Measurement source: p004 / SI p.4 · S1.2 Methods · Figures 3c,d and S8

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Low-humidity (001) peak position before shift	25.52 degrees at low humidity (1-25% RH), shifting lower at 30-80% RH	—	—	Text Exact Reported	p003 / article p.20215 · Results and Discussion · Figure 3d
Hydrated/dehydrated (100) peak position	3.72 degrees	—	—	Text Exact Reported	p003 / article p.20215 · Results and Discussion · Figure 3c

Laboratory powder X-ray diffraction

X-ray diffraction and scattering

Cu3HHTT2 powder · Powder

Reflection mode Bruker Advance II with Ni-filtered Cu Kalpha radiation; sample on zero-background silicon substrate; scan speed 2 deg min-1.

Context: pristine target framework
Measurement source: p004 / SI p.4 · S1.2 Methods

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu3HHTT2 PXRD (100) peak position	3.91 degrees 2theta	—	—	Text Exact Reported	p002 / article p.20214 · Results and Discussion · Figure 1b
Cu3HHTT2 PXRD (200) peak position	7.93 degrees 2theta	—	—	Text Exact Reported	p002 / article p.20214 · Results and Discussion · Figure 1b