Electrical Transport — Fluorescent metal-organic frameworks for selective sensing of toxic cations (Tl3+, Hg2+) and highly oxidizing anions ((CrO4)2−, (Cr2O7)2−, (MnO4)−)

2 measurement groups · 9 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

compound I powdered single-crystal pellet with silver paint contacts · Pellet

Conductivity measured over 200-300 K; single crystals powdered and pressed into 0.4 cm diameter pellets with 0.034-0.045 cm thickness.

Temperature: 200-300; 300 K value reported
Atmosphere: not specified
Geometry: pressed pellet, two silver-paint contacts on opposite sides
Context: pristine MOF pellet
Measurement source: p004 / article p.1156 · Electrical Properties · Figure S13 referenced

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Arrhenius activation energy	0.27 eV	—	—	Text Rounded Reported	p004 / article p.1156 · Electrical Properties
DC conductivity at approximately 200 K read from Figure S13	approximately 3.1 x 10^-10 S m^-1 at 1000/T approximately 5.0 K^-1	—	—	Figure Axis Approximate	SI p.14 · Electrical properties · Figure S13a
DC conductivity at 300 K	in the range of 10^-10 S m^-1	—	—	Text Approximate	p004 / article p.1156 · Electrical Properties
DC conductivity at approximately 300 K read from Figure S13	approximately 8.5 x 10^-10 S m^-1 at 1000/T approximately 3.33 K^-1	—	—	Figure Axis Approximate	SI p.14 · Electrical properties · Figure S13a
Temperature dependence of conductivity	conductivity increases exponentially with decreasing temperature	—	—	Qualitative Qualitative	p004 / article p.1156 · Electrical Properties · Figure S13 referenced

compound II powdered single-crystal pellet with silver paint contacts · Pellet

Conductivity measured over 200-300 K; single crystals powdered and pressed into 0.4 cm diameter pellets with 0.034-0.045 cm thickness.

Temperature: 200-300; 300 K value reported
Atmosphere: not specified
Geometry: pressed pellet, two silver-paint contacts on opposite sides
Context: pristine MOF pellet
Measurement source: p004 / article p.1156 · Electrical Properties · Figure S13 referenced

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Arrhenius activation energyMarked as a best value within this paper	0.24 eV	—	—	Text Rounded Reported	p004 / article p.1156 · Electrical Properties
DC conductivity at approximately 200 K read from Figure S13	approximately 4.5 x 10^-9 S m^-1 at 1000/T approximately 5.0 K^-1	—	—	Figure Axis Approximate	SI p.14 · Electrical properties · Figure S13b
DC conductivity at 300 KMarked as a best value within this paper	in the range of 10^-8 S m^-1	—	—	Text Approximate	p004 / article p.1156 · Electrical Properties
DC conductivity at approximately 300 K read from Figure S13	approximately 1.25 x 10^-8 S m^-1 at 1000/T approximately 3.33 K^-1	—	—	Figure Axis Approximate	SI p.14 · Electrical properties · Figure S13b