Complete recipeSource: Main
Route 1: Solvothermal
2 · 2.2. Synthesis of Cu-TATAB crystals
Metal precursorsCu(NO3)2.3H2O (0.2 mmol, 25.4 mg)
Linker precursorsH3TATAB (0.1 mmol, 25.7 mg)
SolventsDMF (5 mL), H2O (3 mL), MeOH (2 mL)
AdditivesAcetic acid glacial (350 uL)
AtmosphereNot specified
Temperature125
Time72; cooled to room temperature over 24 h
Work-upGreen crystals collected and washed by DMF four times.
ActivationSoaked in methanol for one week to remove solvent inside the channels.
Scalability context25 mL Teflon-lined reaction vessel; no yield or scale-up data reported.
Show 6 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | Cu(NO3)2.3H2O | 0.2 mmol, 25.4 mg | 2 · 2.2. Synthesis of Cu-TATAB crystals |
| Linker | H3TATAB | 0.1 mmol, 25.7 mg | 2 · 2.2. Synthesis of Cu-TATAB crystals |
| Solvent | DMF | 5 mL | 2 · 2.2. Synthesis of Cu-TATAB crystals |
| Solvent | H2O | 3 mL | 2 · 2.2. Synthesis of Cu-TATAB crystals |
| Solvent | MeOH | 2 mL | 2 · 2.2. Synthesis of Cu-TATAB crystals |
| Acid | acetic acid | 350 uL | 2 · 2.2. Synthesis of Cu-TATAB crystals |