cMOF Evidence Base

Synthesis evidence

Modular O2 electroreduction activity in triphenylene-based metal-organic frameworks

Miner E.M., Wang L., Dinca M. · Chemical Science · 2018 · 6286-6291

6 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Partial recipeSource: Both

Route 1: Unknown

S4 · Synthesis of the HHTP MOFs

Metal precursorsCo source not specified in this article.
Linker precursorsHHTP; purchased and recrystallized from ethanol before use.
Solventsnot specified for framework synthesis
Additivesbase mentioned generally in main text
Atmosphereair mentioned generally in main text
Oxidant / reductantair, general statement
Work-upnot specified
Activationnot specified
Show 1 structured reagent record
RoleReagentAmount / concentrationSource
Linker2,3,6,7,10,11-hexahydroxytriphenylene (HHTP, 95%)Not specifiedS4 · Synthesis of the HHTP MOFs
Partial recipeSource: Both

Route 2: Unknown

1 · Results and discussion

Metal precursorsCu source not specified in this article.
Linker precursorsHHTP; purchased and recrystallized from ethanol before use.
Solventsnot specified for framework synthesis
Additivesbase mentioned generally in main text
Atmosphereair mentioned generally in main text
Oxidant / reductantair, general statement
Work-upnot specified
Activationnot specified
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Linker2,3,6,7,10,11-hexahydroxytriphenylene (HHTP, 95%)Not specified1 · Results and discussion
BasebaseNot specified1 · Results and discussion
OxidantairNot specified1 · Results and discussion
Vague recipeSource: SI

Route 3: Unknown

S4 · Synthesis of the HITP MOFs

Metal precursorsCu source not specified in this article.
Linker precursorsHATP-derived HITP linker; exact precursor not specified here.
Solventsnot specified
Additivesnot specified
Atmospherenot specified
Work-upnot specified
Activationnot specified
Show 1 structured reagent record
RoleReagentAmount / concentrationSource
LinkerHITP/HATP-derived triphenylene ligandNot specifiedS4 · Synthesis of the HITP MOFs
Complete recipeSource: SI

Route 4: Drop Cast

S4 · Deposition of the MOFs onto the electrodes

Metal precursorspreformed MOF powder
Linker precursorspreformed MOF powder
Solvents1:1 Millipore water:isopropyl alcohol, 190 uL total
Additives10 uL of 5 wt% Nafion 117 solution
Atmosphereambient during ink preparation; vacuum drying before use
Time0.4167 h sonication
Substrate orientationpolished or otherwise cleaned glassy carbon electrodes
Work-upsonicated 25 min; 2 x 5 uL ink deposited on electrode
Activationdried under vacuum before use
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
OtherMOF catalyst powder2 mgS4 · Deposition of the MOFs onto the electrodes
Solvent1:1 Millipore water:isopropyl alcohol190 uLS4 · Deposition of the MOFs onto the electrodes
AdditiveNafion 117 solution in isopropanol10 uL · 5 wt%S4 · Deposition of the MOFs onto the electrodes
Partial recipeSource: Both

Route 5: Unknown

S4 · Synthesis of the HHTP MOFs

Metal precursorsNi source not specified in this article.
Linker precursorsHHTP; purchased and recrystallized from ethanol before use.
Solventsnot specified for framework synthesis
Additivesbase mentioned generally in main text
Atmosphereair mentioned generally in main text
Oxidant / reductantair, general statement
Work-upnot specified
Activationnot specified
Show 1 structured reagent record
RoleReagentAmount / concentrationSource
Linker2,3,6,7,10,11-hexahydroxytriphenylene (HHTP, 95%)Not specifiedS4 · Synthesis of the HHTP MOFs
Vague recipeSource: SI

Route 6: Unknown

S4 · Synthesis of the HITP MOFs

Metal precursorsNi source not specified in this article.
Linker precursorsHATP ligand; 2,3,6,7,10,11-hexaaminotriphenylene.
Solventsnot specified
Additivesnot specified
Atmospherenot specified
Work-upnot specified
Activationnot specified
Show 1 structured reagent record
RoleReagentAmount / concentrationSource
Linker2,3,6,7,10,11-hexaaminotriphenylene (HATP)Not specifiedS4 · Synthesis of the HITP MOFs