cMOF Evidence Base
Electrochemistry Application — Isoreticular Linker Substitution in Conductive Metal–Organic Frameworks with Through-Space Transport Pathways

Measurement evidence

Electrochemistry Application

Isoreticular Linker Substitution in Conductive Metal–Organic Frameworks with Through-Space Transport Pathways · Xie L.S., Park S.S., Chmielewski M.J. et al. · Angewandte Chemie - International Edition · 2020 · 19623-19626

1 measurement group · 2 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

cyclic voltammetry

Voltammetry

H4Ni(dbg)2 solution sample · Unknown

1 mM H4Ni(dbg)2 in 0.1 M TBAPF6 degassed DMF; glassy carbon working electrode; Ag pseudo-reference; Pt counter; 100 mV/s

Temperature
296
Atmosphere
nitrogen
Geometry
one-compartment cell
Context
molecular linker control
Measurement source
S6; S47-S48 · Electrochemical methods; attempted doping · Figure S25
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
reversible oxidation featuresno reversible features corresponding to oxidation processes——Text
Qualitative		S48 · Attempted doping · Figure S25
reversible reduction E1/2Marked as a best value within this paperE1/2 = -0.77 V vs Fc/Fc+——Text
Exact Reported		S48 · Attempted doping · Figure S25