Huang Q.-Q., Lin Y.-J., Zheng R. et al. · Inorganic Chemistry Communications · 2019 · 119-124
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
Cu-TATAB is a cubic 3D porous MOF containing two types of Cu24 cages and open channels.
Caveat: Bond distance/angle details cited to missing SI Tables S1-S2 were not available for extraction.
3 · Results and discussion · Figs. 1-2 · Linked to 4 structured results
Cu-TATAB retains a similar crystal structure after TCNQ doping.
Caveat: Supported by qualitative PXRD comparison in the main text; no refined doped structure is reported.
5 · Results and discussion · Fig. 3a · Linked to 1 structured result
TCNQ doping increases Cu-TATAB conductivity by more than four orders of magnitude, transforming it from an insulator to a semiconductor.
Caveat: Conductivity measured by two-probe pressed-pellet method; no error bars or replicate statistics reported.
5 · Conclusion · Fig. 4b-d · Linked to 4 structured results
TCNQ molecules form localised conducting regions/charge-transfer channels in Cu-TATAB, enabling electron hopping between localised states under an applied field.
Caveat: Mechanism inferred from spectroscopy and Mott VRH fitting; exact TCNQ loading and microscopic distribution are not quantified.
5 · Results and discussion · Figs. 3b-d and 4d · Linked to 4 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Cu-TATAB | [Cu2(TATAB)3].7.5H2O; crystal-table empirical formula C32H21Cu2N8O10Cu(II) paddlewheel secondary building units; two crystallographically independent Cu(II) atoms coordinated by five oxygen atoms · TATAB3- polyacid linker from H3TATAB | 3D · PristineCubic 3D porous MOF, space group Im-3, with two types of icosahedral Cu24 cages and open microchannels along three orthogonal directions. | 2 · Introduction / Results and discussion · Table 1; Figs. 1-2 |
| TCNQ@Cu-TATAB | TCNQ-doped Cu-TATAB; exact guest loading not reportedCu(II) paddlewheel secondary building units retained after TCNQ doping · TATAB3- framework linker with TCNQ guest/dopant in the channels | 3D · PristinePost-synthetically TCNQ-doped Cu-TATAB retaining a similar crystal structure by PXRD and showing TCNQ coordination/charge-transfer signatures by FT-IR, TGA, and UV-vis-NIR. | 5 · Results and discussion · Figs. 3-4 |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Activated Cu-TATAB green crystalsresearch_0110__mat__mat_cu_tatab | Single Crystal · Pristine Control · Pristine Framework | Green solvothermal crystals washed with DMF four times and soaked in methanol for one week to remove solvent from the channels. | 2 · 2.2. Synthesis of Cu-TATAB crystals |
| Cu-TATAB pressed pelletresearch_0110__mat__mat_cu_tatab | Pellet · Pristine Control · Pristine Framework | Pressed pellet with both faces painted with silver paint for two-probe electrical measurements. | 5 · Results and discussion · Fig. 4b |
| TCNQ@Cu-TATAB dark crystalsresearch_0110__mat__mat_tcnq_cu_tatab | Single Crystal · Target Sample · Doped | Activated Cu-TATAB soaked in methanol solution of TCNQ for three days, changing colour from green to dark. | 4 · Results and discussion · Fig. 4a |
| TCNQ@Cu-TATAB pressed pelletresearch_0110__mat__mat_tcnq_cu_tatab | Pellet · Target Sample · Doped | Doped Cu-TATAB pressed into a pellet with both faces painted with silver paint for two-probe I-V measurements. | 5 · Results and discussion · Fig. 4b-d |