Electrochemistry Application — An Electrically Conducting Li-Ion Metal-Organic Framework

4 measurement groups · 22 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

galvanostatic cycling with varied conductive carbon content

Galvanostatic cycling

Li2-Mn-DOBDC composite Li half-cell electrode · Electrode

Li2-Mn-DOBDC active material with 10, 20 or 40 wt.% superP carbon, 10 or 5 wt.% PTFE, 1 M LiTFSI DOL/DME, 2.0-3.55 V at C/2.

Atmosphere: Ar-filled glovebox assembly
Geometry: coin cell, Li half-cell
Context: composite electrode
Measurement source: 26 · Supplementary Figures and Data · Figure S11

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
approximate first-cycle capacity with 10 wt.% carbon	approximately 42 mAh/g from Figure S11	—	approximate visual estimate	Figure Axis Approximate	26 · Figure S11 · Figure S11A
approximate first-cycle capacity with 40 wt.% carbonMarked as a best value within this paper	approximately 65 mAh/g from Figure S11	—	approximate visual estimate	Figure Axis Approximate	26 · Figure S11 · Figure S11A

galvanostatic charge/discharge in Li half-cells

Galvanostatic cycling

Li2-Mn-DOBDC composite Li half-cell electrode · Electrode

Two-electrode coin cells assembled in Ar-filled glovebox; Li foil counter/reference; varied cut-off potentials; standard rate 1 electron in 10 h per formula for Figure 4.

Atmosphere: Ar-filled glovebox for assembly
Geometry: coin cell, Li half-cell
Context: composite electrode with conductive carbon and PTFE
Measurement source: 6 · 2.3. Electrochemistry · Figure 4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Li2-Mg-DOBDC recovered charge in 2.0-3.55 V window	only 0.2 e-/Li+	—	only	Text Rounded Reported	23 · Figure S9 discussion · Figure S9B
Li2-Mg-DOBDC recovered charge in 2.0-4.0 V window, SI discussion	more than 0.7 e-/Li+	—	>	Text Approximate	23 · Figure S9 discussion · Figure S9B
Li2-Mg-DOBDC reversible exchange in 2.0-4.0 V window	0.3 e-/Li+ equivalents	—	—	Text Rounded Reported	6 · 2.3. Electrochemistry · Figure 4B
Li2-Mn-DOBDC reversible exchange in 2.0-4.0 V windowMarked as a best value within this paper	1.1 e-/Li+ equivalents	—	—	Text Rounded Reported	6 · 2.3. Electrochemistry · Figure 4C
Mn-CPO-27 minor discharge response R1	3.25 V, less than 0.05 electrons exchanged	—	<0.05 e- exchanged	Text Rounded Reported	23 · Figure S9 discussion · Figure S9A
Mn-CPO-27 minor discharge response R2	2.4 V, less than 0.05 electrons exchanged	—	<0.05 e- exchanged	Text Rounded Reported	23 · Figure S9 discussion · Figure S9A
Mn-CPO-27 Ox1 charge cut-off onset	steep potential increase up to 3.65 V; short sloping profile up to 3.8 V	—	—	Text Rounded Reported	23 · Figure S9 discussion · Figure S9A
Mn-CPO-27 Ox2 irreversible redox range	3.8-3.9 V	—	—	Text Range	23 · Figure S9 discussion · Figure S9A
DOBDC redox potential increase upon Mn incorporation	nearly 800 mV with respect to Li4-DOBDC	800 mV	nearly	Text Approximate	7 · 2.3. Electrochemistry · Scheme 2

galvanostatic cycling electrolyte screen

Galvanostatic cycling

Li2-Mn-DOBDC composite Li half-cell electrode · Electrode

Li half-cells using Li2-Mn-DOBDC, 40 wt.% superP carbon, 10 wt.% PTFE; 2.0-3.55 V at C/2; various 1 M electrolytes.

Atmosphere: Ar-filled glovebox assembly
Geometry: coin cell, Li half-cell
Context: composite electrode
Measurement source: 25 · Supplementary Figures and Data · Figure S10

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
average Coulombic efficiency after 100 cyclesMarked as a best value within this paper	99.7%	0.997 fraction	—	Text Exact Reported	7 · 2.4. Lithium Storage Performance · Figure 5
best capacity retention after 100 cyclesMarked as a best value within this paper	91% with 1 M LiTFSI in DOL/DME	0.91 fraction	—	Text Exact Reported	7 · 2.4. Lithium Storage Performance · Figure 5; Figure S10
ether-based solvent capacity retention range	60-80%	—	range	Text Range	7 · 2.4. Lithium Storage Performance · Figure S10
ionic liquid capacity retention	only 40%	0.4 fraction	only	Text Rounded Reported	7 · 2.4. Lithium Storage Performance · Figure S10

capacity-rate test and cycling retention

Li2-Mn-DOBDC composite Li half-cell electrode · Electrode

Li half-cell using Li2-Mn-DOBDC active electrode and 1 M LiTFSI in DOL/DME; rates from C/20 to 1C and long cycling.

Atmosphere: Ar-filled glovebox assembly
Geometry: coin cell, Li half-cell
Context: composite electrode
Measurement source: 7 · 2.4. Lithium Storage Performance · Figure 5; Figure S12

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
approximate discharge capacity at 1C	approximately 52 mAh/g from Figure 5A	—	approximate visual estimate	Figure Axis Approximate	7 · 2.4. Lithium Storage Performance · Figure 5A
approximate discharge capacity at C/20Marked as a best value within this paper	approximately 67 mAh/g from Figure 5A	—	approximate visual estimate	Figure Axis Approximate	7 · 2.4. Lithium Storage Performance · Figure 5A
cycling discharge capacity after 100 cycles	approximately 57 mAh/g after 100 cycles from Figure 5B	—	approximate visual estimate	Figure Axis Approximate	7 · 2.4. Lithium Storage Performance · Figure 5B
Li2-Mn-DOBDC average discharge potential	3.2 V vs Li+/Li0	—	—	Text Rounded Reported	1 · Abstract
capacity retained at 1C relative to low-rate capacity	83% of the capacity at 1C	0.83 fraction	—	Text Exact Reported	7 · 2.4. Lithium Storage Performance · Figure 5A; Figure S12
approximate 1C capacity from Figure S12	approximately 55 mAh/g	—	approximate visual estimate	Figure Axis Approximate	27 · Figure S12 · Figure S12
approximate C/20 capacity from Figure S12Marked as a best value within this paper	approximately 68 mAh/g	—	approximate visual estimate	Figure Axis Approximate	27 · Figure S12 · Figure S12