Synthesis · Conductive MOFs with tailored polarization loss for broadband absorption at ultrathin thickness

6 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Complete recipeSource: Both

Route 1: Hydrothermal

2 · Tables · Table S3

Metal precursors11.35 mg Cu(OAc)2.H2O; 10.20 mg Co(OAc)2.4H2O

Linker precursors14 mg HHTP

Solvents15 mL deionised water

Atmospherenot specified

Temperature85

Time12

Work-upNatural cooling to room temperature; washed three times with deionised water; dried in vacuum oven at 60 C for 12 h.

ActivationVacuum drying at 60 C for 12 h.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	HHTP	14 mg	2 · Tables · Table S3
Metal Source	Cu(OAc)2.H2O	11.35 mg	2 · Tables · Table S3
Metal Source	Co(OAc)2.4H2O	10.20 mg	2 · Tables · Table S3
Solvent	deionized water	15 mL	2 · Tables · Table S3

Complete recipeSource: Both

Route 2: Hydrothermal

1 · Fabrication of CuM-HHTP · Table S3

Metal precursors11.35 mg Cu(OAc)2.H2O; 10.04 mg Mn(OAc)2.4H2O

Linker precursors14 mg HHTP

Solvents15 mL deionised water

Atmospherenot specified

Temperature85

Time12

Work-upNatural cooling to room temperature; washed three times with deionised water; dried in vacuum oven at 60 C for 12 h.

ActivationVacuum drying at 60 C for 12 h.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	HHTP	14 mg	1 · Fabrication of CuM-HHTP · Table S3
Metal Source	Cu(OAc)2.H2O	11.35 mg	1 · Fabrication of CuM-HHTP · Table S3
Metal Source	Mn(OAc)2.4H2O	10.04 mg	1 · Fabrication of CuM-HHTP · Table S3
Solvent	deionized water	15 mL	1 · Fabrication of CuM-HHTP · Table S3

Complete recipeSource: Both

Route 3: Hydrothermal

2 · Tables · Table S3

Metal precursors11.35 mg Cu(OAc)2.H2O; 10.19 mg Ni(OAc)2.4H2O

Linker precursors14 mg HHTP

Solvents15 mL deionised water

Atmospherenot specified

Temperature85

Time12

Work-upNatural cooling to room temperature; washed three times with deionised water; dried in vacuum oven at 60 C for 12 h.

ActivationVacuum drying at 60 C for 12 h.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	HHTP	14 mg	2 · Tables · Table S3
Metal Source	Cu(OAc)2.H2O	11.35 mg	2 · Tables · Table S3
Metal Source	Ni(OAc)2.4H2O	10.19 mg	2 · Tables · Table S3
Solvent	deionized water	15 mL	2 · Tables · Table S3

Complete recipeSource: Both

Route 4: Hydrothermal

1-2 · Fabrication of CuM-HHTP · Table S3

Metal precursors15.15 mg Cu(OAc)2.H2O; 7.65 mg Zn(OAc)2.2H2O

Linker precursors14 mg HHTP

Solvents15 mL deionised water

Atmospherenot specified

Temperature85

Time12

Work-upNatural cooling to room temperature; washed three times with deionised water; dried in vacuum oven at 60 C for 12 h.

ActivationVacuum drying at 60 C for 12 h.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	HHTP	14 mg	1-2 · Fabrication of CuM-HHTP · Table S3
Metal Source	Cu(OAc)2.H2O	15.15 mg	1-2 · Fabrication of CuM-HHTP · Table S3
Metal Source	Zn(OAc)2.2H2O	7.65 mg	1-2 · Fabrication of CuM-HHTP · Table S3
Solvent	deionized water	15 mL	1-2 · Fabrication of CuM-HHTP · Table S3

Complete recipeSource: Both

Route 5: Hydrothermal

1 · Fabrication of CuM-HHTP · Table S3

Metal precursors11.35 mg Cu(OAc)2.H2O; 11.47 mg Zn(OAc)2.2H2O

Linker precursors14 mg HHTP

Solvents15 mL deionised water

Atmospherenot specified

Temperature85

Time12

Work-upNatural cooling to room temperature; washed three times with deionised water; dried in vacuum oven at 60 C for 12 h.

ActivationVacuum drying at 60 C for 12 h.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	HHTP	14 mg	1 · Fabrication of CuM-HHTP · Table S3
Metal Source	Cu(OAc)2.H2O	11.35 mg	1 · Fabrication of CuM-HHTP · Table S3
Metal Source	Zn(OAc)2.2H2O	11.47 mg	1 · Fabrication of CuM-HHTP · Table S3
Solvent	deionized water	15 mL	1 · Fabrication of CuM-HHTP · Table S3

Complete recipeSource: Both

Route 6: Hydrothermal

2 · Tables · Table S3

Metal precursors7.57 mg Cu(OAc)2.H2O; 15.30 mg Zn(OAc)2.2H2O

Linker precursors14 mg HHTP

Solvents15 mL deionised water

Atmospherenot specified

Temperature85

Time12

Work-upNatural cooling to room temperature; washed three times with deionised water; dried in vacuum oven at 60 C for 12 h.

ActivationVacuum drying at 60 C for 12 h.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	HHTP	14 mg	2 · Tables · Table S3
Metal Source	Cu(OAc)2.H2O	7.57 mg	2 · Tables · Table S3
Metal Source	Zn(OAc)2.2H2O	15.30 mg	2 · Tables · Table S3
Solvent	deionized water	15 mL	2 · Tables · Table S3