Electrochemistry Application — Triphenylene-Bridged Trinuclear Complexes of Cu: Models for Spin Interactions in Two-Dimensional Electrically Conductive Metal-Organic Frameworks

Measurement evidence

Electrochemistry Application

Triphenylene-Bridged Trinuclear Complexes of Cu: Models for Spin Interactions in Two-Dimensional Electrically Conductive Metal-Organic Frameworks · Yang L., He X., Dinca M. · Journal of the American Chemical Society · 2019 · 10475-10480

2 measurement groups · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

cyclic voltammetry

complex 1 CV solution · Unknown

0.1 M TBAPF6 in propylene carbonate under N2; glassy carbon working electrode, Pt counter, Ag wire pseudo-reference; 100 mV/s scan rate; potentials vs Fc+/Fc.

Atmosphere
N2
Geometry
three-electrode cell
Context
model_system
Measurement source
p003 / article p.10477 · Results and Discussion · Figure 3a
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
complex 1 HOTP5-/6- to HOTP3-/4- potential differenceDelta E = 0.71 VText
Exact Reported
p003 / article p.10477
complex 1 comproportionation constantKc = 10^12.0Text
Exact Reported
p003 / article p.10477
complex 1 reversible reduction potential 1-0.80 V vs Fc+/FcText
Exact Reported
p003 / article p.10477 · Figure 3a
complex 1 reversible reduction potential 2-0.45 V vs Fc+/FcText
Exact Reported
p003 / article p.10477 · Figure 3a
complex 1 reversible reduction potential 3-0.09 V vs Fc+/FcText
Exact Reported
p003 / article p.10477 · Figure 3a
CV scan rate100 mV s-1Text
Exact Reported
S2

cyclic voltammetry

complex 2 CV solution · Unknown

0.1 M TBAPF6 in propylene carbonate under N2; glassy carbon working electrode, Pt counter, Ag wire pseudo-reference; 100 mV/s scan rate; potentials vs Fc+/Fc.

Atmosphere
N2
Geometry
three-electrode cell
Context
model_system
Measurement source
p003 / article p.10477 · Results and Discussion · Figure 3b
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
complex 2 first irreversible reduction potential-0.51 V vs Fc+/FcText
Exact Reported
p003 / article p.10477 · Figure 3b