Other — Nanorods of a novel highly conductive 2D metal-organic framework based on perthiolated coronene for thermoelectric conversion

3 measurement groups · 13 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Ni-PTC nanorod dark powder · Powder

C by Flash EA 1112; Ni by ICP-OES after fuming nitric acid dissolution; S/Ni by EPMA JXA-8100.

Geometry: powder
Context: pristine Ni-PTC MOF powder
Measurement source: 4 · Synthesis and structural characterizations · Table S2; Fig. S6

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Carbon content by elemental analysis	C = 33.70 wt%	—	—	SI Table Exact Reported	6 · Supplementary Figures · Table S2
EPMA S/Ni atom ratio, sample 1	S/Ni atom ratio: 4.12	—	—	Visual Estimate Exact Reported	7 · Supplementary Figures · Fig. S6
EPMA S/Ni atom ratio, sample 2	S/Ni atom ratio: 4.00	—	—	Visual Estimate Exact Reported	7 · Supplementary Figures · Fig. S6
EPMA S/Ni atom ratio, sample 3	S/Ni atom ratio: 4.09	—	—	Visual Estimate Exact Reported	7 · Supplementary Figures · Fig. S6
EPMA S/Ni atom ratio, sample 4	S/Ni atom ratio: 3.96	—	—	Visual Estimate Exact Reported	7 · Supplementary Figures · Fig. S6
S/Ni atom ratio by EPMA	S/Ni atom ratio about 4:1	—	about	Text Approximate	4 · Synthesis and structural characterizations · Fig. S6
Nickel content by ICP-OES, main-text value	Ni = 21.29 wt% in main text	—	—	Text Uncertain	4 · Synthesis and structural characterizations
Nickel content by ICP-OES, SI table	Ni = 20.29 wt% in Table S2	—	—	SI Table Exact Reported	6 · Supplementary Figures · Table S2

Ni-PTC nanorod dark powder · Powder

Commercial Quantum Design MPMS-XL5 SQUID magnetometer; 300 to 2.5 K at 1 kOe; diamagnetic contribution subtracted by Pascal constants.

Temperature: 2.5-300
Geometry: powder
Context: pristine Ni-PTC MOF powder
Measurement source: 5-6 · Magnetic susceptibilities and electron spin resonance (ESR) · Fig. 5a

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Curie constant from Curie-Weiss fit	C = 1.839 emu K mol-1	—	—	Text Exact Reported	6 · Magnetic susceptibilities and electron spin resonance (ESR) · Fig. 5a
Magnetic ordering lower bound	No magnetic ordering observed down to 2.5 K	—	down to	Text Rounded Reported	6 · Magnetic susceptibilities and electron spin resonance (ESR) · Fig. 5a,c
chi_M T at one NiS4C8 subunit	chi_M T = 0.618 emu K mol-1	—	—	Text Exact Reported	6 · Magnetic susceptibilities and electron spin resonance (ESR) · Fig. 5a
Weiss temperature	theta = -595 K	—	—	Text Exact Reported	6 · Magnetic susceptibilities and electron spin resonance (ESR) · Fig. 5a

Ni-PTC nanorod dark powder · Powder

Shimadzu DTG 60 instrument under Ar atmosphere.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
TGA weight-loss onset	MOFs begin weight loss at 460 K	186.85 deg C	—	Caption Rounded Reported	4 · Supplementary Figures · Fig. S2