Porosity — Tunable Charge Transport and Spin Dynamics in Two-Dimensional Conjugated Metal-Organic Frameworks

Measurement evidence

Porosity

Tunable Charge Transport and Spin Dynamics in Two-Dimensional Conjugated Metal-Organic Frameworks · Lu Y., Hu Z., Petkov P. et al. · Journal of the American Chemical Society · 2024 · 2574-2582

4 measurement groups · 13 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

N2 sorption, BET surface area and NLDFT/QSDFT pore-size analysis

Ni3(HATI_H)2 black powder · Powder

Activated powder; N2 sorption at 77 K.

Temperature
77
Atmosphere
N2 sorption; activation at 90 C overnight before measurement
Context
pristine framework
Measurement source
p004 · Structural Elucidation · Figure 2b,c; Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface area788 m2 g-1Text
Exact Reported
p004 · Structural Elucidation · Figure 2b,c; Table S1
pore sizeMarked as a best value within this paper2.02 nmText
Exact Reported
p004 · Structural Elucidation · Figure 2c
t-plot pore area447.483 m2 g-1SI Table
Exact Reported
p028 · Supplementary Figures and tables · Table S1
t-plot pore volume0.172 cm3 g-1SI Table
Exact Reported
p028 · Supplementary Figures and tables · Table S1

N2 sorption, BET surface area and NLDFT/QSDFT pore-size analysis

Ni3(HATI_iPr)2 black powder · Powder

Activated powder; N2 sorption at 77 K.

Temperature
77
Atmosphere
N2 sorption; activation at 90 C overnight before measurement
Context
pristine framework
Measurement source
p004 · Structural Elucidation · Figure 2b,c; Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface areaMarked as a best value within this paper1625 m2 g-1Text
Exact Reported
p004 · Structural Elucidation · Figure 2b,c; Table S1
large pore size1.60 nmText
Exact Reported
p004 · Structural Elucidation · Figure 2c
small pore size0.60 nmText
Exact Reported
p004 · Structural Elucidation · Figure 2c
t-plot pore areaMarked as a best value within this paper1208.626 m2 g-1SI Table
Exact Reported
p028 · Supplementary Figures and tables · Table S1
t-plot pore volumeMarked as a best value within this paper0.435 cm3 g-1SI Table
Exact Reported
p028 · Supplementary Figures and tables · Table S1

N2 sorption, BET surface area and NLDFT/QSDFT pore-size analysis

Ni3(HATI_nPr)2 black powder · Powder

Activated powder; N2 sorption at 77 K.

Temperature
77
Atmosphere
N2 sorption; activation at 90 C overnight before measurement
Context
pristine framework
Measurement source
p004 · Structural Elucidation · Figure 2b,c
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface area411 m2 g-1Text
Exact Reported
p004 · Structural Elucidation · Figure 2b,c
pore size1.40 nmText
Exact Reported
p004 · Structural Elucidation · Figure 2c

N2 sorption, BET surface area and NLDFT/QSDFT pore-size analysis

Ni3(HATI_vPr)2 black powder · Powder

Activated powder; N2 sorption at 77 K.

Temperature
77
Atmosphere
N2 sorption; activation at 90 C overnight before measurement
Context
pristine framework
Measurement source
p004 · Structural Elucidation · Figure 2b,c
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface area472 m2 g-1Text
Exact Reported
p004 · Structural Elucidation · Figure 2b,c
pore size1.66 nmText
Exact Reported
p004 · Structural Elucidation · Figure 2c